Please wait a minute...
Chin J Mater Res  2009, Vol. 23 Issue (4): 399-404    DOI:
论文 Current Issue | Archive | Adv Search |
Preparation and properties of butyl methacrylate/styrene copolymer fiber
ZHANG Yuting; XIAO Changfa
Tianjin Municipal Key Label of Fiber Modification and Functional Fiber; Tianjin Polytechnic University; Tianjin 300160
Cite this article: 

ZHANG Yuting XIAO Changfa. Preparation and properties of butyl methacrylate/styrene copolymer fiber. Chin J Mater Res, 2009, 23(4): 399-404.

Download:  PDF(977KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Butyl methacrylate/styrene copolymer was synthesized with butyl methacrylate and styrene monomer by suspension polymerization, with BPO as initiator. The spinning liquid was prepared by dissolving synthetic copolymer into dimethyl acetylamide (DMAc) and then spun into fibers. The fiber with absorption function was obtained. The methacrylate/styrene copolymer were characterized by FTIR and 1H nuclear magnetic resonance (NMR) spectrometer. The related performance of copolymer fiber were analysized by thermogravimetric analysis (TG), dynamic mechanical analysis (DMA) and single–wire power equipment. It showed that BMA/St70/30 copolymer fiber which had better absorptive ability for specific kinds of oil was prepared had good performance. Its per gram methacrylate/styrene copolymer fiber saturated absorbency of kerosene, petroleumether, gasoline was 3.7 g kerosene/g copolymer fiber, 5.3 g petroleum/g copolymer fiber, 4.1 g heptane/g copolymer fiber respectively.

Key words:  organic polymer materials      butyl methacrylate      styrene      copolymer fiber      absorptive performance     
Received:  27 February 2009     
ZTFLH: 

TB324

 
  TQ342

 
Fund: 

Supported by National Natural Scientific Foundation of China No.50673077.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2009/V23/I4/399

