|
|
|
| Effect of System of Nano–sized Mesoporous MCM–41–M/Coupling Agents on the Properties of Natural Rubber Composites |
| WANG Na, MI Long, JIANG Sen, ZHANG Jing, FANG Qinghong |
| School of Material Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142 |
|
Cite this article:
WANG Na MI Long JIANG Sen ZHANG Jing FANG Qinghong. Effect of System of Nano–sized Mesoporous MCM–41–M/Coupling Agents on the Properties of Natural Rubber Composites. Chin J Mater Res, 2012, 26(3): 289-294.
|
|
|
Abstract The nano–sized mesoporous MCM–41–M, chemical modification of MCM–41–M by coupling agents, and four different coupling agents were used to prepare natural rubber(NR) composites. The effects of content of nano–sized mesoporous MCM–41–M, the kinds of coupling agents, and adding method of coupling agent on the mechanical properties of the composites were investigated. The results show that the MCM–41–M has better reinforcing effects in the NR matrix. The tensile strength of the NR composites raised by 12.7% compared with pure NR when the content(mass fraction) of MCM–41–M is 3%. Compared with NR/MCM–41–M/KH–570, the tensile strength of NR/KH–570 modified MCM–41–M raised by 50%. NR/KH–570 modified MCM–41–M shows a higher glass transition temperature, lower tanδ peak value and higher storage modulus under all temperature regions.
|
|
Received: 12 January 2012
|
|
|
| Fund: Supported by National Natural Science Foundation of China Nos.51103086 & 51173110, and Distinguished Young Scholars of Liaoning Province Higher Growth Plans No.LJQ2011040. |
| 1 WANG Na, ZHAO Changli, SHI Zhaoxin, SHAO Yawei, LI Hongwei, GAO Na, Co–incorporation of MMT and MCM–41 nanomaterials used as fillers in PP composite, Materials Science and Engineering, B, 157(1), 44(2009)2 Y.Kojima, T.Matsuoka, H.Takahashi, Preparation of nylon 66/mesoporous molecular sieve composite under high pressure, Journal of Applied Polymer Science, 74(13), 3254 (1999)3 GU Yingying, LI Jiang, ZHAO Xinhua, WANG Liping, SHAN Yongkui, Synthesis of iron and vanadium iIncorporated SBA–15 molecular sieves and its catalysis for hydroxylation of benzene, Acta Chimica Sinica, 65(21), 2423(2007)(顾颖颖, 李 疆, 赵新华, 王莉萍, 单永奎, Fe_V取代SBA--15分子筛的合成及其对苯羟基化反应的催化, 化学学报, 65(21), 2423(2007))4 WANG Na, SHAO Yawei, SHI Zhaoxin, ZHANG Jing, LI Hongwei, Preparation and Characterization of epoxy composites filled with functionalized nano–sized MCM–41 particles, Journal of Materials Science, 43(10), 3683(2008)5 WANG Na, SHAO Yawei, SHI Zhaoxin, ZHANG Jing, LI Hongwei, Influence of MCM–41 particle on mechanical and morphological behavior of polypropylene, Materials Science and Engineering A, 497(1–2), 363(2008)6 WANG Na, FANG Qinghong, ZHANG Jing, CHEN Erfan, ZHANG Xiubin, Incorporation of nano–sized mesoporous MCM–41 material used as fillers in natural rubber composite, Materials Science and Engineering A, 528(9), 3321(2011)7 C.T.Kresge, M.E.Leonowicz, W.J.Roth, J.C.Vartuli, J.S.Beck, Ordered mesoporous molecular sieves synthesized by a liquid–crystal