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Chinese Journal of Materials Research  2013, Vol. 27 Issue (5): 520-525    DOI:
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Characterization of Polyurethane / Polyhedral Oligomeric Silsesquioxanes (PU/POSS) Composites Fibers by Electrospinning Method
ZHOU Shengzhi1 SONG Xiaoyan1** CHENG Bowen2 CHENG Guoqing1 CHEN Tianjun1
1. College of Material Science and Engineering, Tianjin Polytechnic University, Tianjin 300387
2. Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University,
Tianjin 300387
Cite this article: 

ZHOU Shengzhi, SONG Xiaoyan, CHENG Bowen, CHENG Guoqing, CHEN Tianjun. Characterization of Polyurethane / Polyhedral Oligomeric Silsesquioxanes (PU/POSS) Composites Fibers by Electrospinning Method. Chinese Journal of Materials Research, 2013, 27(5): 520-525.

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Abstract  The effect of applied voltage, collecting distance and extrusion speed on morphology of polyurethane fiber were systematically investigated. Polyurethane/ polyhedral oligomeric silsesquioxanes (PU/POSS) fibers were spun by electrospinning method with the conditions of 8% solution, 6 mL/h extruding speed, 30 kV voltage and 15 cm distance. The effect of POSS on morphology, mechanical and thermal properties of polyurethane fiber was studied. The average diameters of PU/POSS composite fibers increase compared to the pure PU fibers. The onset temperature of decomposition and glass transition temperature of PU/POSS composite fiber respectively increase by 22℃ and 15℃ than pure PU fiber. The mechanical properties of PU/POSS composite fiber was improved compared with pure PU fiber.
Key words:  composites      polyurethane      POSS      composites fibers      electrospinning      thermal stability     
ZTFLH:  TS 102. 6  

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https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2013/V27/I5/520

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