Preparation of Montmorillonite by Two-step Intercalation and Its Effect on the Corrosion Resistance of Epoxy Coatings

doi:10.11901/1005.3093.2014.163

Chinese Journal of Materials Research

2014, Vol. 28

Issue (9): 668-674 DOI: 10.11901/1005.3093.2014.163

Current Issue | Archive | Adv Search

Preparation of Montmorillonite by Two-step Intercalation and Its Effect on the Corrosion Resistance of Epoxy Coatings

Mingming LIU¹,Guilai YIN²,Fuchun LIU^1,^**(

),Nan TANG²,Enhou HAN¹,Junbiao WAN²,Jingwei DENG²

1. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2. State Grid Jiangxi Electric Power Research Institute, Nanchang 330096

Cite this article:

Mingming LIU,Guilai YIN,Fuchun LIU,Nan TANG,Enhou HAN,Junbiao WAN,Jingwei DENG. Preparation of Montmorillonite by Two-step Intercalation and Its Effect on the Corrosion Resistance of Epoxy Coatings. Chinese Journal of Materials Research, 2014, 28(9): 668-674.

Download:

HTML

PDF(1574KB)
Export: BibTeX | EndNote (RIS)

Abstract

Two-step intercalation montmorillonites were prepared with montmorillonites (MMTs) as raw material and firstly octadecylamine was used as an modifier to prepare organic MMTs and then 8-hydroxyquinoline as the inhibitor to treat organic MMTs. The MMTs were characterized by infrared spectra and X-ray diffraction. The results show that octadecylamine and 8-hydroxyquinoline have intercalated into the layer of MMTs, and the spacing of MMTs respectively enlarged from 1.17 nm to 1.57 nm and 1.82 nm. The resultant MMTs enhanced significantly the corrosion resistance of the epoxy coating according to EIS results.

Key words: organic polymer materials montmorillonite intercalation agents anticorrosive materials power transmission equipment

Received: 01 April 2014

Fund: *Supported by National Science and Technology Support Program No.2012BAB15B00 and State Grid Practical Project No.521820130014.

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Mingming LIU
	Guilai YIN
	Fuchun LIU
	Nan TANG
	Enhou HAN
	Junbiao WAN
	Jingwei DENG

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2014.163 OR https://www.cjmr.org/EN/Y2014/V28/I9/668

Fig.1 Intercalation process of MMTs with firstly octadecylamine modified and then inhibitor 8-hydroxyquinoline treated

Fig.2 Small angle X-ray scattering spectra of unmodified MMT(a), modified MMT(b), two-step intercalation MMT(c)

Table1 Interlayer spacing of MMTs treated with different methods

Fig.3 IR of unmodified MMT(a), modified MMT(b), two-step intercalation MMT(c)

Fig.4 Nyquist and Bode plots for unmodified MMT/epoxy coating(a), modified MMT/epoxy coating(b), two-step intercalation MMT/epoxy coating(c)

Fig.5 EEC models for the coatings at different immersion stages

Fig.6 Coating resistance and capacitance changes during immersion. (a) resistance, (b) capacitance

Fig.7 Small angle XRD spectra of epoxy coating containing MMT treated with 8-hydroxyquinoline

Fig.8 Linear fitting of Fick diffusion in initial immersion time. (a) unmodified MMT/epoxy coating; (b) modified MMT/epoxy coating; (c) two-step intercalation MMT/epoxy coating

