熔融氯化物环境中结构材料的高温腐蚀行为的研究进展

doi:10.11901/1005.3093.2025.259

材料研究学报

2026, Vol. 40

Issue (10): 721-732 DOI: 10.11901/1005.3093.2025.259

综述

本期目录 | 过刊浏览

熔融氯化物环境中结构材料的高温腐蚀行为的研究进展

林新顺¹, 陈思含²(

), 苏允海¹, 薛海龙¹, 姜海昌²(

), 戎利建², 林如山³

^1.沈阳工业大学材料科学与工程学院沈阳 110870
^2.中国科学院金属研究所中国科学院核用材料与安全评价重点实验室沈阳 110016
^3.中国原子能科学研究院北京 102413

Progress of High Temperature Corrosion Behavior of Structural Materials in Molten Chloride Environment

LIN Xinshun¹, CHEN Sihan²(

), SU Yunhai¹, XUE Hailong¹, JIANG Haichang²(

), RONG Lijian², LIN Rushan³

^1.School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
^2.CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.China Institute of Atomic Energy, Beijing 102413, China

引用本文:

林新顺, 陈思含, 苏允海, 薛海龙, 姜海昌, 戎利建, 林如山. 熔融氯化物环境中结构材料的高温腐蚀行为的研究进展[J]. 材料研究学报, 2026, 40(10): 721-732.
Xinshun LIN, Sihan CHEN, Yunhai SU, Hailong XUE, Haichang JIANG, Lijian RONG, Rushan LIN. Progress of High Temperature Corrosion Behavior of Structural Materials in Molten Chloride Environment[J]. Chinese Journal of Materials Research, 2026, 40(10): 721-732.

全文: PDF(6920 KB) HTML

摘要:

综述了不锈钢和镍基高温合金在熔盐环境中的腐蚀行为，重点探讨了合金元素、腐蚀环境、温度及杂质(水、氧)等因素的影响机制。研究表明，镍基合金因含有大量难熔金属元素而表现出优于不锈钢的耐蚀性能。通过熔盐纯化可有效降低杂质含量，从而显著改善材料的腐蚀问题。在氯化物熔盐环境中，铀(U)元素会影响合金的耐熔盐腐蚀性能，但其放射性等因素对实验条件要求较为苛刻。因此，鉴于铀(U)与铈(Ce)在离子半径等物理化学上的相似性，深入分析了CeCl₃对熔盐体系中材料耐蚀性的影响机制，为深入理解铀对材料在熔盐中的腐蚀行为提供了重要参考。

关键词 ：金属材料, 熔盐腐蚀, 氯化物熔盐, 镍基合金, 乏燃料

Abstract：

Chloride molten salts, endowed with excellent physicochemical properties, exhibit broad application prospects in the electrochemical separation of spent nuclear fuel (SNF) and molten salt reactors (MSRs), in which they function as electrolytes, fuel solvents and coolants. However, the high-temperature, strongly chlorinating, and oxidizing environment of molten salt systems poses severe challenges to the corrosion resistance of structural materials, which has become the key factor restricting their engineering applications. In this study, the corrosion behaviors of stainless steels and Ni-based superalloys in molten salt environments are systematically reviewed, with a focus on the effects of various factors, including alloying elements, corrosive environments, temperatures and impurities (water and oxygen). Studies have indicated that Ni-based superalloys exhibit superior corrosion resistance compared with stainless steels due to the incorporation of a large number of refractory metal elements. Molten salt purification can effectively reduce the impurity content in the system, thereby significantly mitigating material corrosion. In chloride molten salt environments, uranium (U) exerts a significant influence on the corrosion resistance of alloys. However, its radioactivity and other inherent properties impose stringent requirements on the experimental conditions for related studies. Given the similarities in physicochemical properties such as ionic radius between U and cerium (Ce), this study investigates the mechanism by which CeCl₃ affects the corrosion resistance of materials in molten salt systems. These findings provide important insights into the corrosion behavior of materials induced by U in molten salts. Currently, the corrosion of metallic materials in high-temperature molten salts remains a major bottleneck in the development of SNF reprocessing technology. Future research should focus on developing commercial alloys with excellent corrosion resistance to chloride molten salts, and further exploring their corrosion mechanisms and influencing factors, thereby providing critical support for the advancement of SNF reprocessing technology.

