MOFs Derived C/LDH/rGO Network Composite Materials for High Specific Capacity High-performance Aqueous Zinc Ion Capacitors

doi:10.11901/1005.3093.2024.328

Chinese Journal of Materials Research

2025, Vol. 39

Issue (5): 371-376 DOI: 10.11901/1005.3093.2024.328

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MOFs Derived C/LDH/rGO Network Composite Materials for High Specific Capacity High-performance Aqueous Zinc Ion Capacitors

LIU Yanyun¹(

), WANG Na¹, ZHANG Zhihua², BAI Wen¹, LIU Yunjie¹, CHEN Yongqiang³, LI Wanxi¹, LI Yu¹

^1.Department of Materials Science and Engineering, Jinzhong University, Jinzhong 030619, China
^2.Customs Technology Center of Taiyuan, Taiyuan 030006, China
^3.Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong 030619, China

Cite this article:

LIU Yanyun, WANG Na, ZHANG Zhihua, BAI Wen, LIU Yunjie, CHEN Yongqiang, LI Wanxi, LI Yu. MOFs Derived C/LDH/rGO Network Composite Materials for High Specific Capacity High-performance Aqueous Zinc Ion Capacitors. Chinese Journal of Materials Research, 2025, 39(5): 371-376.

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Abstract

Aqueous Zn ion hybrid capacitors (ZICs), as an emerging energy storage device with low cost, high operational safety and low redox potential, have become a research hotspot in the field of energy storage. This paper focuses on the important research of low energy density of capacitor electrode materials in ZICs. Metal-organic frameworks (MOFs)-derived carbon (C)/layered double hydroxides (LDH)/graphene (rGO) network composite materials with self-supporting characteristics are designed and synthesized. The structure and morphology of the material were characterized by X-ray diffractometer, scanning electron microscope and X-ray photoelectron spectroscopy. The results showed that the MOFs-derived C/ Ni-Co LDH particles were granular structure, dispersed on lamellae of the rGO, forming a network composite material. The specific capacitance of the Zn ion capacitor assembled by this material can reach 248 F·g^-1 at a current density of 1.0 A·g^-1, which is much larger than the specific capacitance of rGO (142 F·g^-1). After 1500 cycles, the capacitance retention rate of the Zn ion capacitor is still as high as 97.1%. The network structure not only provides more transmission channels for electrolyte ions, but also provides more pseudocapacitive active sites. The completion of this paper provides some theoretical guidance and practical significance for the development of high specific energy storage devices.

Key words: composite materials zinc ion capacitors hydrothermal method energy density

Received: 25 July 2024

ZTFLH:

TB383

Fund: Shanxi Province Basic Research Free Exploration Project(202103021224307);Postgraduate Education Innovation Plan Project(2021YJG336);Shanxi Province Science and Technology Innovation Youth Talent Team

Corresponding Authors: LIU Yanyun, Tel: 15698402116, E-mail: 312217642@qq.com

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	LIU Yanyun
	WANG Na
	ZHANG Zhihua
	BAI Wen
	LIU Yunjie
	CHEN Yongqiang
	LI Wanxi
	LI Yu

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https://www.cjmr.org/EN/10.11901/1005.3093.2024.328 OR https://www.cjmr.org/EN/Y2025/V39/I5/371

Fig.1 Preparation flow chart of MOFs derived C/LDH/rGO network composite materials

Fig.2 XRD (a), SEM (b~d) and EDS mapping images (e~h) of MOFs derived C/LDH/rGO network composite materials

Fig.3 XPS spectra of MOFs derived C/LDH/rGO network composite materials
(a) full spectrum, (b) C 1s spectrum, (c) Co 2p spectrum, (d) O 1s spectrum

Fig.4 Zinc ion capacitor assembled by MOFs derived C /LDH /rGO network composite materials
(a) Reaction process simulation diagram, (b) CV curves under different scanning rate, (c) Capacitance contribution CV curve at a scanning rate of 5 mV/s, (d) The proportion of surface-controlled capacitance contribution and diffusion-controlled contribution at different scanning rates, (e) CP curves at different current densities, (f) The relationship between electrode specific capacity and current densities

Fig.5 Comparison of zinc ion capacitors assembled by MOFs derived C/LDH/rGO network composite materials and rGO
(a) CP curves of two devices (current density of 1 A/g), (b) Cycle life diagram of two devices, (c) EIS curves of zinc ion capacitors assembled by MOFs derived C/LDH/rGO network composite materials

