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Chin J Mater Res  2004, Vol. 18 Issue (4): 352-356    DOI:
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Oxidation of Ag--Cr alloys prepared by powder metallurgy in 0.1 MPa O{2}
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宋尽霞110015 沈阳 中科院金属研究所
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. Oxidation of Ag--Cr alloys prepared by powder metallurgy in 0.1 MPa O{2}. Chin J Mater Res, 2004, 18(4): 352-356.

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Abstract  The oxidation behavior of powder metallurgical Ag--Cr ~alloys ~at ~700 and 800℃ ~in ~0.1~MPa O{2} was studied. PM Ag--35Cr alloy formed complex scale including silver metal, Cr$_{2}$O$_{3}$, AgCrO$_{2}$ and internal oxidation zone of chromium. A continuous layer of Cr$_{2}$O$_{3}$ under an external layer of AgCrO$_{2}$ formed on the PM Ag--69Cr alloy. The internal oxidation of chromium was suppressed in this alloy. The oxidation of PM Ag--Cr alloys was strongly affected by the restriction to chromium diffusion due to the presence of two phases and by the relatively large size of the chromium particles, which restrained the formation of exclusive Cr$_{2}$O$_{3}$ scales which restrained the formation of exclusive Cr$_{2}$O$_{3}$ scales at the chromium contents 69\%. The appearance of pure silver on the PM Ag--35Cr alloy was a result of the stress resulting from large volume change caused by internal oxidation.
Key words:  metallic materials      powder metallurgy(PM)      oxidation      Ag-Cr alloy      
Received:  31 August 2004     
ZTFLH:  TG174  
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https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2004/V18/I4/352

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