Facile Synthesis of Ordered Ethane-Bridged Hybrid Mesostructures Assisted by ZrOCl2–NaCl Salt Pair

Chin J Mater Res

2010, Vol. 24

Issue (4): 419-423 DOI:

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Facile Synthesis of Ordered Ethane-Bridged Hybrid Mesostructures Assisted by ZrOCl₂–NaCl Salt Pair

ZHAI Bin， ZHAO Jixiang， ZHAI Shangru， AN Qingda， CHEN Chuandong， SONG Yu

Faculty of Chemical Engineering and Material, Dalian Polytechic University, Dalian 116034

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ZHAI Bin ZHAO Jixiang ZHAI Shangru AN Qingda CHEN Chuandong SONG Yu. Facile Synthesis of Ordered Ethane-Bridged Hybrid Mesostructures Assisted by ZrOCl₂–NaCl Salt Pair. Chin J Mater Res, 2010, 24(4): 419-423.

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Abstract

Structurally ordered ethane-bridged periodic mesoporous organosilicas (PMOs) have been facilely prepared with the assistance of ZrOCl₂–NaCl salt pair using nonionic P123 (EO₂₀PO₇₀EO₂₀) as the structure-directing agent, and was thoroughly characterized by advanced techniques as such SAXS, HRTEM, N₂–adsorption/desorption isotherms and solid state ¹³C CP/²⁹Si CP MAS NMR etc.. The results indicated that the present material possess highly ordered hexagonal structure and organic-inorganic hybrid network, and thus illustrating the effective function of salt pair in the assembly of PMO material under the studied synthesis system.

Key words: foundational discipline in materials science hybrid material mesostructure ethane self-assembly

Received: 01 April 2010

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TB321

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Supported by National Nature Science Foundation of China No.20901012.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2010/V24/I4/419

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