Key words： metallic materials molten salt corrosion chloride molten salt nickel-based alloy spent nuclear fuel

收稿日期: 2025-08-20

ZTFLH:

TG172.6

基金资助:中核集团领创项目(CNNC-LCKY-2024-092)

通讯作者: 陈思含，助理研究员，shchen17b@imr.ac.cn，研究方向为特种合金；
姜海昌，研究员，hcjiang@imr.ac.cn，研究方向为核用结构材料

Corresponding author: CHEN Sihan, Tel: (024)23971985, E-mail: shchen17b@imr.ac.cn;
JIANG Haichang, Tel: (024)23975312, E-mail: hcjiang@imr.ac.cn

作者简介: 林新顺，男，1998年生，硕士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	林新顺
	陈思含
	苏允海
	薛海龙
	姜海昌
	戎利建
	林如山
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2025.259 或 https://www.cjmr.org/CN/Y2026/V40/I10/721

图1 在惰性气氛(Ar)中熔融NaCl-KCl中P91的腐蚀机理[18]

图2 合金在700 ℃下暴露于熔融NaCl-KCl-MgCl2中100 h后Cr的贫化深度[23]

图3 在氯化物熔盐中测试的镍基合金腐蚀速率散点图和镍基合金中Cr、Mo含量图[30~34,56]

图4 Ni-xW-6Cr合金中Ni、W和Cr的活度与W含量之间的关系[45]

图5 三种腐蚀类型模拟装置示意图：熔盐腐蚀[69]，高温蒸汽腐蚀[47]，在熔盐/气体界面腐蚀[36]

图6 GH3535合金熔盐腐蚀300 h后的表面形貌及成分分析：固溶态，晶界工程处理态[50]

图7 双镁电极和交流电压纯化原理图。左侧(阶段1)：去除杂质，且在阴极上生成MgO；右侧(阶段2)：由于Mg→Mg2+溶解，电极上的MgO脱落[24]

图8 在氩气中P91在熔融NaCl-KCl中的腐蚀机理，氧分压对所涉及反应的影响；700 ℃，Fe-Cl-O和Cr-Cl-O体系的热力学稳定性图[18]

图9 活性缝隙中关键化学元素扩散行为示意图[57]

图10 不同温度下UCl3、CeCl3扩散系数图[59]

