Feasibility of Electrospun 2-Dimensional CdO Nanorods for Application in Glucose Sensors

doi:10.11901/1005.3093.2020.036

Chinese Journal of Materials Research

2021, Vol. 35

Issue (1): 53-58 DOI: 10.11901/1005.3093.2020.036

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Feasibility of Electrospun 2-Dimensional CdO Nanorods for Application in Glucose Sensors

WANG Yongpeng, JIA Zhihao, LIU Mengzhu(

)

Jilin Institute of Chemical Technology, Jilin 132022, China

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WANG Yongpeng, JIA Zhihao, LIU Mengzhu. Feasibility of Electrospun 2-Dimensional CdO Nanorods for Application in Glucose Sensors. Chinese Journal of Materials Research, 2021, 35(1): 53-58.

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Abstract

2-dimensional CdO nanorods were fabricated by electrospinning technique with poly(vinyl pyrrolidone) (PVP) as template and subsequently calcinated. SEM, TGA, DSC, FT-IR and XRD were used to characterize the morphology and structure of the as-prepared nanorods. The results show that the CdO nanorods is highly purified with a special morphology, namely, the nanorods stick together to form a porous film. The special morphology is related to the melting of PVP polymer during calcination. The prepared CdO nanorods were subsequently used to modify a glassy carbon electrode and then, with which the direct electrocatalytic oxidation of glucose was investigated. Results show that the CdO nanorods modified electrode has a better response to glucose and stronger resistance to the interference from AA, UA and ethanol rather than the electrode modified with CdO powder. The improved performance can be ascribed to the 2-dimensional CdO nanorods morphology, which enhanced the specific surface area, thereby enhancing the activity of electrode, facilitating the oxidation of glucose. So that, the fabricated CdO nanorods have the possibility of application as glucose sensor.

Key words: synthesizing and processing technics for materials cadmium oxide nanorods electrospinning glucose sensor two-dimensional nano structure

Received: 06 February 2020

ZTFLH:

O69

Fund: Education Department of Jilin Province (Nos. JJKH20190831KJ ＆ JJKH20200249KJ), Science and Technology Innovation Development Program of Jilin City (Nos. 201831765 ＆ 20190104129)

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	Yongpeng WANG
	Zhihao JIA
	Mengzhu LIU

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.036 OR https://www.cjmr.org/EN/Y2021/V35/I1/53

Fig.1 SEM images of before calcination (a), after calcination at 600℃ for 4 h (b) of PVP/Cd(CH₃COO)₂ composite nanofibers and pure CdO powder (c)

Fig.2 Formation mechanism of the nanorods

Fig.3 TGA curves (A) and DSC curves (B) of PVP nano-fibers (a) and PVP/Cd(CH₃COO)₂ composite na-nofibers (b)

Fig.4 FI-IR spectra of (a) PVP/Cd(CH₃COO)₂ composite nanofibers; (b) is (a) after calcination at 600℃ for 4 h

Fig.5 XRD spectra of pure CdO powder (a) and PVP/Cd-(CH₃COO)₂ composite nanofibers (b) after calcination at 600℃ for 4 h

Fig.6 CV curves of different samples in 0.1 mol/L NaOH of CdO-powder-GCE (a) and CdO-NRs-GCE (b) (volatage range is 0.2~0.7 V and the scan rate is 50 mV/s)

Fig.7 CV curves of CdO-NRs-GCE at 50 mV/s. (a) 0.1 mol/L NaOH; (b) 0.1 mol/L NaOH+0.4 mmol/L glucose; (c) 0.1 mol/L NaOH+0.8 mmol/L glucose

Fig.8 Amperometric responses of CdO-powder-GCE(a) and CdO-NRs-GCE (b) with successive additions of 3 mmol/L glucose, 0.1 mmol/L AA, 0.1 mmol/L UA, 10 mmol/L ethanol to 0.1 mol/L NaOH at 0.40 V

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