template mechanism, Nature, 359, 710(1992)8 WANG Na, GAO Na, LI Hongwei, FANG Qinghong, CHEN Erfan, Influence of different structural particle on the properties of PMMA composites, Acta Chimica Sinica, 68(8), 827(2010)(王 娜, 高 娜, 李洪伟, 方庆红, 陈尔凡, 不同结构颗粒对PMMA基复合材料性能影响, 化学学报, 68(8), 827(2010))9 LI Mingtian, WANG Na, WEI Wei, ZHANG Jinsong, Preparation and heat–resistance of PF/MCM–41 nanocomposite, Chinese Journal of Materials Research, 20(3), 314(2006)(李明天, 王 娜, 魏 巍, 张劲松, PF/MCM--41纳米复合材料的制备及其耐热性, 材料研究学报, 20(3), 314(2006))10 LIAO Bing, HUANG Yuhui, CONG Guangmin, Influence of modified wood fibers on the mechanical properties of wood fiber–reinforced polyethylene, Journal of Applied Polymer Science, 66(8), 1561(1997)11 ZHAO Dongyuan, HUO Qisheng, FENG Jianglin, Bradiey F. Chmelka, Galen D. Stucky, Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures, Journal of the American Chemical Society, 120(24), 6024(1998)12 LIANG Yan, ZHANG Jinsong, ZHANG Junqi, Role of surfactant on dispersing nanospherical MCM–41 mesoporous molecular sieves, Chinese Journal of Materials Research, 19(1), 23(2005)(梁 艳, 张军旗, 张劲松, 表面活性剂对纳米MCM--41分子筛分散性的影响, 材料研究学报, 19(1), 23(2005))13 LUO Yongming, HOU Zhaoyin, ZHENG Xiaoming, Rapid synthesis of SBA–15 molecular sieves in low concentration liquid acid media, Acta Chimica Sinica, 65(15), 1481(2007)(罗永明, 侯昭胤, 郑小明, 低浓度液体酸介质中快速合成SBA--15分子筛, 化学学报, 65(15), 1481(2007))14 WANG Na, LI Mingtian, ZHANG Junqi, ZHANG Jinsong, Effect of the content of MCM–41 and coupling modification on composite tensile properties, Acta Material Compositae Sinica, 22(2), 27(2005)(王 娜, 李明天, 张军旗, 张劲松, MCM--41填加量与偶联修饰对复合材料拉伸性能的影响, 复合材料学报, 22(2), 27(2005))15 ZHENG Shan, GAO Lian, GUO Jingkun, Synthesis and charaterization of 3–aminopropyl modified mesoporous silica MCM–41 at room temperature, Journal of Inorganic Materials, 15(5), 844(2000)(郑 珊, 高 濂, 郭景坤, 温和条件下介孔分子筛MCM--41的修饰与表征, 无机材料学报, 15(5), 844(2000))16 LI Ying, YU Jian, GUO Zhaoxia, The influence of silane treatment on nylon6/nano–SiO2 in situ polymerization, Journal of Applied Polymer Science, 84(4), 827(2002)17 WANG Na, LIANG Yan, ZHANG Junqi, LI Mingtian, ZHANG Jinsong, Effect of silane coupling agent modified MCM–41 on the properties of epoxy resin/nanosized mesoporous MCM–41 composites, Chinese Journal of Materials Research, 19(1), 94(2005)(王 娜, 梁 艳, 张军旗, 李明天, 张劲松, 硅烷修饰对环氧树脂/纳米介孔MCM--41复合材料性能的影响, 材料研究学报, 19(1), 94(2005))18 HAN Wei, LIU Wei, WU Chifei, Preparation and properties of natural rubber/organic vermiculite nanocomposites, Acta Material Compositae Sinica, 23(2), 77(2006)(韩 炜, 刘 炜, 吴驰飞, 纳米有机蛭石/天然橡胶复合材料的制备及性能, 复合材料学报, 23(2),77(2006))19 M.Arroyo, M.A.Lopez Manchado, B.Herrero, Organo–montmorillonite as substitute of carbon black in natural rubber compounds, Polymer, 44(8), 2447(2003)20 S.Jamaliah, M.Z.W.Y.WAN, Z.H.M.D.Khairul, H.A.Mansor, Preparation and properties of radiation crosslinked natural rubber/clay nanocomposites, Polymer Testing, 24(2), 211(2005) |
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|
