Properties of Epoxy Resin Based Composite Incorporated with Magnetically Functionalized Reduction Graphene Oxide

doi:10.11901/1005.3093.2021.605

Chinese Journal of Materials Research

2022, Vol. 36

Issue (12): 881-886 DOI: 10.11901/1005.3093.2021.605

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Properties of Epoxy Resin Based Composite Incorporated with Magnetically Functionalized Reduction Graphene Oxide

ZENG Qiang¹, WANG Rongchao¹, LIU Qi¹, PENG Huanan¹, CHEN Ping²(

)

^1.School of Chemistry and Environmental Science, Shangrao Normal University, Shangrao 334001, China
^2.Key Laboratory of Materials Modification by Laser, Ion and Electron Beams of Ministry of Education ＆ School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Cite this article:

ZENG Qiang, WANG Rongchao, LIU Qi, PENG Huanan, CHEN Ping. Properties of Epoxy Resin Based Composite Incorporated with Magnetically Functionalized Reduction Graphene Oxide. Chinese Journal of Materials Research, 2022, 36(12): 881-886.

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Abstract

The magnetic functionalized rGO/Fe₃O₄ was prepared by hydrothermal method with graphene oxide and ferric chloride as raw materials, and subsequently rGO/Fe₃O₄ particles were blend in epoxy resin to prepared composite rGO/Fe3O4/epoxy resin. The results show that the impact strength of rGO/Fe₃O₄/epoxy resin composites reaches 27 kJ/m² when the addition amount of rGO/Fe₃O₄is 30%, which is 58.8% higher than that of the plain epoxy resin. In addition, the absorption performance of epoxy resin composite is significantly enhanced after the addition of rGO/Fe₃O₄. When the addition of rGO/Fe₃O₄ is 20%, the reflection loss of the rGO/Fe₃O₄/epoxy resin composite is less than -10 dB in the frequency range of 7.7~12.3 GHz. The effective absorption bandwidth (reflection loss<-10 dB) is up to 4.6 GHz, which covering the whole X-band. With the increase of graphene content, the position of the minimum reflection loss of rGO/Fe₃O₄/epoxy resin composites moves towards low-frequencies. It follows that by controlling the relative content of rGO and Fe₃O₄, the absorbing performance of rGO/Fe₃O₄/epoxy resin composites can be adjusted to the meet the requirements for materials of desired absorbing performance.

Key words: composite reduced graphene oxide ferric oxide modification electromagnetic absorption properties

Received: 28 October 2021

ZTFLH:

TB332

Fund: National Natural Science Foundation of China(62065016);Department of Education Science and Technology Research Project of Jiangxi Province(GJJ180886);School-level Self-selected Project of Shangrao Normal University(201904);Innovation and Entrepreneurship Training Program for College Students of Shangrao Normal University(2019-CX-20);Key Laboratory of Materials Modification by Laser, Ion and Electron Beams of Ministry of Education(KF2004)

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	Qiang ZENG
	Rongchao WANG
	Qi LIU
	Huanan PENG
	Ping CHEN

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.605 OR https://www.cjmr.org/EN/Y2022/V36/I12/881

Fig.1 XRD patterns of GO and rGO/ Fe₃O₄

Fig.2 XPS Fe2p spectrum of S₃₀ samples

Fig.3 SEM images rGO/Fe₃O₄

Fig.4 Impact strength of rGO/Fe₃O₄/ epoxy resin composites

Fig.5 Reflectance value with different S₃₀ content in epoxy resin

Table 1 Electromagnetic absorption performance with different S30 content in epoxy resin

Fig.6 Reflectance values of epoxy resins composite materials which added S₀, S₁₀, S₃₀, S₅₀ and S₇₀

Table 2 The electromagnetic absorption performance of epoxy resins composite materials which added S₀, S₁₀, S₃₀, S₅₀ and S₇₀

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