Preparation and Property of Bi-continuous Phase TiC/Fe Composite

doi:10.11901/1005.3093.2015.602

Chinese Journal of Materials Research

2017, Vol. 31

Issue (10): 743-750 DOI: 10.11901/1005.3093.2015.602

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Preparation and Property of Bi-continuous Phase TiC/Fe Composite

Jianhong LAI, Yang ZHOU(

), Yong ZHENG, Jiaqi WANG, Zhenying HUANG, Shibo LI, Hongxiang ZHAI

School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China

Cite this article:

Jianhong LAI, Yang ZHOU, Yong ZHENG, Jiaqi WANG, Zhenying HUANG, Shibo LI, Hongxiang ZHAI. Preparation and Property of Bi-continuous Phase TiC/Fe Composite. Chinese Journal of Materials Research, 2017, 31(10): 743-750.

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Abstract

Porous TiC-ceramics of three-dimensional network structure were prepared by organic precursor impregnation method using polyurethane sponge as precursor with a small amount of powders of reduced iron, carbonyl iron and titanium as the sintering additives. The influence of the pore size of polyurethane sponge and times of slurry-applying on the porosity and skeleton diameter of porous TiC-ceramics was investigated. Then composite of Bi-continuous phase TiC/Fe was prepared by pressureless infiltration method. The phase composition, the macro- and micro-structure as well as the hardness distribution of the composite were assessed. Results show that the prepared porous TiC-ceramics is integrated in structure, while their porosity and size of TiC-skeleton are controllable. The composite of TiC/Fe exhibited a perfect bi-continuous phase structure with a good combination between TiC and Fe. A gradient hardness distribution of two-phase combining areas was observed.

Key words: composites bi-continuous phase organic precursor impregnation pressureless infiltration TiC

Received: 27 October 2016

ZTFLH:

TB333

Fund: Supported by National Natural Science Foundation of China (Nos.51472024 & 51372015)

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	Articles by authors
	Jianhong LAI
	Yang ZHOU
	Yong ZHENG
	Jiaqi WANG
	Zhenying HUANG
	Shibo LI
	Hongxiang ZHAI

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.602 OR https://www.cjmr.org/EN/Y2017/V31/I10/743

Table 1 Purity (mass fraction), particle size and content (mass fraction) of raw materials in porous ceramics

Fig.1 Figure of pressureless infiltration

Fig.2 Morphology and structure of the skeleton of porous ceramics with different PPI value. (a, b) 30PPI, (c, d) 45PPI, (e, f) 90PPI

Fig.3 Cross-sectional morphology of the Porous ceramics skeleton

Fig.4 XRD figure of the porous ceramic before and after sintering

Table 2 Mass fraction of each phase in porous ceramic before and after sintering

Fig.5 Macrostructures of porous ceramics prepared with 30 PPI sponge through different coating times (a) 2, (b) 3, (c) 4 and (d) 5

Fig.6 Relations between the diameter of porous ceramic skeleton and the coating times

Fig.7 Relations between the porosity of porous ceramic and the coating times

Fig.8 Back scattering SEM photos of TiC/Fe composite materials' profile

Fig.9 XRD figure of the cross-sectional of the TiC/Fe composite materials

Fig.10 Vickers hardness indentations of the test composites (a) ceramic skeleton; (b) iron matrix; (c) combination region between skeleton and matrix

Fig.11 Vickers hardness values in different areas of the composites

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