Preparation and Property of SiBN Ternary Ceramic Fibers Prepared by Polyborosilazane-Derived Method

doi:10.11901/1005.3093.2018.373

Chinese Journal of Materials Research

2019, Vol. 33

Issue (2): 155-160 DOI: 10.11901/1005.3093.2018.373

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Preparation and Property of SiBN Ternary Ceramic Fibers Prepared by Polyborosilazane-Derived Method

Yongjie CUI,Yong LIU(

),Shuai PENG,Keqing HAN,Muhuo YU

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Cite this article:

Yongjie CUI,Yong LIU,Shuai PENG,Keqing HAN,Muhuo YU. Preparation and Property of SiBN Ternary Ceramic Fibers Prepared by Polyborosilazane-Derived Method. Chinese Journal of Materials Research, 2019, 33(2): 155-160.

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Abstract

Polyborosiliazne precursor was synthesized via multi-stage polymerization process with HSiCl₃, Me₆Si₂NH, BCl₃ and CH₃NH₂ as raw materials. Then SiBN ceramic fibers were obtained by melt spinning, curing and pyrolysis of the as-synthesized polyborosilazane precursor. The chemical structure, high temperature thermal stability, dielectric property and mechanical property of the polyborosilazane and its pyrolysis products were investigated by FT-IR, NMR, XRD, TEM and TGA. FT-IR and NMR. Results show that the polyborosilazane precursors prepared at different temperatures exhibited similar chemical structures, namely, containing Si-N, B-N and N-CH₃ bonds. The obtained SiBN ceramic fibers remained amorphous structure with 14 μm in diameter and 0.91 GPa in tensile strength after heat treatment at 1400^oC. The SiBN ceramic fibers have excellent thermal stability with only 1.5% mass loss in the temperature range from room temperature to 1400^oC. The dielectric constant and dielectric loss loss tangent magnitude of SiBN ceramic fibers are 2.6~2.8 and 10^-2 at 1100^oC, respectively.

Key words: inorganic nonmetallic materials polyborosilazane pyrolysis SiBN ceramic fiber thermal stability dielectric property

Received: 06 June 2018

ZTFLH:

TQ343

Fund: National Natural Science Foundation of China(51703025)

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	Yongjie CUI
	Yong LIU
	Shuai PENG
	Keqing HAN
	Muhuo YU

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.373 OR https://www.cjmr.org/EN/Y2019/V33/I2/155

Fig.1 FT-IR spectra of PBSZ synthesized at different polymerization temperature

Fig.2 ¹³C-MAS NMR spectra of PBSZ prepared at different polymerization temperature

Fig.3 ²⁹Si-NMR spectra of PBSZ prepared at different polymerization temperature

Fig.4 ¹¹B-NMR spectra of PBSZ prepared at different polymerization temperature

Fig.5 Preparation process of PBSZ precursor

Fig.6 XRD patterns of SiBN ceramic fibers pyrolyzed at different temperature

Fig.7 TEM image of SiBN ceramic fibers pyrolyzed at 1400℃

Fig.8 TGA curve of SiBN ceramic fibers (performed in nitrogen)

Fig.9 Dielectric constant and loss of SiBN ceramics fibers with different pyrolysis temperature

Table 1 Mechanical property of PBSZ green fibers, cured fibers and pyrolyzed fibers

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