1 Blaney, Carol Ann, Oil–sorbing article and methods for making and using same, United States Patent, 5, 834, 385. 1998 – 11 – 10 2 WANG Kexin, CHEN Jiangping, Study on molecular weight of butyl methacrylate–styrene copolymer–viscosity. Guangxi Chemical Industry and Technology, 3, 35(1989) (王克信, 陈江平, 甲基丙烯酸丁酯--苯乙烯共聚物分子量的测定--粘度法, 广西化工,  3, 35(1989)) 3 ZOU Yousi, QIU Zhiping, ZHUANG Rongchuan, LIN Donghai, DAI Lizong, Atom transfer radical copolymerization of styrene and butyl methacrylate, Acta Polymerica Sinica, 2, 146(1999) (邹友思, 邱志平, 庄荣传, 林东海, 戴李综, 甲基丙烯酸丁酯和苯乙烯的原子转移自由基共聚, 高分子学报,  2, 146(1999)) 4 JANG Jyongsik, KIM Beom–seok, Studies of crosslinked styrene-alkyl acrylate copolymers for oil absorbency application (I) Synthesis and characterization, J. Appl. Polym. Sci., 77, 903(2000) 5 JANG Jyongsik, KIM Beom–seok, Studies of crosslinked styrene-alkyl acrylate copolymers for oil absorbency application (II) Effects of polymerization conditions on oil absorbency, J. Appl. Polym. Sci., 77, 914(2000) 6 LI Yunyun, SHU Wubing, ZAN Lina, Studies on the synthesis of high oil–absorbing resin by copolymerization, Chemical Industry and Engineering Progress, 26(6), 842(2007) (李芸芸, 舒武炳, 昝丽娜, 二元共聚高吸油树脂的合成工艺, 化工进展,  26(6), 842(2007)) 7 Gordon S. Bond, Southlake, Tex, Process for deabsorbing oil from oil absorbent.US, 5244566(1993) 8 Richard Middleton, Mehtod and system for removing oil from oil absorbent material, US, 5538646(1996) 9 HAN Zhewen, Polymer Science Experiment, (Shanghai, East China university of science technology press, 2004) p.56 (韩哲文, 高分子科学实验  (上海, 华东理工大学出版社, 2004) p.56) 10 WANG Yifeng, FENG Yan, GE Zhaogang, XIAO Changfa, Preparation and oil absorptivity of  polystearylmethacrylate, China Plastics Industry, 34(10), 7(2006) (王仪凤, 封 严, 葛兆刚, 肖长发, 聚甲基丙烯酸十八酯的制备及吸油性能, 塑料工业, 34(10), 7(2006)) 11 Mei Hua Zhou, Won–Jei Cho, Synthesis and properties of high oil–absorbent4–tert–butylstyrene–EPDM– divinylbenzene graft terpolymer, Appl. Poly. Sci., 85(10), 2119(2002) 12 LU Jiang, LIANG Hui, Polymer chemistry, (Beijing, Chemical industry press, 2006) p.98 (卢江, 梁 晖, 高分子化学, (北京, 化学工业出版社, 2006) p.98) 13 YU Dequan, YANG Junshan, Nuclear Magnetic Resonance spectra, (Beijing, Chemical industry press, 2000)p.59 (于德泉, 杨俊山,  分析化学手册(第七分册)--核磁共振波谱分析(北京, 化学工业出版社, 2000) p.59) 14 LU Zhibao, WU Pingping, HAN Zhewen, Study on measurement of relative reactivity ratios of styrene and butyl methacrylate by nuclear magnetic resonance spectrometry, Acta Polymerica Sinica, 1, 47(1996) (陆志豹, 吴平平, 韩哲文, 核磁共振法测定苯乙烯--甲基丙烯酸丁酯竞聚率的研究, 高分子学报,  1, 47(1996)) 15 GUO Junmin, YAN Guoliang, WANG Shuangyan, Analysis of the structure of amorphous area in polyester fibers with DMA method, Petrochemical Technology in Jinshan, 23(2), 6(2004) (郭俊敏, 严国良, 王双燕, DMA法分析聚酯纤维无定形区结构, 金山油化纤, 23(2), 6(2004) 16 GU Junwei, ZHANG Guangcheng, DONG Shanlai, Study on thermal analysis of polyester resin, China Paint, 20(9), 26(2005) (顾军渭, 张广成, 董善来等. 聚酯树膳防火涂料阻燃体系的热分析研究, 中国涂料,  20(9), 26(2005)) 17 D.Kilburn, G.Dlubek, Free volume in poly(n-alkyl methacrylate)s from positron lifetime and PVT experiments and its relation to the structural relaxation, Polymer, (47), 7774(2006)
[1] YE Jiaofeng, WANG Fei, ZUO Yang, ZHANG Junxiang, LUO Xiaoxiao, FENG Libang. Epoxy Resin-modified Thermo-reversible Polyurethane with High Strength, Toughness, and Self-healing Performance[J]. 材料研究学报, 2023, 37(4): 257-263.
[2] LI Hanlou, JIAO Xiaoguang, ZHU Huanhuan, ZHAO Xiaohuan, JIAO Qingze, FENG Caihong, ZHAO Yun. Synthesis of Branched Fluorine-containing Polyesters and their Properties[J]. 材料研究学报, 2023, 37(4): 315-320.
[3] MA Yizhou, ZHAO Qiuying, YANG Lu, QIU Jinhao. Preparation and Dielectric Energy Storage Properties of Thermoplastic Polyimide/Polyvinylidene Fluoride Composite Film[J]. 材料研究学报, 2023, 37(2): 89-94.
[4] SHEN Yanlong, LI Beigang. Preparation of Magnetic Amino Acid-Functionalized Aluminum Alginate Gel Polymer and its Super Adsorption on Azo Dyes[J]. 材料研究学报, 2022, 36(3): 220-230.
[5] LONG Qing, WANG Chuanyang. Thermal Degradation Behavior and Kinetics Analysis of PMMA with Different Carbon Black Contents[J]. 材料研究学报, 2022, 36(11): 837-844.
[6] JIANG Ping, WU Lihua, LV Taiyong, Pérez-Rigueiro José, WANG Anping. Repetitive Stretching Tensile Behavior and Properties of Spider Major Ampullate Gland Silk[J]. 材料研究学报, 2022, 36(10): 747-759.
[7] YAN Jun, YANG Jin, WANG Tao, XU Guilong, LI Zhaohui. Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil[J]. 材料研究学报, 2021, 35(9): 651-656.
[8] ZHANG Hao, LI Fan, CHANG Na, WANG Haitao, CHENG Bowen, WANG Panlei. Preparation of Carboxylic Acid Grafted Starch Adsorption Resin and Its Dye Removal Performance[J]. 材料研究学报, 2021, 35(6): 419-432.
[9] SUN Liying, QIAN Jianhua, ZHAO Yongfang. Preparation and Performance of AgNWs -TPU/PVDF Flexible Film Capacitance Sensors[J]. 材料研究学报, 2021, 35(6): 441-448.
[10] TANG Kaiyuan, HUANG Yang, HUANG Xiangzhou, GE Ying, LI Pinting, YUAN Fanshu, ZHANG Weiwei, SUN Dongping. Physicochemical Properties of Carbonized Bacterial Cellulose and Its Application in Methanol Electrocatalysis[J]. 材料研究学报, 2021, 35(4): 259-270.
[11] SU Chenwen, ZHANG Tingyue, GUO Liwei, LI Le, YANG Ping, LIU Yanqiu. Preparation of Thiol-ene Hydrogels for Extracellular Matrix Simulation[J]. 材料研究学报, 2021, 35(12): 903-910.
[12] ZHANG Xiangyang, ZHANG Qiyang, ZHENG Tao, TANG Tao, LIU Hao, LIU Guojin, ZHU Hailin, ZHU Haifeng. Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes[J]. 材料研究学报, 2021, 35(11): 866-872.
[13] WAN Liying, XIAO Yang, ZHANG Lunliang. Preparation and Properties of PU-DA System Based on Thermoreversible Diels-Alder Dynamic Covalent Bond[J]. 材料研究学报, 2021, 35(10): 752-760.
[14] ZHANG Cuige, HU Liang, LU Zuxin, ZHOU Jiahui. Preparation and Emulsification Properties of Self-assembled Colloidal Particles Based on Alginic Acid[J]. 材料研究学报, 2021, 35(10): 761-768.
[15] HUANG Jian, LIN Chunxiang, CHEN Ruiying, XIONG Wanyong, WEN Xiaole, LUO Xin. Ionic Liquid-assisted Synthesis of Nanocellulose Adsorbent and Its Adsorption Properties[J]. 材料研究学报, 2020, 34(9): 674-682.
No Suggested Reading articles found!