Effect of Annealing Temperature on Microstructure and Martensitic Transformation of Cold Rolled Ti-13V-3Al-0.5Cu Shape Memory Alloy

doi:10.11901/1005.3093.2020.164

Chinese Journal of Materials Research

2020, Vol. 34

Issue (10): 721-729 DOI: 10.11901/1005.3093.2020.164

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Effect of Annealing Temperature on Microstructure and Martensitic Transformation of Cold Rolled Ti-13V-3Al-0.5Cu Shape Memory Alloy

SUN Kuishan¹, LI Jun², MENG Xianglong¹(

), CAI Wei¹

1. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150006, China
2. College of Mechanical and Electrical Engineering, Northeast Forestry University, Harbin 150040, China

Cite this article:

SUN Kuishan, LI Jun, MENG Xianglong, CAI Wei. Effect of Annealing Temperature on Microstructure and Martensitic Transformation of Cold Rolled Ti-13V-3Al-0.5Cu Shape Memory Alloy. Chinese Journal of Materials Research, 2020, 34(10): 721-729.

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Abstract

The effect of post annealing temperature on the microstructure, martensitic transformation behavior, mechanical properties and shape memory effect of the cold rolled Ti-13V-3Al-0.5Cu (%, atomic fraction) alloy was systematically studied by means of XRD, TEM, DSC and tensile test at room temperature. The results showed that the phase composition of the alloy at room temperature was mainly α" phase, together with a small amount of remained β phase, α phase and Ti₂Cu second phase. With the increasing annealing temperature, the shape memory property increased firstly and then decreased. When the annealing temperature is 750℃, the alloy showed a good shape memory effect and the recoverable strain up to 5.3% when the pre-strain was 6%. Furthermore, the morphology of martensite transformed from a V-shape like self-coordinated-structure to a structure of single preferential orientation when the alloy was subjected to a proper cold rolling and annealing treatment. Lower reorientation critical stress and better interface mobility were the main causes for the improvement of shape memory effect.

Key words: metallic materials Ti-V-Al-Cu light-weight shape memory alloy microstructure

Received: 14 May 2020

ZTFLH:

TG15

Fund: National Natural Science Foundation of China(51871080);National Natural Science Foundation of China(51571073)

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	Kuishan SUN
	Jun LI
	Xianglong MENG
	Wei CAI

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.164 OR https://www.cjmr.org/EN/Y2020/V34/I10/721

Fig.1 Schematic drawing of tensile specimen

Fig.2 X-ray diffraction spectra of Ti-13V-3Al-0.5Cu alloy annealed at different temperatures after cold rolling

Fig.3 Bright field image and corresponding diffraction patterns of Ti-V-Al-Cu alloy annealed at (a) 650℃, (b) 750℃ and (c) 900℃

C.V.	[100]_α_"	[010]_α_"	[001]_α_"
CV1	[100]_β	[011]_β	[0 $1 ˉ$ 1]_β
CV2	[ $1 ˉ$ 00]_β	[0 $1 ˉ$ 1]_β	[011]_β
CV3	[010]_β	[101]_β	[10 $1 ˉ$ ]_β
CV4	[0 $1 ˉ$ 0] _β	[10 $1 ˉ$ ]_β	[101]_β
CV5	[001]_β	[110]_β	[ $1 ˉ$ 10]_β
CV6	[00 $1 ˉ$ ]_β	[ $1 ˉ$ 10]_β	[110]_β

Table 1 Orientation relationship between β phase and martensite variants in martensitic transformation

C.V.	T_i	C.V.	T_i
CV1	$0.9374 00 0 1.0051 - 0.0032 0 - 0.0032 1.0051$	CV2	$0.9374 00 0 1.0051 0.0032 0 1.0051 0.0032$
CV3	$1.0051 0 0.0032 0 0.9374 0 0.0032 0 1.0051$	CV4	$1.0051 0 - 0.0032 0 0.9374 0 - 0.0032 0 1.0051$
CV5	$1.0051 0.0032 0 0.0032 1.0051 0 00 0.9374$	CV6	$1.0051 - 0.0032 0 - 0.0032 1.0051 0 00 0.9374$

Table 2 Lattice distortion matrix for six lattice corresponding variants

Fig.4 The self-accommodation morphologies in the Ti-V-Al-Cu alloy (a) V-shape type; (b) triangular type

Fig.5 DSC curves of Ti-13V-3Al-0.5Cu alloy annealed at different temperatures after cold rolling (a) 650℃; (b) 700℃; (c) 750℃; (d) 800℃

Fig.6 (a) stress-strain curves of Ti-13V-3Al-0.5Cu alloy annealed at different temperatures after cold rolling, (b) effect of annealing temperature on strength and fracture strain

Fig.7 Stress-strain curves of Ti-13V-3Al-0.5Cu alloy an-nealed at different temperatures after cold rolling (a) 700℃; (b) 750℃; (c) 800℃; (d) relationship between recoverable strain and annealing tem-perature

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