[1]	Buongiorno J, Corradini M, Parsons J, et al. Nuclear energy in a carbon-constrained world: big challenges and big opportunities [J]. IEEE Power Energy Mag., 2019, 17(2): 69 doi: 10.1109/MPE.2018.2885250
[2]	Tang C B, Chai X M, Zhu Y H, et al. Development opportunities and challenges for China's nuclear power equipment under the “dual carbon” goals [J]. Nucl. Power Eng., 2025, 46(05): 205
[2]	唐传宝, 柴晓明, 朱永辉等. “双碳”背景下我国核电装备的发展机遇及挑战 [J]. 核动力工程, 2025, 46(05): 205
[3]	Wang C L, Chai X M, Yang B, et al. Development and prospect of advanced nuclear energy [J]. Nucl. Power Eng., 2023, 44(5): 1
[3]	王丛林, 柴晓明, 杨博等. 先进核能技术发展及展望 [J]. 核动力工程, 2023, 44(5): 1
[4]	Zhang D H, Qiao P R, Yang Y, et al. Strategic thinking on development of China fast reactor and advanced nuclear fuel cycle system [J]. Atom. Energy Sci. Technol., 2019, 53(10): 1816
[4]	张东辉, 乔鹏瑞, 杨勇等. 中国快堆及先进核燃料循环体系发展战略思考 [J]. 原子能科学技术, 2019, 53(10): 1816 doi: 10.7538/yzk.2019.youxian.0487
[5]	Zhong Z Y, Lin R S, Chen Z H, et al. Progress of spent fuel dry reprocessing facilities for spent nuclear fuel abroad [J]. Nucl. Sci. Eng., 2024, 44(1): 206
[5]	钟振亚, 林如山, 陈志华等. 国外乏燃料干法后处理设施进展 [J]. 核科学与工程, 2024, 44(1): 206
[6]	Chen B, Lin R S, Chen Z H, et al. Economic analysis of spent fuel dry and aqueous reprocessing facilities [J]. Guangdong Chem. Ind., 2024, 51(4): 61
[6]	陈彪, 林如山, 陈志华等. 乏燃料干法和水法后处理设施经济性分析 [J]. 广东化工, 2024, 51(4): 61
[7]	Lin R S, Zhong Z Y. Progress and development thinking of dry reprocessing technology for spent nuclear fuel from fast reactor [J]. Atom. Energy Sci. Technol., 2025, 59(S1): 41
[7]	林如山, 钟振亚. 快堆乏燃料干法后处理技术与发展思考 [J]. 原子能科学技术, 2025, 59(S1): 41
[8]	Choi E Y, Lee C H. Review of recent advances in electrochemical processes in molten salt electrolyte for recycling used nuclear fuel [J]. Korean J. Chem. Eng., 2025, 42: 1249 doi: 10.1007/s11814-024-00323-x
[9]	Mirza M, Abdulaziz R, Maskell W C, et al. Electrochemical processing in molten salts–a nuclear perspective [J]. Energy Environ. Sci., 2023, 16(3): 952 doi: 10.1039/D2EE02010F
[10]	Xu S P, Zheng Y H, Zhan F Q, et al. Effect of different pre-oxidation temperature on corrosion resistance of Ni-Al coatings to high temperature chloride molten salt [J]. Chin. J. Mater. Res., 2024, 38(12): 922 doi: 10.11901/1005.3093.2024.170
[10]	许世鹏, 郑月红, 占发琦等. 预氧化处理温度对镍铝涂层耐腐蚀性能的影响 [J]. 材料研究学报, 2024, 38(12): 922 doi: 10.11901/1005.3093.2024.170
[11]	Du Y, Wang C, Zhu S L, et al. High temperature oxidation and electrochemical corrosion behavior of Al Nano-particle modified silicone coating on 304 stainless steel [J]. Chin. J. Mater. Res., 2019, 33(12): 942 doi: 10.11901/1005.3093.2019.159
[11]	杜瑶, 王成, 朱圣龙等. 304不锈钢表面纳米铝改性有机硅涂层的高温氧化和电化学行为 [J]. 材料研究学报, 2019, 33(12): 942
[12]	Zhao Y Y. Molten chloride thermophysical properties, chemical optimization, and purification [R]. Golden: National Renewable Energy Lab, 2020
[13]	Sawant S S, Gajbhiye B D, Tyagi S, et al. High temperature corrosion studies in molten salt using salt purification and alloy coating [J]. Indian Chem. Eng., 2017, 59(3): 242
