Preparation and Electrochemical Performance of rGO/PANI/MnO2 Ternary Composites

doi:10.11901/1005.3093.2021.431

Chinese Journal of Materials Research

2022, Vol. 36

Issue (7): 552-560 DOI: 10.11901/1005.3093.2021.431

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Preparation and Electrochemical Performance of rGO/PANI/MnO₂ Ternary Composites

LIU Yanyun(

), LIU Yutao, LI Wanxi

Department of Materials Science and Engineering, Jinzhong University, Jinzhong 030619, China

Cite this article:

LIU Yanyun, LIU Yutao, LI Wanxi. Preparation and Electrochemical Performance of rGO/PANI/MnO₂ Ternary Composites. Chinese Journal of Materials Research, 2022, 36(7): 552-560.

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Abstract

Graphene/polyaniline/manganese dioxide ternary composites (rGO/PANI/MnO₂) were prepared by hydrothermal method, followed by freeze-dried in vacuum treatment in this paper. The composites prepared by this simple and efficient method had self-supporting properties. The composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The results show that the prepared ternary composites had an interconnected network structure. During the reaction MnO₂ and polyaniline formed an irregular block structure and co-deposited on the network layer formed by graphene self-assembly. The composite electrode showed good capacitive properties, with a specific capacitance of 388 F·g^-1 (0.5 A·g^-1), which was better than that of graphene (rGO, 234 F·g^-1) and polyaniline (PANI, 176 F·g^-1). In addition, an asymmetric supercapacitor was assembled using the composite as the positive electrode and rGO as the negative electrode. The asymmetric capacitor could be reversibly cycled in the range of 0~1.6 V. When the power density was 17.48 W·kg^-1, the maximum energy density could reach 13.5 Wh·kg^-1.

Key words: composite graphene hydrothermal method electrochemical properties

Received: 13 August 2021

ZTFLH:

TB383

Fund: Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2020L0576);Shanxi “1331 Project” Key Innovative Research Team(PY201817);Jinzhong University “1331 Project” Key Innovative Research Team(jzxycxtd2019005);Collaborative Innovation Center for the Modified Application of Lightweight Materials(jzxyxtcxzx202103)

About author: LIU Yanyun, Tel: 15698402116, E-mail: 312217642@qq.com

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.431 OR https://www.cjmr.org/EN/Y2022/V36/I7/552

Fig.1 XRD patterns of rGO/PANI/MnO₂, GO and rGO

Fig.2 XPS spectra of rGO/PANI/MnO₂-3 (a) survey, (b) Mn2p, (c) N1s and (d) C1s

Fig.3 SEM images of the rGO/PANI/MnO₂-3

Fig.4 CV curves of rGO、PANI and rGO/PANI/MnO₂-3 at 2 mV/s (a), CP curves of rGO、PANI and rGO/PANI/MnO₂-3 at 0.2 A·g^-1 (b), EIS curve of rGO、PANI and rGO/PANI/MnO₂-3 (c), and inset shows the high-frequency region of the plot

Fig.5 CV curves of the three composites at 2 mV/s (a), CV curves of rGO/PANI/MnO₂-3 at different scan rates (b), the capacitive contribution at a scan rate of 5 mV/s (c), the ratio of capacitive effects and diffusion controlled contributions at different scan rates (d)

Fig.6 CP curves of the three composites at 0.2 A·g^-1 (a), CP curves of rGO/PANI/MnO₂-3 under different current densities (b), the relationships between C_e and current densities of rGO/PANI/MnO₂-3 (c) and EIS curve of the three composites (d)

Fig.7 CV curves of asymmetric supercapacitor at different potential windows at 100 mV/s (a), CV curves of asymmetric supercapacitor at different scan rates (b), CP curves of asymmetric supercapacitor at different potential windows at 1 A·g^-1 (c), CP curves of asymmetric supercapacitor under different current densities (d), Ragone plots of the energy density versus power density for asymmetric supercapacitors (e) and Cycling life of asymmetric supercapacitors at 0.5 A·g^-1 (f)

