Fluorescent Tracing Abilities and Mechanical Properties of Au NCs/HA/PVA Composite Hydrogel

doi:10.11901/1005.3093.2020.500

Chinese Journal of Materials Research

2022, Vol. 36

Issue (2): 107-113 DOI: 10.11901/1005.3093.2020.500

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Fluorescent Tracing Abilities and Mechanical Properties of Au NCs/HA/PVA Composite Hydrogel

LIAO Jingwen, RAO Chunxing, WANG Yanqin(

), CHEN Weiyi

College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Cite this article:

LIAO Jingwen, RAO Chunxing, WANG Yanqin, CHEN Weiyi. Fluorescent Tracing Abilities and Mechanical Properties of Au NCs/HA/PVA Composite Hydrogel. Chinese Journal of Materials Research, 2022, 36(2): 107-113.

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Abstract

Composite hydrogel of Au NCs/HA/PVA with double network was prepared by means of chemical crosslinking and cyclic freezing-thawing with polyvinyl alcohol (PVA) as raw material, gold nanocluster (Au NCs) and hydroxyapatite (HA) as dopants, and glutaraldehyde as crosslinking agent. The effect of Au NCs content and the number of freezing-thawing cyclics on the physical properties of Au NCs/HA/PVA composite hydrogels was investigated. The results show that the mechanical strength of the gels increased with the increasing number of the freezing-thawing cycles. When the Au NCs content is 2.6% and the number of the freezing-thawing cyclic is 9, the gel has the optimized mechanical properties. The elastic modulus, breaking strength and fracture energy of the gel are 63.09 kPa, 152.84 kPa and 130.36 kJ·m^-3, respectively. The moisture content is about 80%, which is similar to the human cartilage tissue, and shows remarkable fluorescence properties.

Key words: composite double networks hydrogels mechanical characterization gold nanoclusters fluorescence tracing

Received: 23 November 2020

ZTFLH:

R318.08

Fund: National Natural Science Foundation of China(12172243);Natural Science Foundation of Shanxi Province(20210302123158)

About author: WANG Yanqin, Tel: (0351)3176655, E-mail: wangyanqin@tyut.edu.cn

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	Jingwen LIAO
	Chunxing RAO
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	Weiyi CHEN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.500 OR https://www.cjmr.org/EN/Y2022/V36/I2/107

Fig.1 Structure diagram of Au NCs/HA/PVA hydrogel

Fig.2 Transmission electron microscopy of Au NCs

Fig.3 Fluorescence spectra of Au NCs

Fig.4 Au NCs/HA/PVA composite hydrogels with different Au NCs contents under natural light (a) and ultraviolet light (b)

Fig.5 Fracture energy of Au NCs/HA/PVA composite hydrogel with different Au NCs content

Fig.6 Fracture stress of Au NCs/HA/PVA composite hydrogel with different Au NCs content

Fig.7 Elastic modulus of Au NCs/HA/PVA composite hydrogel with different Au NCs content during tensile

Fig.8 Elastic modulus of Au NCs/HA/PVA composite hydrogel with different Au NCs content in compression

Fig.9 SEM image of Au NCs_5.3/HA/PVA hydrogel

Fig.10 Fracture energy of Au NCs/HA/PVA composite hydrogel after different freezing thawing cycles

Fig.11 Fracture stress of Au NCs/HA/PVA composite hydrogel after different freezing thawing cycles

Fig.12 Elastic modulus of Au NCs/HA/PVA composite hydrogel after different freezing thawing cycles during tensile

Fig.13 Elastic modulus of Au NCs/HA/PVA composite hydrogel after different freezing thawing cycles in compression

Fig.14 Change of swelling ratio of Au NCs/HA/PVA composite hydrogel with different Au NCs content over time

