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| Preparation of Double-layer Carbon Coated Na3V2(PO4)3 as Cathode Material for Sodium-ion Batteries by Ultrasonic-assisted Solution Combustion and Its Electrochemical Performance |
LUO Yu, CHEN Qiuyun, XUE Lihong( ), ZHANG Wuxing, YAN Youwei |
| State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong Universtiy of Scienc and Technology, Wuhan 430074, China |
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Cite this article:
LUO Yu, CHEN Qiuyun, XUE Lihong, ZHANG Wuxing, YAN Youwei. Preparation of Double-layer Carbon Coated Na3V2(PO4)3 as Cathode Material for Sodium-ion Batteries by Ultrasonic-assisted Solution Combustion and Its Electrochemical Performance. Chinese Journal of Materials Research, 2023, 37(2): 129-135.
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Abstract Double-layer carbon coated Na3V2(PO4)3 (NVP), as cathode material for sodium-ion batteries, was successfully synthesized by ultrasonic-assisted solution combustion synthesis, and its structure, morphology and electrochemical properties were investigated. The results show that the surface of NVP particles is firstly coated with an amorphous hard carbon layer, subsequently with a graphene layer. When the graphene content is 5.0%, the carbon-coated NVP composite exhibits excellent electrochemical properties. It delivers an initial discharge capacity of 117 mAh·g–1 at 1 C, and retains 79% of the initial capacity after 300 cycles. Even at 10 C, it still maintains a discharge capacity as high as 100 mAh·g–1. The significant improvement of the sodium storage performance can be ascribed to the special structure of homogeneous double-layer carbon coating, which can act as a 3-dimentional network as electron pathway.
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Received: 28 September 2021
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| Fund: National Key Research and Development Program of China(2016YFB0100302) |
About author: XUE Lihong, Tel: 13667116231，E-mail: xuelh@hust.edu.cn
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