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| Preparation and Electrochemical Properties of Rare Earth Ion Doped Diatom Anode Materials |
SUN Shimao1, LIU Hongchang1,2( ), LIU Hongwei1,2, WANG Jun1,2, SHANG Chenkai1 |
1.School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
2.Key Lab of Biometallurgy of Ministry of Education, Central South University, Changsha 410083, China |
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Cite this article:
SUN Shimao, LIU Hongchang, LIU Hongwei, WANG Jun, SHANG Chenkai. Preparation and Electrochemical Properties of Rare Earth Ion Doped Diatom Anode Materials. Chinese Journal of Materials Research, 2025, 39(7): 499-509.
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Abstract Diatoms were prepared by adding extraction solution prepared from ionic rare earth ores to diatom culture media. The results indicate that high concentrations of rare earth extraction solution inhibited the growth of diatoms. An appropriate amount of rare earth extraction solution was added to cultivate diatoms, and diatom frustules modified with rare earth ions were used as rare earth ion doped diatom anode materials for lithium-ion batteries. The natural hollow porous structure of diatom frustules provided enough buffering space for the volumetric strain of SiO2. The doping of rare earth ions reduced the electrochemical impedance of the anode electrode of diatom frustules, significantly improving its long cycle and rate performance. The specific discharge capacity of the diatom frustule anode (DBS@C-REE-10) prepared with 10 mL/L rare earth extract after 150 cycles was 879 mAh·g-1, which was much greater than that of the diatom anode without rare earth ion modification.
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Received: 16 October 2024
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| Fund: National Key Research and Development Program of China(2022YFC2105300) |
Corresponding Authors:
LIU Hongchang, Tel: 15874293360, E-mail: hchliu2050@csu.edu.cn
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