[14]	Qiu G X, Li J N, Li Q, et al. High temperature oxidation behavior of FeCrAl ferritic stainless steel [J]. Met. Funct. Mater., 2024, 31(5): 101
[14]	邱国兴, 李嘉宁, 李琦等. FeCrAl铁素体不锈钢高温氧化行为 [J]. 金属功能材料, 2024, 31(5): 101
[15]	Hofmeister M, Klein L, Miran H, et al. Corrosion behaviour of stainless steels and a single crystal superalloy in a ternary LiCl-KCl-CsCl molten salt [J]. Corros. Sci., 2015, 90: 46 doi: 10.1016/j.corsci.2014.09.009
[16]	Guo S Q, Zhang J S, Wu W, et al. Corrosion in the molten fluoride and chloride salts and materials development for nuclear applications [J]. Prog. Mater. Sci., 2018, 97: 448 doi: 10.1016/j.pmatsci.2018.05.003
[17]	Ruiz-Cabañas F J, Prieto C, Madina V, et al. Materials selection for thermal energy storage systems in parabolic trough collector solar facilities using high chloride content nitrate salts [J]. Sol. Energy Mater. Sol. Cells, 2017, 163: 134 doi: 10.1016/j.solmat.2017.01.028
[18]	Grégoire B, Oskay C, Meißner T M, et al. Corrosion mechanisms of ferritic-martensitic P91 steel and Inconel 600 nickel-based alloy in molten chlorides. Part I: NaCl-KCl binary system [J]. Sol. Energy Mater. Sol. Cells, 2020, 215: 110659 doi: 10.1016/j.solmat.2020.110659
[19]	Guo L L, Liu Q, Yin H Q, et al. Excellent corrosion resistance of 316 stainless steel in purified NaCl-MgCl₂ eutectic salt at high temperature [J]. Corros. Sci., 2020, 166: 108473 doi: 10.1016/j.corsci.2020.108473
[20]	Gomez-Vidal J C, Tirawat R. Corrosion of alloys in a chloride molten salt (NaCl-LiCl) for solar thermal technologies [J]. Sol. Energy Mater. Sol. Cells, 2016, 157: 234 doi: 10.1016/j.solmat.2016.05.052
[21]	Mortazavi A, Zhao Y, Esmaily M, et al. High-temperature corrosion of a nickel-based alloy in a molten chloride environment-the effect of thermal and chemical purifications [J]. Sol. Energy Mater. Sol. Cells, 2022, 236: 111542 doi: 10.1016/j.solmat.2021.111542
[22]	Liu X Y, Bawane K, Zheng X Y, et al. Temperature-dependent morphological evolution during corrosion of the Ni-20Cr alloy in molten salt revealed by multiscale imaging [J]. ACS Appl. Mater. Interfaces, 2023, 15(10): 13772 doi: 10.1021/acsami.2c23207
[23]	Sun H, Wang J Q, Li Z J, et al. Corrosion behavior of 316SS and Ni-based alloys in a ternary NaCl-KCl-MgCl₂ molten salt [J]. Sol. Energy, 2018, 171: 320 doi: 10.1016/j.solener.2018.06.094
[24]	Ding W J, Yang F, Bonk A, et al. Molten chloride salts for high-temperature thermal energy storage: continuous electrolytic salt purification with two Mg-electrodes and alternating voltage for corrosion control [J]. Sol. Energy Mater. Sol. Cells, 2021, 223: 110979 doi: 10.1016/j.solmat.2021.110979
[25]	Rao C J, Shankar A R, Ajikumar P K, et al. Corrosion behavior of structural materials in LiCl-KCl molten salt by thermogravimetric study [J]. Corrosion, 2015, 71(4): 502 doi: 10.5006/1341
[26]	Ravi Shankar A, Mathiya S, Thyagarajan K, et al. Corrosion and microstructure correlation in molten LiCl-KCl medium [J]. Metall. Mater. Trans. A, 2010, 41(7): 1815 doi: 10.1007/s11661-010-0223-5
