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| Hydroxyapatite Coatings on Titanium Substrate Prepared by Hydrothermal-Electrochemical Deposition |
Jing DU1,Daihua HE1,**( ),Ping LIU1,Xinkuan LIU1,Fengcang MA1,Wei LI1,Xiaohong CHEN1,Ke ZHANG1,Jun ZHAO2 |
1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
2. Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050, China |
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Cite this article:
Jing DU,Daihua HE,Ping LIU,Xinkuan LIU,Fengcang MA,Wei LI,Xiaohong CHEN,Ke ZHANG,Jun ZHAO. Hydroxyapatite Coatings on Titanium Substrate Prepared by Hydrothermal-Electrochemical Deposition. Chinese Journal of Materials Research, 2016, 30(10): 787-794.
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Abstract Hydroxyapatite coatings were deposited on the Ti6Al4V surface by hydrothermal-electrochemical deposition method in an electrolyte composited of 0.025 mol/L Ca2+, 0.015 mol/L H2PO4- and 0.1 mol/L NO3- with addition of 2.5×10-4 mol/L Na-Citrate . The effect of the citrate and deposition time on the composition, microstructure, crystallinity and thickness of coatings as well as the bonding strength between the coating and the substrate were investigated. The results show that: in comparison with the electrolyte without citrate, HA coating formed in the electrolyte with addition of citrate exhibits uniform and compact appearance with smaller gain size, which covers entirely the substrate, correspondingly the bonding strength between the coating and the substrate increases from 15.39 MPa to 24.31 MPa. The thickness of HA coating increases non-linearly with deposition time. With the increase of deposition time, the orientation index of the (002) plane of HA increases first and then decreases, which reaching a maximum for 2 h deposition while the coating has much smaller grain size; the crystallinity and bonding strength of HA coatings all increase first, and then decrease, which come to peak values, ca 75.7% and 24.3 MPa respectively by 2 h deposition.
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Received: 17 March 2016
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| Fund: *Supported by the Key Laboratory of Inorginic Coating Materials, Chinese Academy of Sciences No. KLICM-2014-11, and the Shanghai Municipal Natural Science Foundation Sponsored by Shanghai Municipal Science and Technology Commissions No. 15ZR1428300. |
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