1	Li H X, Lang J W, Lei S L, et al. A high-performance sodium-ion hybrid capacitor constructed by metalorganic framework-derived anode and cathode materials [J]. Adv. Funct. Mater., 2018, 28: 1800757 doi: 10.1002/adfm.201800757
2	Wang B, Zhao J, Zhang D H, et al. Three-dimensional porous carbon framework coated with one-dimensional nanostructured polyaniline nanowires composite for high performance supercapacitors [J]. Appl. Surf. Sci., 2019, 474: 147 doi: 10.1016/j.apsusc.2018.04.057
3	Lian C, Janssen M, Liu H R, et al. Blessing and curse: how a supercapacitor's large capacitance causes its slow charging [J]. Phys. Rev. Lett., 2020, 124: 076001
4	Chao D, Liang P, Chen Z, et al. Pseudocapacitive Na-ion storage boosts high-rate and areal capacity of self-branched 2D layered metal chalcogenide nanoarrays [J]. ACS Nano, 2016, 10: 10211 doi: 10.1021/acsnano.6b05566
5	Li A J, Chuan X Y, Huang D B, et al. KOH activation of diatomite-templated carbon and its electrochemical property in supercapacitor [J]. Chin. J. Mater. Res., 2017, 31: 321
	李爱军, 传秀云, 黄杜斌等. KOH活化硅藻土模板炭及其电化学性能研究 [J]. 材料研究学报, 2017, 31: 321 doi: 10.11901/1005.3093.2016.366
6	Geim A K. Graphene: Status and prospects [J]. Science, 2009, 324: 1530 doi: 10.1126/science.1158877 pmid: 19541989
7	El-Kady M F, Strong V, Dubin S, et al. Laser Scribing of high-performance and flexible graphene-based electrochemical capacitors [J]. Science, 2012, 335: 1326 doi: 10.1126/science.1216744 pmid: 22422977
8	Zhu Y, Murali S, Stoller M D, et al. Carbon-based supercapacitors produced by activation of graphene [J]. Science, 2011, 332: 1537 doi: 10.1126/science.1200770
9	Shaikh S F, Shaikh F F M, Shaikh A V, et al. Electrodeposited more-hydrophilic nano-nest polyaniline electrodes for supercapacitor application [J]. J. Phys. Chem. Solid., 2021, 149: 109774 doi: 10.1016/j.jpcs.2020.109774
10	Zhao J, Zhu B, Yang G, et al. Vacuum annealed MnO₂ ultra-thin nanosheets with oxygen defects for high performance supercapacitors [J]. J. Phys. Chem. Solid., 2021, 150: 109856 doi: 10.1016/j.jpcs.2020.109856
11	Kakaei K, Khodadoost S, Gholipour M, et al. Core-shell polyaniline functionalized carbon quantum dots for supercapacitor [J]. J. Phys. Chem. Solids, 2021, 148: 109753 doi: 10.1016/j.jpcs.2020.109753
12	Zhu S Z, Tang G X, Wang J, et al. Preparation and capacitance properties of polyaniline/carbon microcoil composites [J]. Chin. J. Mater. Res., 2016, 30: 186
	朱士泽, 唐国霞, 王健等. 聚苯胺/碳螺旋纤维复合材料的合成及其电容特性研究 [J], 材料研究学报, 2016, 30: 186 doi: 10.11901/1005.3093.2015.361
13	Pal R, Goyal S L, Rawal I, High-performance solid-state supercapacitors based on intrinsically conducting polyaniline/MWCNTs composite electrodes [J]. J. Polym. Res., 2020, 27: 179 doi: 10.1007/s10965-020-02144-y
14	Ge M, Hao H, Lv Q, et al. Hierarchical nanocomposite that coupled nitrogen-doped graphene with aligned PANI cores arrays for high-performance supercapacitor [J]. Electrochim. Acta, 2020, 330: 135236 doi: 10.1016/j.electacta.2019.135236
15	Pal R, Goyal S L, Rawal I, Transition of charge transport phenomena from 3D to 1D hopping at low temperatures in polyaniline/graphene composites[J]. J. Appl. Phys., 2020, 128: 175108 doi: 10.1063/5.0020745
16	Viswanathan A, Shetty A N, Effect of dopants on the energy storage performance of reduced graphene oxide/polyaniline nanocomposite[J]. Electrochim. Acta, 2019, 327: 135026 doi: 10.1016/j.electacta.2019.135026
17	Li J, Xiao D, Ren Y, et al. Bridging of adjacent graphene/polyaniline layers with polyaniline nanofibers for supercapacitor electrode materials [J]. Electrochim. Acta, 2019, 300: 193 doi: 10.1016/j.electacta.2019.01.089
18	Ahirrao D J, Mohanapriya K, Wilson H M, et al. Solar reduced porous graphene incorporated within polyaniline network for high-performance supercapacitor electrode [J]. Appl. Surf. Sci., 2020, 510: 145485 doi: 10.1016/j.apsusc.2020.145485
