Influence of High Temperature Water Vapor on Characteristics of CO2 Electrochemical Sensor

doi:10.11901/1005.3093.2018.711

Chinese Journal of Materials Research

2019, Vol. 33

Issue (9): 713-720 DOI: 10.11901/1005.3093.2018.711

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Influence of High Temperature Water Vapor on Characteristics of CO₂ Electrochemical Sensor

WANG Guangwei^1,²(

),CHEN Hongzhen²,LI Youfeng¹,XIE Bo¹,JIANG Zhongyuan¹

1. Department of Chemistry and Chemical Engineering, Zunyi Normal University, Zunyi 563006, China
2. Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology (CIGIT), Chinese Academy of Sciences, Chongqing 400714, China

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WANG Guangwei,CHEN Hongzhen,LI Youfeng,XIE Bo,JIANG Zhongyuan. Influence of High Temperature Water Vapor on Characteristics of CO₂ Electrochemical Sensor. Chinese Journal of Materials Research, 2019, 33(9): 713-720.

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Abstract

Carbon dioxide electrochemical sensor was prepared with Li and Ba co-doped oxycarbonate as auxiliary sensing electrode and YSZ as electrolyte, then the influence of high temperature water vapor on the performance of the sensor was investigated. The results show that the potentiometric sensor respond correctly and rapidly to the change of CO₂ concentration (271~576802 μL/L) after pretreatment in water vapor (300℃) for 24~120 h. The number of transfer electrons of the electrode reactions were approximately 2. Low oxygen dependency was found for the sensors, whether they were pretreated or not in water vapor for 120 h, all responded rapidly and accordingly for different oxygen content. The sensor worked not only in water vapor for relatively long term, but also after the constantly water vapor treatment to some extent.

Key words: inorganic non-metallic materials dope oxycarbonate water vapor YSZ CO₂ sensor

Received: 16 December 2018

ZTFLH:

TQ174.7

Fund: National Natural Science Foundation of China(41763008);Natural Science Foundation of the Science & Technology Department of Guizhou Province(2019-1461);Science and Technology Foundation of the Science & Technology Department of Guizhou Province(2018-2774);Natural Science Research Project of Education Department of Guizhou Province(2017-086);Doctor Foundation of Zunyi Normal College(BS2017-02);Frontier and Application Foundation Research Program of Chongqing(cstc2015jcyjA20008)

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	Guangwei WANG
	Hongzhen CHEN
	Youfeng LI
	Bo XIE
	Zhongyuan JIANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.711 OR https://www.cjmr.org/EN/Y2019/V33/I9/713

Fig.1 Schematic draw of CO₂ sensor

Table 1 Pretreatment of sensors by elevated temperature water vapor

Fig.2 XRD diffraction patterns of the sensing electrode (A: Entry1; B: Entry6)

Fig.3 SEM images of sensing electrode surfaces (a) Entry 1 without Au paste; (b) Entry 6 without Au paste; (c) Entry 1 with Au paste; (d) Entry 6 with Au paste

Fig.4 Response of sensor with the continuous change (576802→271→576802 μL/L) of CO₂ concentration (a) Entry1; (b) Entry2; (c) Entry3; (d) Entry4; (e) Entry5; (f) Entry6

Fig.5 Response of sensor with the continuous change (271→576802→271 μL/L) of CO₂ concentration (a) Entry 1; (b) Entry 2; (c) Entry 3; (d) Entry 4; (e) Entry 5; (f) Entry 6

Table 2 Transfer electrons (n) and potentials per lgc(CO₂) (△E) with continuous change (576802→271→576802 μL/L) of CO₂ concentration

Table 3 Transfer electrons (n) and potentials per lgc(CO₂) (△E) with continuous change (271→576802→271 μL/L) of CO₂ concentration

Fig.6 Stability of sensors (a: Entry 1 with air; b: Entry 1 with 2% oxygen; c: Entry 1 with 0.2% oxygen; d: Entry 6 with air; e: Entry 6 with 2% oxygen; f: Entry 6 with 0.2% oxygen)

Fig.7 Response of sensor with the existence of 10% water vapor

Fig.8 Long term stability of sensor with the existence of 10% water vapor

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