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| Biomimetic Synthesis of Vaterite by N-Succinyl-O-Hydroxypropyl Sulfonated Chitosan |
CHEN Xiaodong, XIN Meihua, LI Mingchun**( ), CHEN Zhangxu, CHEN Zhiqiang |
| College of Material Science and Engineering, Huaqiao University, Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Xiamen 361021, China |
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Cite this article:
CHEN Xiaodong, XIN Meihua, LI Mingchun, CHEN Zhangxu, CHEN Zhiqiang. Biomimetic Synthesis of Vaterite by N-Succinyl-O-Hydroxypropyl Sulfonated Chitosan. Chinese Journal of Materials Research, 2016, 30(1): 31-37.
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Abstract N-succinyl-O-hydroxypropyl sulfonated chitosan (SA-HPSCS) was prepared and then characterized by FT-IR and 1HNMR. The role of SA-HPSCS in the biomimetic synthesis of CaCO3 was studied, while the CaCO3 crystal produced in a pure water system was used as a reference. The influence of pH value on the morphology and crystallographic structure of CaCO3 crystal in the SA-HPSCS system was investigated and the relevant mechanism was proposed. The results show that the calcite is the only phase of CaCO3 crystal prepared in the pure water system, while the vaterite is dominant phase of those prepared in the SA-HPSCS system. By pH=6 the vaterite content in the prepared CaCO3 reached 95.8%, but both the size and the content of the vaterite dropped with the increase of pH value. The results also indicate that SA-HPSCS could regulate effectively the synthesis process of the CaCO3 crystal in terms of morphology, polymorph and dimension, and the pH value could strongly affect its regulation effect.
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Received: 04 February 2015
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| Fund: *Supported by the Key Science Projects of Fujian Province No.2009H0030, the Natural Science Foundation of Fujian Province No.2012J01396, and the Ministry of Science and Technology Personnel Service Enterprise Project No.2009GJC40030 |
| About author: ** To whom correspondence should be addressed, Tel: (0595)22690819, E-mail: mcli@hqu.edu.cn |
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