19	Yu H, Ge X, Bulin C, et al. Facile fabrication and energy storage analysis of graphene/PANI paper electrodes for supercapacitor application [J]. Electrochim. Acta, 2017, 253: 239 doi: 10.1016/j.electacta.2017.09.071
20	Li J, Xie H, Li Y, et al. Electrochemical properties of graphene nanosheets/polyaniline nanofibers composites as electrode for supercapacitors [J]. J. Power Sources, 2011, 196: 10775 doi: 10.1016/j.jpowsour.2011.08.105
21	Xu Y, Schwab M G, Strudwick A J, et al. Screen printable thin film supercapacitor device utilizing graphene/polyaniline inks [J]. Adv. Energy Mater., 2013, 3: 1035 doi: 10.1002/aenm.201300184
22	Song N, Wang W, Wu Y, et al. Fabrication of highly ordered polyaniline nanocore on pristine graphene for high-performance supercapacitor electrodes [J]. J. Phys. Chem. Solid., 2018, 115: 148 doi: 10.1016/j.jpcs.2017.12.022
23	Liu L, Lang J W, Zhang P, et al. Facile synthesis of Fe₂O₃ nano-dots@nitrogen-doped graphene for supercapacitor electrode with ultralong cycle life in KOH electrolyte [J]. ACS Appl. Mater. Interfaces, 2016, 8: 9335 doi: 10.1021/acsami.6b00225
24	Chauhan N P S, Mozafari M, Chundawat N S, et al. High-performance supercapacitors based on polyaniline-graphene nanocomposites: some approaches, challenges and opportunities [J]. J. Industrial Eng. Chem., 2016, 36: 13 doi: 10.1016/j.jiec.2016.03.003
25	Zhang J M, Zhang Y, Yuan J, et al. High rate capability electrode from a ternary composite of nanodiamonds/reduced graphene oxide@PANI for electrochemical capacitors [J]. Chem. Phys., 2019, 526: 110461 doi: 10.1016/j.chemphys.2019.110461
26	Liu Y Y, Ma L, Chen Y Q, A simple one-step approach for preparing flexible rGO-MnO 2 electrode material [J]. J. Mater. Sci.: Mater. Electron., 2018, 29: 17438 doi: 10.1007/s10854-018-9843-0
27	Liu Y Y, Ma L, Zhang D, et al. A simple route to prepare a Cu₂O-CuO-GN nanohybrid for high-performance electrode materials [J]. RSC Advances, 2017, 7: 12027 doi: 10.1039/C6RA26535A
28	Wang G X, Tang Q Q, Bao H, et al. Synthesis of hierarchical sulfonated graphene/MnO₂/polyaniline ternary composite and its improved electrochemical performance [J]. J. Power Sources, 2013, 241: 231 doi: 10.1016/j.jpowsour.2013.04.122
29	Peng H R, Lv S S, Li G C. Preparation and characterization of graphene/SnO₂/polyaniline nano-composites [J]. J Qingdao Tech. Univ. 2011, 32: 6
	彭红瑞, 吕莎莎, 李桂村. 石墨烯/SnO₂/聚苯胺纳米复合材料的制备与表征 [J]. 青岛理工大学学报, 2011, 32: 6
30	Liu Z, Chen W L, Fan Xin, Preparation of 3D MnO₂/polyaniline/graphene hybrid material via interfacial polymerization as high-performance supercapacitor electrode [J]. Chin. J. Chem., 2016, 34: 839 doi: 10.1002/cjoc.201600217
31	Fu S N, Ma L, Gan M Y, 3D reduced graphene oxide/MnO₂/polyaniline composite for high-performance supercapacitor [J]. J Mater Sci: Mater Electron, 2017, 28: 3621 doi: 10.1007/s10854-016-5964-5
32	Chigane M, Ishikawa M, Manganese oxide thin film preparation by potentiostatic electrolyses and electrochromism [J]. J. Electrochem. Soc., 2000, 147: 2246 doi: 10.1149/1.1393515
33	Jayaramulu K., Horn M., Schneemann A., et al. Covalent graphene-MOF hybrids for high-performance asymmetric supercapacitors [J]. Adv. Mater., 2021, 33: 2004560 doi: 10.1002/adma.202004560
34	Brezesinski T., Wang J., Tolbert S. H., et al. Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors [J]. Nat. Mater., 2010, 9: 146 doi: 10.1038/nmat2612 pmid: 20062048
35	Shen K. X., Chen H. D., Qin H. Q., et al. Construct pseudo-capacitance of a fexible 3D-entangled carbon nanofber flm as freestanding anode for dual-ion full batteries [J]. J Mater Sci: Mater Electron, 2020, 31: 10962 doi: 10.1007/s10854-020-03587-1

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