[27]	Na J S, Kim S H, Kim S J, et al. Corrosion effect by preferential formation of Cr and Fe-based ceramic compounds under NaCl-KCl-MgCl₂ molten salts [J]. J. Korean Ceram. Soc., 2025, 62(3): 539 doi: 10.1007/s43207-025-00490-5
[28]	Lu X D, Wang F L. Isothermal oxidation behaviour of Ni-Cr-Co-Mo-W-Ta-Al superalloy at 900 ^oC and 1000 ^oC [J]. Chin. J. Mater. Res., 2016, 30(8): 589
[28]	卢旭东, 王复利. Ni-Cr-Co-Mo-W-Ta-Al合金在900 ℃和1000 ℃的高温氧化行为 [J]. 材料研究学报, 2016, 30(8): 589 doi: 10.11901/1005.3093.2016.163
[29]	Lu X D, Tian S G, Yu X F, et al. Isothermal oxidation behavior of Ni-Cr-Ta-Al-Co-Mo alloy at 900 ^oC and 1000 ^oC [J]. Chin. J. Mater. Res., 2011, 25(4): 427
[29]	卢旭东, 田素贵, 于兴福等. Ni-Cr-Ta-Al-Co-Mo合金在900 ℃和1000 ℃的恒温氧化行为 [J]. 材料研究学报, 2011, 25(4): 427
[30]	Vignarooban K, Pugazhendhi P, Tucker C, et al. Corrosion resistance of Hastelloys in molten metal-chloride heat-transfer fluids for concentrating solar power applications [J]. Sol. Energy, 2014, 103: 62 doi: 10.1016/j.solener.2014.02.002
[31]	Ding W, Shi H, Xiu Y, et al. Hot corrosion behavior of commercial alloys in thermal energy storage material of molten MgCl₂/KCl/NaCl under inert atmosphere [J]. Sol. Energy Mater. Sol. Cells, 2018, 184: 22 doi: 10.1016/j.solmat.2018.04.025
[32]	Ravi Shankar A, Kanagasundar A, Mudali U K. Corrosion of nickel-containing alloys in molten LiCl-KCl medium [J]. Corrosion, 2013, 69(1): 48 doi: 10.5006/0627
[33]	Xu Q, Li X, Zhang Y P, et al. Corrosion mechanism of Fe-Cr-based alloys in molten LiCl-KCl mediated by CeCl₃ [J]. Corros. Sci., 2026, 271: 114119 doi: 10.1016/j.corsci.2026.114119
[34]	Indacochea J E, Smith J L, Litko K R, et al. High-temperature oxidation and corrosion of structural materials in molten chlorides [J]. Oxid. Met., 2001, 55(1): 1 doi: 10.1023/A:1010333407304
[35]	Lv R M, Tang X, Ying Z M, et al. Corrosion mechanism and properties of 316L stainless steel in NaCl-KCl molten salt at high temperatures [J]. Crystals, 2025, 15(3): 280 doi: 10.3390/cryst15030280
[36]	Yu Z D, Wu J P, Liu H L, et al. Corrosion behavior of the GH3535 and C276 alloys at the liquid/gas LiCl-KCl salt interface at 550 ^oC [J]. J. Mater. Eng. Perform., 2025, 34: 13391 doi: 10.1007/s11665-024-10095-4
[37]	Liu B, Wei X L, Wang W L, et al. Corrosion behavior of Ni-based alloys in molten NaCl-CaCl₂-MgCl₂ eutectic salt for concentrating solar power [J]. Sol. Energy Mater. Sol. Cells, 2017, 170: 77 doi: 10.1016/j.solmat.2017.05.050
[38]	Xie S J, Lei M, Sun J W, et al. Corrosion behavior of 20G and TP347H in molten LiCl-NaCl-KCl salt [J]. Nanomaterials, 2024, 14(12): 1026 doi: 10.3390/nano14121026
[39]	Li Y S, Spiegel M, Shimada S. Corrosion behaviour of various model alloys with NaCl-KCl coating [J]. Mater. Chem. Phys., 2005, 93(1): 217 doi: 10.1016/j.matchemphys.2005.03.015
[40]	Asghari-Rad P, Smith N D, Kim S W, et al. Electrochemical stability and corrosion behavior of Ni-Cr alloy in molten LiCl-KCl salt [J]. Electrochim. Acta, 2025, 532: 146507 doi: 10.1016/j.electacta.2025.146507
