<strong>BN</strong>粉体的结晶度对<strong>Cu-Si</strong>合金润湿行为的影响

doi:10.11901/1005.3093.2025.288

材料研究学报

2026, Vol. 40

Issue (6): 457-464 DOI: 10.11901/1005.3093.2025.288

研究论文

本期目录 | 过刊浏览

BN粉体的结晶度对Cu-Si合金润湿行为的影响

杨睿韬¹^,², 梁斌², 庞生洋², 胡成龙², 张伟³, 樊俊铃³, 汤素芳²(

)

^1.中国科学技术大学材料科学与工程学院沈阳 110016
^2.中国科学院金属研究所沈阳 110016
^3.中国飞机强度研究所强度与结构完整性全国重点实验室西安 710065

Wetting Behavior of Molten Cu-Si Alloy on Synthesized BN Powder of Varying Crystallinities

YANG Ruitao¹^,², LIANG Bin², PANG Shengyang², HU Chenglong², ZHANG Wei³, FAN Junling³, TANG Sufang²(

)

^1.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
^2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.National Key Laboratory of Strength and Structural Integrity, Aircraft Strength Research Institute of China, Xi'an 710065, China

引用本文:

杨睿韬, 梁斌, 庞生洋, 胡成龙, 张伟, 樊俊铃, 汤素芳. BN粉体的结晶度对Cu-Si合金润湿行为的影响[J]. 材料研究学报, 2026, 40(6): 457-464.
Ruitao YANG, Bin LIANG, Shengyang PANG, Chenglong HU, Wei ZHANG, Junling FAN, Sufang TANG. Wetting Behavior of Molten Cu-Si Alloy on Synthesized BN Powder of Varying Crystallinities[J]. Chinese Journal of Materials Research, 2026, 40(6): 457-464.

全文: PDF(5812 KB) HTML

摘要:

以硼酸和尿素为原料制备h-BN粉体，评估了在1450 ℃, h-BN与Cu-Si合金之间的润湿性和h-BN的结晶度对润湿性的影响。结果表明：在硼酸与尿素摩尔比为1∶2和氮化温度为1400 ℃条件下制备的h-BN纯度和结晶度最高。Cu-Si合金与不同结晶度的h-BN之间均不润湿，且对h-BN结晶度的变化不敏感。其原因是，h-BN的表面没有悬空键、表面能极低，且不同结晶度的h-BN的本征表面属性相似。

关键词 ：无机非金属材料, 结晶度, 润湿行为, BN, Cu-Si合金, C/SiC-Cu

Abstract：

Carbon fiber-reinforced ceramic-metal matrix composites, represented by C/SiC-Cu, show potential applications in thermal protection systems of high-speed aircraft due to their exceptional long-term oxidation and ablation resistance at ultra-high temperatures. Hexagonal boron nitride (h-BN) characterized by its hexagonal lamellar structure is an ideal interfacial material, given that it is one of the few materials that does not wet with liquid silicon and possesses excellent oxidation resistance. However, there is currently no public literature on the wetting behavior of Cu-Si alloys to h-BN material. In this study, h-BN powder was synthesized in nitrogen atmosphere with boric acid and urea as raw materials, and the wetting behavior of molten Cu-Si alloy to h-BN matrix, as well as the influence of its crystallinity on the wettability were investigated. The results indicate that among others, the h-BN synthesized at 1400 ^oC with the molar ratio of boric acid to urea is 1:2 presents the highest purity and crystallinity. While the varying crystallinities of the synthesized h-BNs show little influence on the wetting behavior of Cu-Si alloy. This can be attributed to the absence of dangling bonds on h-BN surfaces, namely, the extremely low surface energy of h-BN, and the similar intrinsic surface properties of h-BN with different crystallinity. The findings may provide a significant reference for the preparation of BN interfacial layers on carbon fiber and the regulation of properties of carbon fiber-reinforced ceramic (-metal) matrix composites.

