Effect of OMMT on Morphology and Property of PTT/ASA Blends

doi:10.11901/1005.3093.2013.748

Chinese Journal of Materials Research

2014, Vol. 28

Issue (2): 107-113 DOI: 10.11901/1005.3093.2013.748

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Effect of OMMT on Morphology and Property of PTT/ASA Blends

Jun CHEN¹,Qinghua CHEN^2,³,Qingrong QIAN^2,³,Baoquan HUANG^2,³,Xinping LIU^2,³,Jing XU^2,³,Liren XIAO^1,^**(

)

1. College of Materials Science and Engineering, Fujian Normal University, Fuzhou, 350007
2. College of Environmental Science and Engineering, Fujian Normal University, Fuzhou, 350007
3. Fujian Key Laboratory of Pollution Control & Resource Reuse, Fuzhou, 350007

Cite this article:

Jun CHEN,Qinghua CHEN,Qingrong QIAN,Baoquan HUANG,Xinping LIU,Jing XU,Liren XIAO. Effect of OMMT on Morphology and Property of PTT/ASA Blends. Chinese Journal of Materials Research, 2014, 28(2): 107-113.

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Abstract

Nanocomposites of poly(trimethylene-terephthalate)/poly(acrylonitrile-styrene-acrylate)/organic montmorillonite (PTT/ASA/OMMT) were prepared by means of melt-blending intercalation. The effect of OMMT contents on the phase morphology, crystallization behavior, rheological- and mechanical-properties were investigated. The results show that the size of dispersed phases decreases with increasing OMMT content. The crystallization peak shifts to high temperature and melting peak moves to low temperature owing to the heterogeneous nucleation of OMMT. The exfoliated OMMT is located in the PTT matrix and at interface of PTT/ASA phases The rheological measurements show that the elastic modulus and complex viscosity increase with increasing OMMT content. The interfacial modulus and interfacial layer thickness predicted by Palierne and Gramspacher-Meissner models are enhanced by introduction of OMMT. The tensile strength and notched impact strength of blends increase with increasing OMMT content.

Key words: organic polymer materials PTT/ASA blends OMMT morphology rheology mechanical property

Received: 10 October 2013

Fund: *Supported by the Natural Science Foundation of Fujian Province Nos. 2011J01287 & 2012J01195.

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	Jun CHEN
	Qinghua CHEN
	Qingrong QIAN
	Baoquan HUANG
	Xinping LIU
	Jing XU
	Liren XIAO

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https://www.cjmr.org/EN/10.11901/1005.3093.2013.748 OR https://www.cjmr.org/EN/Y2014/V28/I2/107

Fig.1 SEM images for PTT/ASA/OMMT blends (a) 70/30/0; (b) 70/30/0.5; (c) 70/30/1; (d) 70/30/1.5; (e) 70/30/2; (f) 70/30/2.5

Fig.2 DSC curves for PTT/ASA/OMMT blends (a) cold-crystallization; (b) second-melting

Table 1 DSC analyses for PTT/ASA/OMMT blends

Fig.3 XRD spectra for OMMT, PTT, PTT/ASA and PTT/ASA/OMMT blends, (a) small angle X-ray diffraction; (b) wide angle X-ray diffraction

Fig.4 Curves of dynamic frequency sweep for PTT/ASA/OMMT blends (a) G′ vs ω; (b) η^* vs ω

Fig.5 Han plots for PTT/ASA/OMMT blends

Fig.6 Weighted relaxation spectrum polts for PTT/ASA/OMMT blends

Fig.7 Estimation of linear viscoelastic properties by Palierne and Gramspacher-Meissner models for PTT/ASA/OMMT blends, (a) 70/30/0; (b) 30/70/0.5