[41]	Suzuki Y, Watanabe T, Goto T. Electrochemical and spectroscopic study on corrosion behavior of Ni-based alloys in chloride melts: materials for an integral molten salt fast reactor [J]. Nucl. Eng. Des., 2023, 415: 112699 doi: 10.1016/j.nucengdes.2023.112699
[42]	Lloyd A C, Noël J J, McIntyre S, et al. Cr, Mo and W alloying additions in Ni and their effect on passivity [J]. Electrochim. Acta, 2004, 49(17-18): 3015 doi: 10.1016/j.electacta.2004.01.061
[43]	Kazakovtseva N A, Mazannikov M V, Nikitina E V, et al. Corrosion electrochemical behavior of molybdenum in the LiCl-KCl melt containing additives of cerium and neodymium trichlorides [J]. Russ. Metall., 2020, 2020(8): 925 doi: 10.1134/S0036029520080066
[44]	Alkhamis M. Stability of metals in molten chloride salt at 800 ^oC [D]. Tucson: The University of Arizona, 2016
[45]	Liu S L, Ye X X, Yan S, et al. Unexpected accelerated corrosion of Cr in Ni-xW-6Cr alloy with W content increasing [J]. Corros. Sci., 2021, 191: 109761 doi: 10.1016/j.corsci.2021.109761
[46]	Yang L J, Qian H C, Kuang W J. Corrosion behaviors of heat-resisting alloys in high temperature carbon dioxide [J]. Materials, 2022, 15(4): 1331 doi: 10.3390/ma15041331
[47]	Liu Q, Wang Z R, Liu W H, et al. Ni-Mo-Cr alloy corrosion in molten NaCl-KCl-MgCl₂ salt and vapour [J]. Corros. Sci., 2021, 180: 109183 doi: 10.1016/j.corsci.2020.109183
[48]	Grosu Y, Udayashankar N, Bondarchuk O, et al. Unexpected effect of nanoparticles doping on the corrosivity of molten nitrate salt for thermal energy storage [J]. Sol. Energy Mater. Sol. Cells, 2018, 178: 91 doi: 10.1016/j.solmat.2018.01.002
[49]	Ravi Shankar A, Mudali U K. Corrosion of type 316L stainless steel in molten LiCl-KCl salt [J]. Mater. Corros., 2008, 59(11): 878
[50]	Wang C C, Zhang J M, Yu Z D, et al. Effect of grain boundary engineering on corrosion behavior and mechanical properties of GH3535 alloy in LiCl-KCl molten salt [J]. J. Nucl. Mater., 2025, 604: 155513 doi: 10.1016/j.jnucmat.2024.155513
[51]	Gao B X, Yu R, Chen S Y, et al. Corrosion behavior of surface-modified Ni-based alloys in molten NaCl-KCl for thermal energy storage [J]. Mater. Chem. Phys., 2025, 332: 130288 doi: 10.1016/j.matchemphys.2024.130288
[52]	Muránsky O, Yang C, Zhu H, et al. Molten salt corrosion of Ni-Mo-Cr candidate structural materials for Molten Salt Reactor (MSR) systems [J]. Corros. Sci., 2019, 159: 108087 doi: 10.1016/j.corsci.2019.07.011
[53]	Bender R, Schütze M. The role of alloying elements in commercial alloys for corrosion resistance in oxidizing-chloridizing atmospheres. Part I: literature evaluation and thermodynamic calculations on phase stabilities [J]. Mater. Corros., 2003, 54: 567
[54]	Sim J H, Kim Y S, Cho I J. Corrosion behavior induced by LiCl-KCl in type 304 and 316 stainless steel and copper at low temperature [J]. Nucl. Eng. Technol., 2017, 49(4): 769 doi: 10.1016/j.net.2017.02.007
[55]	Wang C Y, Xu X R, Tong Y, et al. O^2-affected corrosion of nickel-based alloy in LiCl-KCl molten salt for pyroprocessing of spent nuclear fuel [J]. J. Nucl. Mater., 2025, 610: 155773 doi: 10.1016/j.jnucmat.2025.155773