Key words： inorganic non-metallic materials crystallinity wetting behavior BN Cu-Si alloy C/SiC-Cu

收稿日期: 2025-09-17

ZTFLH:

TB321

基金资助:国家自然科学基金(52272075);国家自然科学基金(52402095);国家自然科学基金(52472053)

通讯作者: 汤素芳，研究员，sftang@imr.ac.cn，研究方向为热防护复合材料

Corresponding author: TANG Sufang, Tel: (024)83978056, E-mail: sftang@imr.ac.cn

作者简介: 杨睿韬，女，2001年生，硕士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	杨睿韬
	梁斌
	庞生洋
	胡成龙
	张伟
	樊俊铃
	汤素芳
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2025.288 或 https://www.cjmr.org/CN/Y2026/V40/I6/457

图1 氮化温度为1000 ℃和1200 ℃，用不同摩尔比的硼酸-尿素制备的h-BN的XRD谱

图2 在不同氮化温度制备的h-BN样品的XRD谱

图3 在不同氮化温度制备的h-BN样品的拉曼光谱

图4 三种h-BN样品的XPS全谱

图5 BN1400, BN1200和BN1000样品的XPS精细谱

表1 对XPS全谱分析得到的元素组成

图6 BN1400和BN1000样品的HRTEM图像和SAED花样

图7 摩尔比为1∶2的硼酸-尿素混合物的TG-DTA曲线

图8 润湿测试过程中Cu-Si合金形貌的变化

图9 Cu-Si合金与BN1400和BN1000之间的润湿曲线

[1]	Uyanna O, Najafi H. Thermal protection systems for space vehicles: a review on technology development, current challenges and future prospects [J]. Acta Astronaut., 2020, 176: 341 doi: 10.1016/j.actaastro.2020.06.047
[2]	Patel M, Saurabh K, Prasad V V B, et al. High temperature C/C-SiC composite by liquid silicon infiltration: a literature review [J]. Bull. Mater. Sci., 2012, 35(1): 63 doi: 10.1007/s12034-011-0247-5
[3]	Zhao R D, Hu C L, Wang Y H, et al. Construction of sandwich-structured C/C-SiC and C/C-SiC-ZrC composites with good mechanical and anti-ablation properties [J]. J. Eur. Ceram. Soc., 2022, 42(4): 1219 doi: 10.1016/j.jeurceramsoc.2021.12.006
[4]	Li W, Xiang Y, Wang S, et al. Ablation behavior of three-dimensional braided C/SiC composites by oxyacetylene torch under different environments [J]. Ceram. Int., 2013, 39(1): 463 doi: 10.1016/j.ceramint.2012.06.049
[5]	Liu L, Li H J, Feng W, et al. Effect of surface ablation products on the ablation resistance of C/C-SiC composites under oxyacetylene torch [J]. Corros. Sci., 2013, 67: 60 doi: 10.1016/j.corsci.2012.10.003
[6]	Wu Y, Zhao R D, Liang B, et al. Construction of C/SiC-Cu₃Si-Cu interpenetrating composites for long-duration thermal protection at 2500 ^oC by cooperative active-passive cooling [J]. Composites, 2023, 266B: 111015
[7]	Wang P, Zhang H B, Yin J, et al. Effect of pyrolytic carbon interface thickness on conductivity and mechanical and wear properties of copper mesh modified carbon/carbon composite [J]. Mater. Des., 2018, 154: 302 doi: 10.1016/j.matdes.2018.05.031
[8]	Wu Y, Liang B, Zhao R D, et al. Fracture mechanical and ablation behaviors of C/SiC-Cu₃Si-Cu interpenetrating composites and their dependence on metal addition and interface thickness [J]. Composites, 2024, 283B: 111632
[9]	Drevet B, Eustathopoulos N. Wetting of ceramics by molten silicon and silicon alloys: a review [J]. J. Mater. Sci., 2012, 47(24): 8247 doi: 10.1007/s10853-012-6663-0
[10]	Drevet B, Voytovych R, Israel R, et al. Wetting and adhesion of Si on Si₃N₄ and BN substrates [J]. J. Eur. Ceram. Soc., 2009, 29(11): 2363 doi: 10.1016/j.jeurceramsoc.2009.01.024
[11]	Polkowski W, Sobczak N, Polkowska A, et al. Silicon as a phase change material: performance of h-BN ceramic during multi-cycle melting/solidification of silicon [J]. JOM, 2019, 71(4): 1492 doi: 10.1007/s11837-019-03364-4