Table 2 Linear fitting and water diffusion coefficient of coatings

1	CUI Huiwang,DU Guanben, Characteristics and preparation of OMMT, Industrial Minerals and Processing, (3), 14(2009)
1	崔会旺, 杜官本, 有机蒙脱土的制备及表征, 化工矿物与加工, (3), 14(2009)
2	ZHANG Xiaohong, CAI Libin, YIN Guoqiang, ZHANG Weigang, CUI Yingde, Preparation of organic-intercalated montmorillonite by two-step intercalation, Modern Chemical Industry, 23(11), 38(2003)
2	张小红, 蔡立彬, 尹国强, 张维刚, 崔英德, 二次插层法制备有机蒙脱石的研究, 现代化工, 23(11), 38(2003)
3	CHEN Haiqun, LI Yingyong, ZHU Junwu, YANG Xujie, LU Lude, WANG Xin, Preparation and characterization of the organic montmorillonite with sodium laurylsulfonate, Chinese Journal of Inorganic Chemistry, 20(3), 251(2004)
3	陈海群, 李英勇, 朱俊武, 杨绪杰, 陆路德, 汪信, 十二烷基磺酸钠改性蒙脱土的制备与表征, 无机化学学报, 20(3), 251(2004)
4	M. L. Zhu, Y. Jie, J. X. Hong,Polyimide/montmorillonite nanocompositer based on thermally stable, rigid-rob aromatic amine modifier, Polymer, 44, 1391(2003)
5	Jin Ho Choy,Seo Young Kwak, Yang Su han, New organo-montmorillonite complexes with hydrophobic and hydrophilic function, Material Letters, 33(3), 143(1997)
6	GE Jinlong,QIN Yingyue, WANG Chuanhu, Study on preparation and application of organic montmorillionite, New Chemical Materials, 39(9), 113(2009)
6	葛金龙, 秦英月, 王传虎, 有机蒙脱土的制备及应用研究, 化工新型材料, 39(9), 113(2009)
7	N. Hasegawa, H. Okamoto, M. Kato, A. Usuki,Preparation and mechanical properties of polypropylene-clay hybrids based on modified poly-propylene and organophilic clay, Journal of Applied Polymer Science, 78(11), 1918(2000)
8	M. R. Bagherzadeh, T. Mousavinejad,Preparation and investigation of anticorrosion properties of the water-based epoxy-clay nanocoating modified by Na+-MMT and Cloisite 30B, Progress in Organic Coatings, 74(3), 589(2012)
9	Amir H. Navarchian, Mehrnaz Joulazadeh, Fariba Karimi, Investigation of corrosion protection performance of epoxy coatings modified by polyaniline/clay nanocomposites on steel surfaces, Progress in Organic Coatings, 77(2), 347(2014)
10	Milo?D. Tomi?, Branko Dunji?, Violeta Liki?, Jelena Bajat, Jelena Rogan, Jasna Djonlagi?, The use of nanoclay in preparation of epoxy anticorrosive coatings, Progress in Organic Coatings, 77(2), 518(2014)
11	LI Fengqi,Preparation and characterization of multi-insert layer organophilic montmorillonite and its dispersibility, New Chemical Materials, 36(8), 89(2008)
11	李风起, 有机蒙脱土的复合插层及分散性研究, 化工新型材料, 36(8), 89(2008)
12	F. C. Liu, E. H. Han, W. Ke, N. Tang, J. B. Wan, G. L. Yin, J. W. Deng, K. W. Zhao,Polar influence of the organic modifiers on the structure of montmorillonite in epoxy nanocomposites, Journal of Materials Science Technology, 29(11), 1040(2013)
13	LIN Yifan,PAN Taijun, Organic modification of montmorillonite and choice of intercalation agent, Science Technology in Chemical Industry, 18(1), 24(2010)
13	林一凡, 潘太军, 蒙脱土的有机化改性剂插层剂的选择, 化工科技, 18(1), 24(2010)
14	ZHANG Jing,YANG Yukun, Preparation of PMMA/montmorillonite nanocomposite by using intercalation method and suspension polymerization, Acta Polymerica Sinica, (1), 79(2001)
14	张径, 杨玉昆, 插层法悬浮聚合制PMMA/蒙脱土纳米复合材料, 高分子学报, (1), 79(2001)
15	MA Xiaoyan, LIANG Guozheng, LU Haijun, Polymer-Natural Silicate Clay Nano-Composites (Beijing, Science Press, 2009) p.216
15	马晓燕, 梁国正, 鹿海军, 聚合物/天然硅酸盐黏土纳米复合材料 (北京, 科学出版社, 2009) p.216
16	Chen Lizhuang,Study on the inhibition mechanism of organic corrosion inhibitor in epoxy coatings, Master?s thesis, Jiangsu University of Science Technologyd(2006)
16	陈立庄, 有机缓蚀剂在环氧涂层中的作用机理研究, 硕士学位论文, 江苏科技大学(2006)
17	M. L. Zheludkevich, K. A. Yasakau, A. C. Bastos,On the application of electrochemical impedance spectroscopy to study the self-healing properties of protective coatings, Electrochemistry Communications, 9(10), 2622(2007)