[56]	Walczak M, Pineda F, Fernández Á G, et al. Materials corrosion for thermal energy storage systems in concentrated solar power plants [J]. Renew. Sustain. Energy Rev., 2018, 86: 22 doi: 10.1016/j.rser.2018.01.010
[57]	Henderson J D, Ebrahimi N, Dehnavi V, et al. The role of internal cathodic support during the crevice corrosion of Ni-Cr-Mo alloys [J]. Electrochim. Acta, 2018, 283: 1600 doi: 10.1016/j.electacta.2018.07.048
[58]	Marsden K C, Pesic B. Evaluation of the electrochemical behavior of CeCl₃ in molten LiCl-KCl eutectic utilizing metallic Ce as an anode [J]. J. Electrochem. Soc., 2011, 158(6): F111 doi: 10.1149/1.3575637
[59]	Yoon D, Phongikaroon S. Electrochemical properties and analyses of CeCl₃ in LiCl-KCl eutectic salt [J]. J. Electrochem. Soc., 2015, 162(10): E237 doi: 10.1149/2.0401510jes
[60]	Masset P, Bottomley D, Konings R, et al. Electrochemistry of uranium in molten LiCl-KCl eutectic [J]. J. Electrochem. Soc., 2005, 152(6): A1109 doi: 10.1149/1.1901083
[61]	Masset P, Konings R J M, Malmbeck R, et al. Thermochemical properties of lanthanides (Ln = La, Nd) and actinides (An = U, Np, Pu, Am) in the molten LiCl-KCl eutectic [J]. J. Nucl. Mater., 2005, 344(1-3): 173 doi: 10.1016/j.jnucmat.2005.04.038
[62]	Kuznetsov S A, Hayashi H, Minato K, et al. Electrochemical transient techniques for determination of uranium and rare-earth metal separation coefficients in molten salts [J]. Electrochim. Acta, 2006, 51(12): 2463 doi: 10.1016/j.electacta.2005.07.028
[63]	Kuznetsov S A, Hayashi H, Minato K, et al. Electrochemical behavior and some thermodynamic properties of UCl₄ and UCl₃ dissolved in a LiCl-KCl eutectic melt [J]. J. Electrochem. Soc., 2005, 152(4): C203 doi: 10.1149/1.1864532
[64]	Hoover R O, Shaltry M R, Martin S, et al. Electrochemical studies and analysis of 1-10 wt% UCl₃ concentrations in molten LiCl-KCl eutectic [J]. J. Nucl. Mater., 2014, 452(1-3): 389 doi: 10.1016/j.jnucmat.2014.05.057
[65]	Fukumoto K I, Nakagawa K, Takebayashi D, et al. Corrosion behavior of Hastelloy alloys and stainless steel in the molten chloride salt NaCl-CaCl₂-CeCl₃ [J]. J. Nucl. Sci. Technol., 2024, 61(11): 1397 doi: 10.1080/00223131.2024.2338367
[66]	Nikitina E V, Kazakovtseva N A. High temperature corrosion of 12Kh18N10T steel in molten lithium and potassium chlorides with a cerium trichloride addition [J]. Russ. Metall., 2018, 2018: 747 doi: 10.1134/S003602951808013X
[67]	Sun H, Zhang P, Wang J Q. Effects of alloying elements on the corrosion behavior of Ni-based alloys in molten NaCl-KCl-MgCl₂ salt at different temperatures [J]. Corros. Sci., 2018, 143: 187 doi: 10.1016/j.corsci.2018.08.021
[68]	Lan Y P, Sohn H Y, Murali A, et al. The formation and growth of CeOCl crystals in a molten KCl-LiCl flux [J]. Appl. Phys., 2018, 124A(10) : 702
[69]	Chi L D, Sun H, Zhou X T. Effects of alloying elements (Mo and W) on corrosion behavior of Ni-based alloys in NaCl-KCl-MgCl₂ molten salt [J]. Corros. Sci., 2024, 237: 112313 doi: 10.1016/j.corsci.2024.112313

