Preparation of Nitrogen and Phosphorus Co-doped Graphene Oxide and Corrosion Resistance of Waterborne Composite Coatings NPGO/Epoxy Resin

doi:10.11901/1005.3093.2023.498

Chinese Journal of Materials Research

2024, Vol. 38

Issue (11): 861-871 DOI: 10.11901/1005.3093.2023.498

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Preparation of Nitrogen and Phosphorus Co-doped Graphene Oxide and Corrosion Resistance of Waterborne Composite Coatings NPGO/Epoxy Resin

LI Yufeng¹^,²(

), FENG Feng¹, LIU Shibo¹, LIU Lishuang¹, GAO Xiaohui¹

1 College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
2 College of Light Industry and Textile, Qiqihar University, Qiqihar 161006, China

Cite this article:

LI Yufeng, FENG Feng, LIU Shibo, LIU Lishuang, GAO Xiaohui. Preparation of Nitrogen and Phosphorus Co-doped Graphene Oxide and Corrosion Resistance of Waterborne Composite Coatings NPGO/Epoxy Resin. Chinese Journal of Materials Research, 2024, 38(11): 861-871.

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Abstract

N and P co-doped graphene oxide (NPGO) was prepared by low temperature solution method with graphene oxide (GO) as raw material, phytic acid (PA) as P source, and aqueous ammonia solution (NH₃·H₂O) as N source, and then, N and P co-doped graphene/epoxy resin (NPGO/EP) waterborne composite coating was prepared by using waterborne epoxy resin (EP) as the film former. The structure and morphology of NPGO were characterized by FTIR, XPS, XRD, SEM and TEM. The corrosion resistance of composite coatings was assessed by contact angle measurement, electrochemical measurement and salt spray test. The results show that NPGO/EP composite coating has better metal protection effect than pure EP coating, GO/EP composite coating, as well as single P doped graphene/epoxy resin (PGO/EP) composite coating and single N doped graphene/epoxy resin (NGO/EP) composite coating. NPGO/EP composite coating showing good corrosion resistance when the addition amount of NPGO is 1.5% (mass fraction): the electrochemical impedance reaches 4.85 × 10⁸ Ω·cm², and slight rust marks appear only after 480 h of salt spray test.

Key words: materials failure and protection corrosion resistance nitrogen-phosphorus graphene waterborne epoxy resin composite coating

Received: 11 October 2023

ZTFLH:

TB304

Fund: Fundamental Research Funds in Heilongjiang Provincial Universities(135509128)

Corresponding Authors: LI Yufeng, Tel: 15145240877, E-mail: lyf1170@163.com

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	LI Yufeng
	FENG Feng
	LIU Shibo
	LIU Lishuang
	GAO Xiaohui

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https://www.cjmr.org/EN/10.11901/1005.3093.2023.498 OR https://www.cjmr.org/EN/Y2024/V38/I11/861

Fig.1 Schematic illustration of the synthesis route of NPGO

Table 1 Amounts of graphene for different types of composite coatings

Fig.2 FTIR spectra of GO, PGO and NPGO

Fig.3 XPS spectra of NPGO

Fig.4 XRD patterns of GO、PGO and NPGO

Fig.5 SEM images of GO (a)、PGO (b) and NPGO (c)

Fig.6 TEM images of GO (a), PGO (b) and NPGO (c)

Fig.7 Variations of the contact angle and water absorption of the composite coating with the content of NPGO

Fig.8 Effects of various fillers on the adhesion strength of the composite coating

Fig.9 (a) Nyquist and (b) Bode plots of EP, GO/EP, NGO/EP, PGO/EP, NPGO/EP coatings after immersion in 3.5%NaCl solution for 24 h

Table 2 Fitted data of EIS in Fig.9

Fig.10 Equivalent circuit model for fitted EIS of various coatings

Fig.11 (a, c, e, g) Nyquist and (b, d, f, h) Bode plots of NPGO/EP composite coatings with different contents of NPGO after immersion in 3.5%NaCl solution for (a, b) 24 h, (c, d) 240 h, (e, f) 480 h, (g, h) 720 h

Fig.12 Macro-photos of (a) EP, (b) GO/ EP, (c) NGO/EP, (d) PGO/EP, (e) 0.5%NPGO/EP, (f) 1.0%NPGO/EP, (g) 1.5%NPGO/EP and (h) 2.0%NPGO/EP coatings after salt spray test for different time

Fig.13 Schematic diagram of corrosion resistant mechanism of NPGO/EP composite coating

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