[1]	YE Jiaofeng, WANG Fei, ZUO Yang, ZHANG Junxiang, LUO Xiaoxiao, FENG Libang. Epoxy Resin-modified Thermo-reversible Polyurethane with High Strength, Toughness, and Self-healing Performance[J]. 材料研究学报, 2023, 37(4): 257-263.
[2]	LI Hanlou, JIAO Xiaoguang, ZHU Huanhuan, ZHAO Xiaohuan, JIAO Qingze, FENG Caihong, ZHAO Yun. Synthesis of Branched Fluorine-containing Polyesters and their Properties[J]. 材料研究学报, 2023, 37(4): 315-320.
[3]	MA Yizhou, ZHAO Qiuying, YANG Lu, QIU Jinhao. Preparation and Dielectric Energy Storage Properties of Thermoplastic Polyimide/Polyvinylidene Fluoride Composite Film[J]. 材料研究学报, 2023, 37(2): 89-94.
[4]	SHEN Yanlong, LI Beigang. Preparation of Magnetic Amino Acid-Functionalized Aluminum Alginate Gel Polymer and its Super Adsorption on Azo Dyes[J]. 材料研究学报, 2022, 36(3): 220-230.
[5]	LONG Qing, WANG Chuanyang. Thermal Degradation Behavior and Kinetics Analysis of PMMA with Different Carbon Black Contents[J]. 材料研究学报, 2022, 36(11): 837-844.
[6]	JIANG Ping, WU Lihua, LV Taiyong, Pérez-Rigueiro José, WANG Anping. Repetitive Stretching Tensile Behavior and Properties of Spider Major Ampullate Gland Silk[J]. 材料研究学报, 2022, 36(10): 747-759.
[7]	YAN Jun, YANG Jin, WANG Tao, XU Guilong, LI Zhaohui. Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil[J]. 材料研究学报, 2021, 35(9): 651-656.
[8]	ZHANG Hao, LI Fan, CHANG Na, WANG Haitao, CHENG Bowen, WANG Panlei. Preparation of Carboxylic Acid Grafted Starch Adsorption Resin and Its Dye Removal Performance[J]. 材料研究学报, 2021, 35(6): 419-432.
[9]	SUN Liying, QIAN Jianhua, ZHAO Yongfang. Preparation and Performance of AgNWs -TPU/PVDF Flexible Film Capacitance Sensors[J]. 材料研究学报, 2021, 35(6): 441-448.
[10]	TANG Kaiyuan, HUANG Yang, HUANG Xiangzhou, GE Ying, LI Pinting, YUAN Fanshu, ZHANG Weiwei, SUN Dongping. Physicochemical Properties of Carbonized Bacterial Cellulose and Its Application in Methanol Electrocatalysis[J]. 材料研究学报, 2021, 35(4): 259-270.
[11]	SU Chenwen, ZHANG Tingyue, GUO Liwei, LI Le, YANG Ping, LIU Yanqiu. Preparation of Thiol-ene Hydrogels for Extracellular Matrix Simulation[J]. 材料研究学报, 2021, 35(12): 903-910.
[12]	ZHANG Xiangyang, ZHANG Qiyang, ZHENG Tao, TANG Tao, LIU Hao, LIU Guojin, ZHU Hailin, ZHU Haifeng. Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes[J]. 材料研究学报, 2021, 35(11): 866-872.
[13]	WAN Liying, XIAO Yang, ZHANG Lunliang. Preparation and Properties of PU-DA System Based on Thermoreversible Diels-Alder Dynamic Covalent Bond[J]. 材料研究学报, 2021, 35(10): 752-760.
[14]	ZHANG Cuige, HU Liang, LU Zuxin, ZHOU Jiahui. Preparation and Emulsification Properties of Self-assembled Colloidal Particles Based on Alginic Acid[J]. 材料研究学报, 2021, 35(10): 761-768.
[15]	HUANG Jian, LIN Chunxiang, CHEN Ruiying, XIONG Wanyong, WEN Xiaole, LUO Xin. Ionic Liquid-assisted Synthesis of Nanocellulose Adsorbent and Its Adsorption Properties[J]. 材料研究学报, 2020, 34(9): 674-682.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed