Synthesis and Performance of a Novel Aromatic Amine Curing Agent for Epoxy Resin

doi:10.11901/1005.3093.2014.031

Chinese Journal of Materials Research

2014, Vol. 28

Issue (9): 715-720 DOI: 10.11901/1005.3093.2014.031

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Synthesis and Performance of a Novel Aromatic Amine Curing Agent for Epoxy Resin

Xuhai XIONG¹,Siyang LIU¹,Ping CHEN^1,^2,^**(

),Fang LU²,Rong REN¹

1. Liaoning Key Laboratory of Advanced Polymer Matrix Composites Manufacturing Technology, Faculty of Aerospace Engineering, Shenyang Aerospace University, Shenyang 1101362.
2. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024

Cite this article:

Xuhai XIONG,Siyang LIU,Ping CHEN,Fang LU,Rong REN. Synthesis and Performance of a Novel Aromatic Amine Curing Agent for Epoxy Resin. Chinese Journal of Materials Research, 2014, 28(9): 715-720.

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Abstract

A new curing agent (PBMI-DDE) for epoxy resin was synthesized from phthalide-containing bismaleimide (PBMI) and aromatic amine (DDE) according to the Michael addition reaction. The chemical structure of PBMI-DDE was characterized by ¹H NMR spectroscopy and Fourier transform infrared spectroscopy (FTIR). The curing performance and kinetics of E-51/ PBMI-DDE was studied by DSC. Apparent activation energy evaluated according to Kissinger model or FWO model is 46.7 or 49.1 kJ/mol, respectively, and the calculated reaction order is 0.88 based on Crane method. The DMA and TGA results show that the cured resin possesses excellent thermostability with a glass transition temperature 153℃ for the completely cured resin.

Key words: organic polymer materials aromatic amine epoxy resin Michael addition reaction cure kinetics

Received: 14 January 2014

Fund: *Supported by National Natural Science Foundation of China No. 51303107, National Defense 12-5 year Fundamental Research Program No.A352******* and Excellent Talent Project of Liaoning Provincial Education Department No. LR2013002.

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	Xuhai XIONG
	Siyang LIU
	Ping CHEN
	Fang LU
	Rong REN

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.031 OR https://www.cjmr.org/EN/Y2014/V28/I9/715

Fig.1 Synthesis route of PBMI-DDE

Fig.2 FTIR spectra of PBMI- DDE and PBMI

Fig.3 ¹H NMR spectra of PBMI-DDE

Fig.4 DSC curves of E-51/ PBMI-DDE system at different heating rates

Table 1 Curing characteristics of E-51/ PBMI-DDE systems at different heating rates

Fig.5 Relationship of T and β

Fig.6 Plots of ln(β/T_P²)and lnβ versus 1000/T_p

Fig.7 Flynn-Wall- Ozawa analysis curve

Fig.8 DMA thermograph of cured E-51/ PBMI-DDE system.(a) the first scanning, (b) the second scanning

Fig.9 TG and DTG curves of cured E-51/ PBMI-DDE system

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