[1]	何一梅, 付志豪, 杨超云, 刘航, 刘朋, 李星, 石帅, 赵燕青, 栾义坤, 李殿中. 稀土Ce对渗碳齿轮钢摩擦磨损性能的影响[J]. 材料研究学报, 2026, 40(9): 641-652.
[2]	李冰冰, 徐磊, 尹一峰, 田晓生, 卢正冠, 吴杰. 热等静压参数对Ti₂AlNb粉末合金力学性能的影响[J]. 材料研究学报, 2026, 40(9): 653-664.
[3]	张丰之, 吴云胜, 管现军, 侯介山, 周兰章. Al+Ti对一种Ni-Cr合金组织及力学性能的影响[J]. 材料研究学报, 2026, 40(9): 665-676.
[4]	郭非凡, 马继刚, 陈丽娟, 谢伟智, 魏博, 马瑞, 安田田, 李奕华, 李新月. 高氯煤烟中的氯腐蚀锅炉换热器的机理[J]. 材料研究学报, 2026, 40(9): 697-709.
[5]	刘志辉, 张世一, 邹爱华, 张凱尧, 曾卓, 张世翼, 涂嘉剑, 严旭. 激光冲击强化对 Al_xCoCrFeNi高熵合金激光熔覆层组织及耐磨性能的影响[J]. 材料研究学报, 2026, 40(9): 710-720.
[6]	胡明, 王啟睿, 邱建科, 雷晓飞, 张金虎, 董利民, 杨锐. 拉拔变形量对超高强钛合金棒材强塑性的影响[J]. 材料研究学报, 2026, 40(8): 561-571.
[7]	杨垒, 尚学文, 田晓生, 高慧颖, 徐磊. 粉末冶金热等静压工艺成形TC11合金长时间热暴露后的力学性能[J]. 材料研究学报, 2026, 40(8): 572-582.
[8]	陈尧, 陈志勇, 柏春光. Ti₂AlNb合金薄板的微观组织、织构和力学性能[J]. 材料研究学报, 2026, 40(8): 583-594.
[9]	宋肖桐, 陈思旭, 邱建科, 胡明, 张明杰, 昝晓东, 雷家峰. 热加工对紧固件用Ti55531棒材断裂韧性的影响[J]. 材料研究学报, 2026, 40(8): 595-604.
[10]	张铭原, 闻明, 李思勰, 张滨, 张广平. 制备工艺参数对磁控溅射Ni5Pt薄膜的影响[J]. 材料研究学报, 2026, 40(8): 613-623.
[11]	包方玄, 宫明龙, 刘恩瑞, 刘凤芳, 白静, 高秋志. FeCoNiCuSi _x B_{1 -}_x 高熵合金力学性能的优化和高压强化机制[J]. 材料研究学报, 2026, 40(7): 481-496.
[12]	谢贞俊, 朱艳坤, 赵振凯, 陆彦地, 周相海, 曹明, 张鹏, 张哲峰. 一种含复合夹杂物的贝马复相钢疲劳开裂机制[J]. 材料研究学报, 2026, 40(7): 519-527.
[13]	王娜, 兰中华, 屈金萌, 刘艳云, 李万喜, 刘慧超, 冯丽萍. 纤维素衍生多孔碳的制备及其电化学储能性能[J]. 材料研究学报, 2026, 40(7): 535-542.
[14]	周明晗, 陈双龙, 王秋实, 王雪娇, 刘才龙. Si₃N₄(Si₃N₄:Ho³⁺/Yb³⁺)分支纳米线的制备及其温度传感性能[J]. 材料研究学报, 2026, 40(7): 543-552.
[15]	郑沁园, 郑成武, 路轶, 朱海龙, 刘朋, 栾义坤, 李殿中. 软化退火对冷轧中锰钢再结晶和相变的影响[J]. 材料研究学报, 2026, 40(6): 401-413.

Viewed

Full text

Abstract

Cited

Shared

Discussed