1	Lee K Y , Mooney D J . Hydrogels for tissue engineering [J]. Chem. Rev., 2001, 101: 1869
2	Niu C , Zhang H J , Yang B . A nanocomposite interpenetrating hydrogel with high toughness: effects of the posttreatment and molecular weight [J]. Colloid Polym. Sci., 2021, 299: 1
3	Pan T , Zhang Y , Wang C H , et al . Mulberry-like polyaniline-based flexible composite fabrics with effective electromagnetic shielding capability [J]. Compo. Sci. Technol., 2020, 188: 107991
4	Han X , Li M Y , Fan Z W , et al . PVA/Agar Interpenetrating network hydrogel with fast healing, high strength, antifreeze, and water retention [J]. Macromol. Chem. Phys., 2020, 221: 2070049
5	Ito K . Novel cross-linking concept of polymer network: synthesis, structure, and properties of slide-ring gels with freely movable junctions [J]. Polym. J., 2007, 39: 489
6	Yang J , Yu X Q , Sun X B , et al . Polyaniline-decorated supramolecular hydrogel with tough, fatigue-resistant, and self-healable performances for all-in-one flexible supercapacitors [J]. ACS Appl. Mater. Interfaces, 2020, 12: 9736
7	Rivero R E , Molina M A , Rivarola C R , et al . Pressure and microwave sensors/actuators based on smart hydrogel/conductive polymer nanocomposite [J]. Sens. Actuat., 2014, 190B: 270
8	Gonzalez J S , Ludueña L N , Ponce A , et al . Poly (vinyl alcohol)/cellulose nanowhiskers nanocomposite hydrogels for potential wound dressings [J]. Mater. Sci. Eng., 2014, 34C: 54
9	Yang B W , Yuan W Z . Highly stretchable and transparent double-network hydrogel ionic conductors as flexible thermal–mechanical dual sensors and electroluminescent devices [J]. ACS Appl. Mater. Interfaces, 2019, 11: 16765
10	Ramakrishna S , Mayer J , Wintermantel E , et al . Biomedical applications of polymer-composite materials: a review [J]. Compo. Sci. Technol., 2001, 61: 1189
11	Chen J R , Shi X T , Ren L , et al . Graphene oxide/PVA inorganic/organic interpenetrating hydrogels with excellent mechanical properties and biocompatibility [J]. Carbon, 2017, 111: 18
12	Morariu S , Bercea M , Gradinaru L M , et al . Versatile poly (vinyl alcohol)/clay physical hydrogels with tailorable structure as potential candidates for wound healing applications [J]. Mater. Sci. Eng., 2020, 109C: 110395
13	Oh S H , An D B , Kim T H , et al . Wide-range stiffness gradient PVA/HA hydrogel to investigate stem cell differentiation behavior [J]. Acta Biomater., 2016, 35: 23
14	Borghei Y S , Hosseini M , Ganjali M R . Oxidase-like catalytic activity of Cys-AuNCs upon visible light irradiation and its application for visual miRNA detection [J]. Sens. Actuat., 2018, 273B: 1618
15	Yu P , Bao R Y , Shi X J , et al . Self-assembled high-strength hydroxyapatite/graphene oxide/chitosan composite hydrogel for bone tissue engineering [J]. Carbohydr. Polym., 2017, 155: 507
16	Chen Y M , Dong K , Liu Z Q , et al . Double network hydrogel with high mechanical strength: Performance, progress and future perspective [J]. Sci. China Technol. Sci., 2012, 55: 2241
17	Xu D D , Huang J C , Zhao D , et al . High‐flexibility, high‐toughness double‐cross‐linked chitin hydrogels by sequential chemical and physical cross‐linkings [J]. Adv. Mater., 2016, 28: 5844
18	Rana H H , Park J H , Ducrot E , et al . Extreme properties of double networked ionogel electrolytes for flexible and durable energy storage devices [J]. Energy Storage Mater., 2019, 19: 197
19	Liu Z Z , Zhang J M , Liu J , et al . Highly compressible and superior low temperature tolerant supercapacitors based on dual chemically crosslinked PVA hydrogel electrolytes [J]. J. Mater. Chem., 2020, 8A: 6219
20	Gong J P , Katsuyama Y , Kurokawa T , et al . Double‐network hydrogels with extremely high mechanical strength [J]. Adv. Mater., 2003, 15: 1155
21	Gao F Y , Wei D L , Zhang X , et al . Research progress of hydrogel and its application in biomedicine [J]. New Chem. Mater., 2018, 46(): 6
	高凤苑, 韦东来, 张鑫等 . 水凝胶的研究进展及在生物医学方面的应用 [J]. 化工新型材料, 2018, 46(): 6
22	Zhang L , Zhang N , Cao Q F . Research progress in preparation methods of PVA hydrogels [J]. Chem. Ind. Times, 2018, 32(2): 29
	张林, 张娜, 曹秋枫 . PVA水凝胶制备方法研究进展 [J]. 化工时刊, 2018, 32(2): 29
23	Hu X Y , Fan L D , Qin G , et al . Flexible and low temperature resistant double network alkaline gel polymer electrolyte with dual-role KOH for supercapacitor [J]. J. Power Sources, 2019, 414: 201
24	Li W W , Lu H , Zhang N , et al . Enhancing the properties of conductive polymer hydrogels by freeze-thaw cycles for high-performance flexible supercapacitors [J]. ACS Appl. Mater. Interfaces, 2017, 9: 20142
25	Liu M C , Guo J Y , Hui C Y , et al . Crack tip stress based kinetic fracture model of a PVA dual-crosslink hydrogel [J]. Extreme Mech. Lett., 2019, 29: 100457
26	Gong Z Y , Zhang G P , Zeng X L , et al . High-strength, tough, fatigue resistant, and self-healing hydrogel based on dual physically cross-linked network [J]. ACS Appl. Mater. Interfaces, 2016, 8: 24030

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