[12]	Polkowski W, Sobczak N, Nowak R, et al. Wetting behavior and reactivity of molten silicon with h-BN substrate at ultrahigh temperatures up to 1750 ^oC [J]. J. Mater. Eng. Perform., 2018, 27(spec. issue10) : 5040
[13]	Li J Z, Zhang L T, Cheng L F, et al. Interfacial zone in continuous fiber-reinforced ceramic composites [J]. Rare Met. Mater. Eng., 2007, 36(9): 1539
[13]	李建章, 张立同, 成来飞等. 纤维增韧碳化硅陶瓷基复合材料的界面区研究 [J]. 稀有金属材料与工程, 2007, 36(9): 1539
[14]	Li J S, Zhang C R, Li B. Advances in boron nitride interphases in ceramic matrix composites [J]. Mater. Rev., 2011, 25A(9) : 14
[14]	李俊生, 张长瑞, 李斌. 陶瓷基复合材料中氮化硼界面相研究进展 [J]. 材料导报, 2011, 25A(9) : 14
[15]	Jiang L Y, Pang S Y, Yang C, et al. Preparation and oxidation behaviors of C/SiC-BN composites [J]. J. Inorg. Mater., 2024, 39(7): 779 doi: 10.15541/jim20230583
[15]	姜灵毅, 庞生洋, 杨超等. C/SiC-BN复合材料的制备及氧化行为 [J]. 无机材料学报, 2024, 39(7): 779
[16]	Niu Z B, Xiao P, Li Z, et al. Effects of h-BN particles on the structure, oxidation behaviour, and kinetics of C/C composites fabricated via CVI [J]. Corros. Sci., 2021, 178: 109059 doi: 10.1016/j.corsci.2020.109059
[17]	Xiao P, Liu Z Y, Li Z C, et al. Oxidation behavior of carbon/carbon-boron nitride composites fabricated by additives and chemical vapor infiltration [J]. Ceram. Int., 2019, 45(4): 4335 doi: 10.1016/j.ceramint.2018.11.108
[18]	Ding D H, Zhou W C, Luo F, et al. Dip-coating of boron nitride interphase and its effects on mechanical properties of SiC_f/SiC composites [J]. Mater. Sci. Eng., 2012, 543A: 1
[19]	Ghanbarian M, Nassaj E T, Kariminejad A. Synthesis of nanostructural turbostratic and hexagonal boron nitride coatings on carbon fiber cloths by dip-coating [J]. Surf. Coat. Technol., 2016, 288: 185 doi: 10.1016/j.surfcoat.2016.01.011
[20]	Liu H T, Tian H. Mechanical and microwave dielectric properties of SiCf/SiC composites with BN interphase prepared by dip-coating process [J]. J. Eur. Ceram. Soc., 2012, 32(10): 2505 doi: 10.1016/j.jeurceramsoc.2012.02.009
[21]	Pankajavalli R, Anthonysamy S, Ananthasivan K, et al. Vapour pressure and standard enthalpy of sublimation of H₃BO₃ [J]. J. Nucl. Mater., 2007, 362(1): 128 doi: 10.1016/j.jnucmat.2006.12.025
[22]	Zheng Y, Wang S B. Synthesis of boron nitride coatings on quartz fibers: thickness control and mechanism research [J]. Appl. Surf. Sci., 2011, 257(24): 10752
[23]	Zhong B, Cheng Y J, Wang M, et al. Three dimensional hexagonal boron nitride nanosheet/carbon nanotube composites with light weight and enhanced microwave absorption performance [J]. Composites, 2018, 112A: 515
[24]	Roy S, Zhang X, Puthirath A B, et al. Structure, properties and applications of two-dimensional hexagonal boron nitride [J]. Adv. Mater., 2021, 33(44): 2101589 doi: 10.1002/adma.v33.44
[25]	Wang J G, Ma F C, Sun M T. Graphene, hexagonal boron nitride, and their heterostructures: properties and applications [J]. RSC Adv., 2017, 7(27): 16801 doi: 10.1039/C7RA00260B
[26]	Adachi M, Schick M, Brillo J, et al. Surface tension and density measurement of liquid Si-Cu binary alloys [J]. J. Mater. Sci., 2010, 45(spec. issue8) : 2002