Fig.8 Curves of mechanical property for PTT/ASA/OMMT blends

1	WU Youping,ZHANG Liqun, WANG Yizhong, WANG Yiqing, SUN Zhaohui, ZHANG Huifeng, YU Dingsheng, Study on structure-properties of clay/xnbr nanocomposites, Chinese Journal of Materials Research, 14(2), 188(2000)
1	(吴友平, 张立群, 王一中, 王益庆, 孙朝晖, 张慧峰, 余鼎声, 粘土/羧基丁腈橡胶纳米复合材料的结构和性能研究, 材料研究学报, 14(2), 188(2000))
2	Y. Li, H. Shimizu,Co-continuous polyamide 6 (PA6)/acrylonitrile-butadiene- styrene (ABS) nanocomposites, Macromolecular Rapid Communications, 26(9), 710(2005)
3	Y. Yoo, C. Y. Park, S. G. Lee, K. Y. Choi, D. S. Kim, J. H. Lee,Influence of addition of organoclays on morphologies in nylon 6/LLDPE blends, Macromolecular Chemistry and Physics, 206(8), 878(2005)
4	Y. Tang, M. Lewin,Maleated polypropylene OMMT nanocomposite: annealing, structural changes, exfoliated and migration, Polymer Degradation and Stability, 92(1), 53(2007)
5	B. B. Khatua, D. J. Lee, H. Y. Kim, J. K. Kim,Effect of organoclay platelets on morphology of nylon-6 and poly(ethylene-ran-propylene)rubber blends, Macromolecules, 37(7), 2454(2004)
6	BAI Maojuan,LIU Yan, XIAO Fengyan, ZHANG Jun, Characteristics of fire residues of HIPS/OMMT nanocomposites formed during cone calorimeter tests, Acta Polymerica Sinica, (5), 539(2012)
6	(白卯娟, 刘岩, 肖凤艳, 张军, HIPS/OMMT纳米复合材料的燃烧性能与其残余物炭层结构特征研究, 高分子学报, (5), 539(2012))
7	W. S. Chow, Z. A. Mohd Ishak, Mechanical morphological and rheological properties of polyamide 6 organo-montmorillonite nanocomposites, Express Polymer Letters, 1(2), 77(2007)
8	HONG Haoqun,HE Hui, DING Chao, JIA Demin, Effect of compound organification of montmorillonite on the structure and properties of polypropylene/montmorillonite nanocomposites, Chinese Journal of Materials Research, 20(2), 197(2006)
8	(洪浩群, 何慧, 丁超, 贾德民, 聚丙烯/蒙脱土纳米复合材料的结构与性能, 材料研究学报, 20(2), 197(2006))
9	D. M. Lincoln, R. A. Vaia, Z. G. Wang, B. S. Hsiao,Secondary structure and elevated temperature crystallite morphology of nylon-6/layered silicate nanocomposites, Polymer, 42(4), 1621(2001)
10	LIU Lan,LUO Yuanfang, JIA Demin, FU Weiwen, Preparation and properties of NR/montmorillonite nanocomposites, Chinese Journal of Materials Research, 20(1), 99(2006)
10	(刘岚, 罗远芳, 贾德民, 傅伟文, 天然橡胶/蒙脱土原土纳米复合材料的制备与性能, 材料研究学报, 20(1), 99(2006))
11	JIA Qingming,LI Jinbo, XU Changzheng, ZHU Jiewu, ZHENG Maosheng, Synergistic effect of polyurethane and organophilic montmorillonite on toughening and reinforcing epoxy resin, Chinese Journal of Materials Research, 21(2), 220(2007)
11	(贾庆明, 李金波, 徐长征, 朱杰武, 郑茂盛, 聚氨酯和蒙脱土协同增韧增强环氧树脂, 材料研究学报, 21(2), 220(2007))
12	HAO Xiangyang,LIU Jipin, TIAN Jun, FENG Shunshan, Advances in polymeric nano-composite research works, Polymer Materials Science and Engineering, 18(4), 38(2002)
12	(郝向阳, 刘吉平, 田军, 冯顺山, 聚合物基纳米复合材料的研究进展, 高分子材料科学与工程, 18(4), 38(2002))
13	K. Wang, Y. Chen, Y. Zhang,Preparation and mechanical properties of PTT/EPDM-g-MA/OMMT nanocomposites, Journal of Materials Engineering, S1, 122(2009)
14	M. T. Run, Q. C. Zhang, W. Zhou, Y. Zhong,Crystal morphology and thermal properties of PTT/POE/OMMT nanocomposites, Solid State Phenomena, 181-182, 39(2012)
15	M. T. Run, M. Yao, B. T. Xing, W. Zhou, Z. K. Wang,Preparation, morphology and properties of poly(trimethylene terephthalate)/maleinized poly(octene-ethylene)/organomontmorillonite nanocomposites, Journal of Thermoplastic Composite Materials, 1, 1(2013)
16	J. F. Palierne,Linear rheology of viscoelastic emulsions with interfacial tension, Rheologica Acta, 29(3), 204(1990)
17	H. Gramespacher, J. Meissner,Interfacial tension between polymer melts measured by shear oscillations of their blends, Journal of Rheology, 36(6), 1127(1992)
18	A. K. Gupta, V. B. Gupta, R. H. Peters, W. G. Harland, J. P. Berry,The effect of addition of high-density polyethylene on the crystallization and mechanical properties of polypropylene and glass-fiber-reinforced polypropylene, Journal of Applied Polymer Science, 27(12), 4669(1982)
19	YU Jie,YAN Wei, QIN Shu, LEI Jinfeng, HE Min, GUO Jianbing, The effect of SMA, OMMT on the morphology and mechanical properties of PA6/ABS blends, Acta Polymerica Sinica, (9), 896(2009)
19	(于杰, 严伟, 秦舒, 雷金锋, 何敏, 郭建兵, SMA, OMMT对PA6/ABS共混物聚集态结构及性能影响的研究, 高分子学报, (9), 896(2009))
20	P. D. Hong, W. T. Chung, C. F. Hsu,Crystallization kinetics and morphology of poly(trimethylene terephthalate), Polymer, 43(11), 3335(2002)
21	M. J. Solomom, A. S. Almusallam, K. F. Seefeldt,Rheology of polypropylene/clay hybrid materials, Macromolecules, 34(6), 1864(2001)
22	A. Sharif-Pakdaman, J. Morshedian, Y. Jahani,Effect of organoclay and silane grafting of polyethylene on morphology, barrierity, and rheological properties of HDPE/PA6 blends, Journal of Applied Polymer Science, 127(2), 1211(2013)
23	H. A. Khonakdar, P. Saen, A. Nodehi, S. H. Jafari, A. Asadinezhad, U. Wagenknecht, G. Heinrich,On rheology-morphology correlation of polypropylene/poly(trimethylene terephthalate) blend nanocomposites, Journal of Applied Polymer Science, 127(2), 1054(2013)

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