Preparation and Electrochemical Properties of Hollow FeS2/NiS2/Ni3S2@NC Cube Composites

doi:10.11901/1005.3093.2023.261

Chinese Journal of Materials Research

2024, Vol. 38

Issue (6): 453-462 DOI: 10.11901/1005.3093.2023.261

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Preparation and Electrochemical Properties of Hollow FeS₂/NiS₂/Ni₃S₂@NC Cube Composites

LIU Ying, CHEN Ping(

), ZHOU Xue, SUN Xiaojie, WANG Ruiqi

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Cite this article:

LIU Ying, CHEN Ping, ZHOU Xue, SUN Xiaojie, WANG Ruiqi. Preparation and Electrochemical Properties of Hollow FeS₂/NiS₂/Ni₃S₂@NC Cube Composites. Chinese Journal of Materials Research, 2024, 38(6): 453-462.

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Abstract

A novel composite hollow FeS₂/NiS₂/Ni₃S₂@NC cube is synthesized through collaborative etch-precipitation (CEP) route, high-temperature calcination, polydopamine coating and high-temperature vulcanization with a pre-prepared Cu₂O cube as sacrificial template. The preparation process is safe, while Ni and Fe are successfully incorporated through the CEP route. The hollow cube structure can effectively restrain the volume expansion and slow down the mechanical stress caused by lithium-ion embedding and release. The introduction of N-doped carbon layer (NC) can greatly improve the conductivity and structural stability of the composite material, so that it can better maintain the stability of the cube structure. Furthermore, after 100 cycles at a current density of 0.2 A·g^-1, the specific discharge capacity of the FeS₂/NiS₂/Ni₃S₂@NC cube composite can be maintained at 899.4 mAh·g^-1, showing high specific capacity, good cycle stability, and great rate performance (427.5 mAh·g^-1 at 3.0 A·g^-1).

Key words: composite lithium-ion batteries anode materials transition metal sulfides

Received: 17 May 2023

ZTFLH:

TM 912

Fund: Liaoning Revitalization Talents Program(XLYC1802085);National Natural Science Foundation of China(51873109);Dalian Science and Technology Innovation Fund Project(2019J11CY007)

Corresponding Authors: CHEN Ping, Tel: (0411)84986100, E-mail: pchen@dlut.edu.cn

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	LIU Ying
	CHEN Ping
	ZHOU Xue
	SUN Xiaojie
	WANG Ruiqi

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https://www.cjmr.org/EN/10.11901/1005.3093.2023.261 OR https://www.cjmr.org/EN/Y2024/V38/I6/453

Fig.1 Schematic diagram of preparation of hollow FeS₂/NiS₂/Ni₃S₂@NC cube

Fig.2 XRD patterns of Cu₂O (a), XRD patterns of NF-OH and NFO (b), XRD patterns of FeS₂/NiS₂/Ni₃S₂@NC and FeS₂/NiS₂/Ni₃S₂ (c) and Raman spectra of FeS₂/NiS₂/Ni₃S₂@NC (d)

Fig.3 IR spectra (a) and N₂ absorption/desorption isotherm and pore size distribution curve (b) of FeS₂/NiS₂/Ni₃S₂@NC

Fig.4 Survey scan of FeS₂/NiS₂/Ni₃S₂@NC (a) and XPS high-resolution spectrum of Ni 2p (b), Fe 2p (c), S 2p (d), C 1s (e), N 1s (f)

Fig.5 SEM images of Cu₂O (a), NF-OH (b), FeS₂/NiS₂/Ni₃S₂ (c), FeS₂/NiS₂/Ni₃S₂@NC (d)

Fig.6 TEM images of FeS₂/NiS₂/Ni₃S₂@NC with different magnifications (a, b), HRTEM image of FeS₂/NiS₂/Ni₃S₂@NC (c) and and corresponding EDS elemental mapping images (d) of FeS₂/NiS₂/Ni₃S₂@NC

Fig.7 CV curves of FeS₂/NiS₂/Ni₃S₂@NC at the scan rate of 0.1 mV·s^-1 (a), GCD profiles of FeS₂/NiS₂/Ni₃S₂@NC for the 1st, 2nd, 5th, 10th, 50th and 100th cycles at the current density of 0.2 A·g^-1 (b), the rate capability (c) and the cycling performance (d) at the current density of 0.2 A·g^-1 of FeS₂/NiS₂/Ni₃S₂@NC and FeS₂/NiS₂/Ni₃S₂

Fig.8 Composion at the current density of 1.0 A·g^-1 after 500 cycles of FeS₂/NiS₂/Ni₃S₂@NC and FeS₂/NiS₂/Ni₃S₂

Fig.9 EIS spectra of FeS₂/NiS₂/Ni₃S₂@NC and FeS₂/NiS₂/Ni₃S₂(a) before the cycle and FeS₂/NiS₂/Ni₃S₂@NC after 100 cycles (b)

Fig.10 CV curves of FeS₂/NiS₂/Ni₃S₂@NC at various scan rates (a), the ratios of lg(i) to lg(ʋ) at different oxidation/reduction peaks (b), the contribution of capacitance and diffusion controlled capacitance at different scan rates (c), the proportions of capacitance in the total charge contribution (d) at a scan rate of 0.8 mV·s^-1

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