Structure and Properties of Cu2O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy

doi:10.11901/1005.3093.2021.411

Chinese Journal of Materials Research

2022, Vol. 36

Issue (6): 409-415 DOI: 10.11901/1005.3093.2021.411

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Structure and Properties of Cu₂O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy

GAO Wei, LIU Jiangnan, WEI Jingpeng, YAO Yuhong, YANG Wei(

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School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China

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GAO Wei, LIU Jiangnan, WEI Jingpeng, YAO Yuhong, YANG Wei. Structure and Properties of Cu₂O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy. Chinese Journal of Materials Research, 2022, 36(6): 409-415.

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Abstract

The microarc oxidation coating doped with coprous oxide was prepared on the surface of TC4 Ti-alloy by adding different amount of cuprous oxide particles into the electrolyte. The microstructure and properties of the cuprous oxide doped microarc oxidation coating were investigated by means of scanning electron microscope (SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscope (XPS) and microhardness tester. The results show that the surface of the microarc oxidation coating doped with cuprous oxide is porous, but the number and size of micropores are small. However the doped Cu oxides are present in the coating in two forms, namely copper oxide and cuprous oxide. Compared with the microarc oxidation coating without doping of cuprous oxide, the wear resistance and antibacterial performance of microarc oxidation coating doped with different amount of cuprous oxide are significantly improved in artifitial seawater, but their corrosion resistance degraded.

Key words: materials failure and protection titanium alloy micro arc oxidation Cu₂O microstructure performance

Received: 16 July 2021

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52071252)

About author: YANG Wei, Tel: 18710688527, E-mail: yangwei_smx@163.com

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.411 OR https://www.cjmr.org/EN/Y2022/V36/I6/409

Fig.1 SEM morphologies of micro arc oxidation coatings on TC4 prepared by different concentrations of Cu₂O (a) 0 g/L; (b) 2 g/L; (c) 6 g/L; (d) 10 g/L

Table 1 EDS results of micro arc oxidation coatings prepared by different concentrations of Cu₂O on TC4 (mass fraction, %)

Fig.2 XRD pattern of micro arc oxidation coatings prepared by different concentrations of Cu₂O on TC4

Fig.3 XPS spectrum of micro arc oxidation coating with 6 g/L Cu₂O addition (a) XPS spetrum; (b) Cu2p high resolution spectra; (c) Ti2p high resolution spectra; (d) Si2p high resolution spectra

Fig.4 Friction curve of micro arc oxidation coatings prepared by adding different concentrations of Cu₂O

Fig.5 SEM and EDS results of micro arc oxidation coating prepared by adding different concentrations of Cu₂O on TC4 (a) 0 g/L; (b) 2 g/L; (c) 6 g/L; (d) 10 g/L

Fig.6 Weight loss curve of micro arc oxidation coatings prepared by different concentration of Cu₂O

Fig.7 Adhesion morphologies of Staphylococcus aureus in micro arc oxidation coatings prepared by adding different concentrations of Cu₂O on TC4 (a) 0 g/L; (b) 2 g/L; (c) 6 g/L; (d) 10 g/L

Table 2 OD value of Staphylococcus aureus cultured on Cu₂O doped MAO coatings for 3 days

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