1	Xia Y, Mathis T S, Zhao M Q, et al. Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes [J]. Nature, 2018, 557(7705): 409
2	Kundu D, Adams B D, Duﬀort V, et al. A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode [J]. Nat. Energy, 2016, 1(10): 16119
3	Bi S, Banda H, Chen M, et al. Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes [J]. Nat. Mater., 2020, 19(5): 552 doi: 10.1038/s41563-019-0598-7 pmid: 32015536
4	Liu Y, Chen P, Zhou X, et al. Preparation and electrochemical properties of hollow FeS₂/NiS₂/Ni₃S₂@NC cube composites [J]. Chin. J. Mater. Res., 2024, 38(6): 453
	刘莹, 陈平, 周雪等. 中空FeS₂/NiS₂/Ni₃S₂@NC立方体复合材料的制备及其电化学性能 [J]. 材料研究学报, 2024, 38(6): 453
5	Lin M C, Gong M, Lu B, et al. An ultrafast rechargeable aluminium-ion battery [J]. Nature, 2015, 520(4): 325
6	Simon P, Gogotsi Y, Materials for electrochemical capacitors[J]. Nat. Mater., 2008, 7(11): 845 doi: 10.1038/nmat2297 pmid: 18956000
7	Ding J, Hu W, Paek E D, et al. Review of hybrid ion capacitors: from aqueous to lithium to sodium [J]. Chem. Rev., 2018, 118(6): 6457
8	Etacheri V, Marom R, Elazari R, et al. Challenges in the development of advanced Li-ion batteries: a review [J]. Energy Environ. Sci., 2011, 4(9): 3243
9	Tang H, Yao J, Zhu Y, et al. Recent developments and future prospects for zinc‐ion hybrid capacitors: a review [J]. Adv. Energy Mater., 2021, 11: 2003994
10	Fang G, Zhou J, Pan A, et al. Recent advances in aqueous zinc-ion batteries [J]. ACS Energy Lett., 2018, 3(7): 2480
11	Tang B, Shan L, Liang S, et al. Issues and opportunities facing aqueous zinc-ion batteries [J]. J. Energy Environ. Sci., 2019, 12(11): 3288
12	An G, Hong J S, Pak Y, et al. 2D metal Zn nanostructure electrodes for high‐performance Zn ion supercapacitors [J]. Adv. Energy Mater., 2020, 10: 1902981
13	Zhu Y, Murali S, Stoller M D, et al. Carbon-based supercapacitors produced by activation of graphene [J]. Science, 2011, 332(6037): 1537 doi: 10.1126/science.1200770 pmid: 21566159
14	Wang B, Zhao J, Zhang D H, et al. Three-dimensional porous carbon framework coated with one-dimensional nanostructured polyaniline nanowires composite for high performance supercapacitors [J]. Appl. Surf. Sci., 2019, 474(30): 147
15	Simon P, Gogotsi Y, Materials for electrochemical capacitors[J]. Nat. Mater. 2008, 7(11): 845 doi: 10.1038/nmat2297 pmid: 18956000
16	Kolleboyina J, Michael H, Andreas S, et al. Covalent graphene-MOF hybrids for high-performance asymmetric supercapacitors [J]. Adv. Mater., 2021, 33: 2004560
17	Pan Z, Jiang Y, Yang P, et al. In Situ Growth of layered bimetallic ZnCo hydroxide nanosheets for high-performance all-solid-state pseudocapacitor [J]. ACS Nano, 2018, 12: 2968
18	Kandula S, Shrestha K, Rajeshkhanna R, et al. Kirkendall growth and ostwald ripening induced hierarchical morphology of Ni-Co LDH/MMoSx (M = Co, Ni, and Zn) heteronanostructures as advanced electrode materials for asymmetric solid-state supercapacitors [J]. ACS Appl Mater Interfaces, 2019, 11(12): 11555
19	Du Q, Su L, Hou L, et al. Rationally designed ultrathin Ni-Al layered double hydroxide and graphene heterostructure for high-performance asymmetric supercapacitor [J]. J. Alloy. Compd., 2018, 740: 1051
20	Hummers W S, Offeman R E, Preparation of graphitic oxide [J]. J. Amer. Chem. Soc., 1958, 80: 1339
21	Liu Y Y, Li W X, Chen Y Q, of MOF derivatives@Synthesis3D graphene hybrid materials towards high-performance electrode material for supercapacitors [J]. J. Mater. Sci.: Mater. Electron, 2022, 33:6514
22	Liu Y Y, Ma L, Chen Y Q, A simple one-step approach for preparing flexible rGO-MnO2 electrode material [J]. J. Mater. Sci.: Mater. Electron, 2018, 29: 17438
23	Zhu Y L, Du W, Zhang Q L, A metal-organic framework template derived hierarchical Mo-doped LDHs@ MOF-Se core-shell array electrode for supercapacitors [J]. Chem. Commun., 2020, 56: 13848
24	Jayaramulu K, Horn M, Schneemann A, et al. Covalent graphene‐MOF hybrids for high‐performance asymmetric supercapacitors [J]. Adv. Mater., 2021, 33: 2004560
25	Brezesinski T, Wang J, Tolbert S H, et al. Ordered mesoporous α-MoO₃ with iso-oriented nanocrystalline walls for thin-film pseudocapacitors [J]. Nat. Mater., 2010, 9: 146 doi: 10.1038/nmat2612 pmid: 20062048

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