[1]	尹晓彤, 田雨欣, 冯盛, 李文颖, 王立兴, 张丽娜, 张伟. Sb₂S₃/Sn₃O₄ S型异质结构光催化剂的制备及其降解甲基橙的性能[J]. 材料研究学报, 2026, 40(5): 352-360.
[2]	张志凯, 雷佳双, 姚冰亚, 陈思雨, 刘硕, 孙玉伟, 汤茜. CuFe₂O₄/BaTiO₃ 复合材料的制备及其降解四环素的性能[J]. 材料研究学报, 2026, 40(5): 361-371.
[3]	赵睿泽, 田俐, 宋佩媛, 方瑶, 孙萌, 樊赛男, 欧治民, 朱海博, 黄容姣, 阳立. 稀土镧离子掺杂二氧化钒的制备和电化学性能[J]. 材料研究学报, 2026, 40(4): 313-320.
[4]	邹俊, 赵润, 戴称民. WSe₂/BiFeO₃/Q2DEG混合异质结的光电性能[J]. 材料研究学报, 2026, 40(3): 210-216.
[5]	韩扬, 李梦晨, 于宏悦, 乔亮, 沈雨歌, 高善彬, 矫义来, 迟克彬. 多级孔ZSM-22分子筛的合成及其正十二烷加氢异构化性能[J]. 材料研究学报, 2026, 40(1): 1-12.
[6]	詹杰, 陈小江, 邹之利, 苏兴东, 谢世宇, 江亮, 王金铃, 王烈林. 纳米Ag⁰@ACF材料的制备及其对气态碘的吸附性能[J]. 材料研究学报, 2025, 39(9): 673-682.
[7]	施渊吉, 程诚, 张海涛, 胡道春, 陈晶晶, 黎军顽. β-SiC半导体器件在滑动摩擦中材料去除行为的纳观分析[J]. 材料研究学报, 2025, 39(9): 701-711.
[8]	周影影, 张瑛嫺, 淡卓娅, 杜旭, 杜浩楠, 甄恩远, 罗发. 掺杂La对YFeO₃ 陶瓷吸波性能的影响[J]. 材料研究学报, 2025, 39(8): 561-568.
[9]	耿瑞文, 杨志豇, 杨蔚华, 谢启明, 游津京, 李立军, 吴海华. 6H-SiC纳米磨削亚表面损伤机理的分子动力学研究[J]. 材料研究学报, 2025, 39(8): 603-611.
[10]	陆通, 王亚娜, 张超, 雷芃, 张鸿荣, 黄光伟, 郑立允. BN掺杂对热变形钕铁硼磁体性能的影响[J]. 材料研究学报, 2025, 39(8): 612-618.
[11]	刘志华, 王明月, 李易娟, 丘一帆, 李翔, 苏伟钊. 1T/2H O-MoS₂@S-pCN催化剂的制备和性能[J]. 材料研究学报, 2025, 39(7): 551-560.
[12]	韩磊磊, 王文涛, 吴赟, 陈嘉俊, 赵勇. 无氟化学溶液法制备YBCO超导焊料的高温生长工艺研究[J]. 材料研究学报, 2025, 39(6): 474-480.
[13]	袁新雨, 史非, 刘敬肖, 张皓杰, 杨大毅, 王美玉, 任明. Er₂O₃ 对二硅酸锂玻璃陶瓷的结构和性能的影响[J]. 材料研究学报, 2025, 39(6): 455-462.
[14]	陈室雨, 李卫, 旷海燕, 高绍巍, 庞东方. 一种稀土Lu³⁺ 掺杂无铅压电陶瓷的介电、铁电和压电性能[J]. 材料研究学报, 2025, 39(4): 272-280.
[15]	李泓霄, 李焕勇, 张炫. β-ZnS透明陶瓷的制备及相生成机理[J]. 材料研究学报, 2025, 39(12): 927-934.

Viewed

Full text

Abstract

Cited

Shared

Discussed