High Temperature Oxidation Performance of a Nb and Ti Stabilized 430 Ferritic Stainless Steel

doi:10.11901/1005.3093.2014.126

Chinese Journal of Materials Research

2014, Vol. 28

Issue (9): 641-648 DOI: 10.11901/1005.3093.2014.126

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High Temperature Oxidation Performance of a Nb and Ti Stabilized 430 Ferritic Stainless Steel

Xunzeng HUANG,Yitao YANG(

)

School of Materials Science and Engineering, Shanghai University, Shanghai 200072

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Xunzeng HUANG,Yitao YANG. High Temperature Oxidation Performance of a Nb and Ti Stabilized 430 Ferritic Stainless Steel. Chinese Journal of Materials Research, 2014, 28(9): 641-648.

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Abstract

High temperature oxidation performance of an Nb-Ti-stabilized 430 ferritic stainless steel (NTS430FSS) and SUS 430 ferritic stainless steel (SUS430FSS) was comparatively investigated by means of isothermal oxidation test, metallographic observation, scanning electron microscope (SEM) along with chemical microanalysis by energy dispersive spectrometry (EDS) and X-ray diffraction analysis. The results show that the oxidation weight gain was reduced for the steel with Nb and Ti addition. And the oxidation activation energies were 72.6 kJ/mol and 121.6 kJ/mol for the steel without and with Nb and Ti addition respectively. The adhesion between the oxide scale and matrix was enhanced by titanium oxide which dopped into the oxide scale. As a result, the Nb-Ti-stabilized 430 ferritic stainless steel exhibited better high temperature oxidation resistance.

Key words: metallic materials ferritic stainless steel high temperature oxidation performance Nb-Ti-stabilized microstructure

Received: 19 March 2014

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.126 OR https://www.cjmr.org/EN/Y2014/V28/I9/641

Table 1 Chemical composition of the investigated ferritic stainless steel (mass fraction, %)

Fig.1 Oxidation kinetics curves at 800℃, 900℃ and 1000℃, respectively

Fig.2 Thickness of oxide layer oxidized at 800℃, 900℃ and 1000℃ for 120 h

Table 2 k_p and oxidation activation energy Q of the two experimental steel at 800℃, 900℃ and 1000℃

Fig.3 SEM images of SUS430FSS (a-c) and NTS430FSS (d- f) oxidized at 800℃ (a, d), 900℃ (b, e) and 1000℃ (c, f) for 120 h

Fig.4 Microstructure of NTS430FSS (a-c) and SUS430FSS (d-f) of matrix (a, d) and oxide layer oxidized at 800℃ (b, e) and 1000℃ (c, f) for 120 h

Fig.5 EDS spectra of oxide particles on the surface of NTS430FSS (a) and SUS430FSS (b) oxidized for 120 h

Fig.6 XRD spectra of NTS430FSS after oxidation for 120 h at 800℃ (a), 900℃ (b) and 1000℃ (c)

Fig.7 XRD spectra of SUS430FSS after oxidation for 120 h at 800℃ (a), 900℃ (b) and 1000℃ (c)

Fig.8 SEM images of surface cross-section of NTS430FSS (a- c) and SUS430FSS (d- f) oxidized for 120 h at 800℃ (a, d), 900℃ (b, e) and 1000℃ (c, f)

Fig.9 EDS spectra of surface cross-section during 120 h at 1000℃

Fig.10 Schematic presentation of oxide coating (a) NTS430FSS-800℃×120 h, (b) NTS430FSS-1000℃×120 h, (c) SUS430FSS-800℃×120 h, (d) SUS430FSS-1000℃×120 h

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