Preparation of a Novel Spherical Nano-sized Iron Oxide

doi:10.11901/1005.3093.2021.268

Chinese Journal of Materials Research

2022, Vol. 36

Issue (12): 887-892 DOI: 10.11901/1005.3093.2021.268

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Preparation of a Novel Spherical Nano-sized Iron Oxide

HAO Suju(

), GAO Yice, JIANG Wufeng(

), SUN Tianhao, ZHANG Yuzhu

School of Metallurgy and Energy, North China University of Science and Technology, Ministry of Education Key Laboratory of Modern Metallurgy Technology, Tangshan 063009, China

Cite this article:

HAO Suju, GAO Yice, JIANG Wufeng, SUN Tianhao, ZHANG Yuzhu. Preparation of a Novel Spherical Nano-sized Iron Oxide. Chinese Journal of Materials Research, 2022, 36(12): 887-892.

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Abstract

A novel spherical nano-ferric oxide of 40~60 nm in diameter was prepared by pyrolysis precursor method, with Fe (NO₃)₃·9H₂O as raw material and urea as precipitator. The prepared spherical nano-sized ferric oxide was characterized by XRD, SEM and EDS. The effect of Fe³⁺ concentration, reaction temperature and other factors on the particle size and morphology of nano-sized ferric oxide were investigated. The preparation conditions of nano-sized ferric oxide were determined and the formation mechanism of nano-sized ferric oxide was also analyzed. The results show that the crystallinity and particle size of nano-sized ferric oxide increase with the increase of temperature. The concentration of Fe (NO₃)₃·9H₂O has little effect on the particle size and morphology of the prepared nano-sized iron oxide. The formation mechanism of spherical ferric oxide nanoparticles is as follows: the iron source hydrolysates and crystallizes under hydrothermal conditions to generate brownish yellow flocculant precipitation FeOOH, and FeOOH dissolves and recrystallizes in conditions of high temperature and high pressure further to generate spherical ferric oxide nanoparticles.

Key words: metallic materials spherical nano iron oxide pyrolysis precursor method Fe(NO₃)₃·9H₂O

Received: 29 April 2021

ZTFLH:

TB31

Fund: National Natural Science Foundation of China(51274084);Hebei Natural Science Foundation(E2018209323);Hebei Natural Science Foundation(E2022209125)

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	Suju HAO
	Yice GAO
	Wufeng JIANG
	Tianhao SUN
	Yuzhu ZHANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.268 OR https://www.cjmr.org/EN/Y2022/V36/I12/887

Fig.1 XRD spectrum of the prepared nanometer iron oxide sample

Fig.2 SEM image of nanometer iron oxide sample

Fig.3 EDS analysis of nanometer iron oxide sample

Fig.4 XRD analysis of samples prepared at different reaction temperatures

Fig.5 SEM images of samples prepared at different reaction temperatures (a) 160℃, (b) 180℃, (c) 200℃, (d) 220℃

Table 1 Particle size statistics of experimental samples at different temperature

Fig.6 Size of sample prepared at different reaction temperature

Fig.7 SEM of samples with different reactants (a) 1.3 g, (b) 1.7 g, (c) 2.1 g, (d) 2.5 g

Table 2 Statistics of particle size of nanometer iron oxide prepared by experiment

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