Preparation and Microwave Absorption Properties of Magnetic Porous RGO@Ni Composites

doi:10.11901/1005.3093.2020.202

Chinese Journal of Materials Research

2020, Vol. 34

Issue (9): 641-649 DOI: 10.11901/1005.3093.2020.202

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Preparation and Microwave Absorption Properties of Magnetic Porous RGO@Ni Composites

LIU Jialiang¹, CHEN Ping¹^,²(

), XU Dongwei¹, YU Qi³

1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
2. Key Laboratory of Materials Modification by Laser, Ion and Electron Beams of Ministry of Education, Dalian University of Technology, Dalian 116024, China
3. Liaoning Key Laboratory of Advanced Polymer Matrix Composites, Shenyang Aerospace University, Shenyang 110136, China

Cite this article:

LIU Jialiang, CHEN Ping, XU Dongwei, YU Qi. Preparation and Microwave Absorption Properties of Magnetic Porous RGO@Ni Composites. Chinese Journal of Materials Research, 2020, 34(9): 641-649.

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Abstract

An economic and green approach for the controllable synthesis of porous functionalized graphene materials as microwave absorbers was proposed in this paper. POROUS RGO@Ni nanocomposites were synthesized by a simple one-pot method based on solvothermal treatment of Ni(acac)₂ and graphene oxide without adding additional reducing agents. The structure and morphology of the as-prepared hybrid materials were characterized by XRD, Raman spectroscopy, XPS, VSM, SEM and TEM. The results show that uniform Ni spheres of about 900 nm in diameter homogeneously distributed on graphene sheets and form a porous structure. The electromagnetic data demonstrated that RGO@Ni nanocomposites exhibited significantly excellent electromagnetic wave (EMW) absorption properties, probably originating from the unique 3D porous structure and synergistic effect. The minimum reflection loss (RL_min) and maximum effective absorption bandwidth (EAB) of RGO@Ni nanocomposites are -61.2 dB and 6.6 GHz, respectively.

Key words: composite electromagnetic wave absorption performance solvothermal three-dimensional grapheme magnetic nanoparticles

Received: 28 May 2020

ZTFLH:

TB332

Fund: National Natural Science Foundation of China(51303106);Dalian Science and Technology Innovation Fund Project(2019J11CY007);Fundamental Research Funds for the Central Universities(DUT20TD207);Liaoning Revitalization Talents Program(XLYC1807003);Liaoning Revitalization Talents Program(XLYC1802085);Key Laboratory of Materials Modification by Laser, Ion and Electron Beams of Ministry of Education(KF2004)

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	Jialiang LIU
	Ping CHEN
	Dongwei XU
	Qi YU

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.202 OR https://www.cjmr.org/EN/Y2020/V34/I9/641

Fig.1 Schematic illustration for the formation of the porous magnetic RGO@Ni nanocomposites

Fig.2 XRD patterns of RGO, Ni microspheres, RGO@Ni nanocomposites

Fig.3 Raman spectra of graphite, GO, RGO@Ni nanocomposites

Fig.4 XPS full spectrum of RGO@Ni (a), Ni 2p spectrum of RGO@Ni (b), C 1s spectrum of RGO@Ni (c) and C 1s spectrum of GO (d)

Fig.5 SEM (a, b) and TEM (c, d) of RGO@Ni

Fig.6 Three-dimensional representation of RL values for pure Ni (a); RGO (b); RGO@Ni (c) and RL values for Ni, RGO, RGO@Ni at 2.2 mm (d)

Fig.7 Relative complex permittivity and relative complex permeability (a) real part (ε′)； (b) imaginary part (ε″)； (c) real part (μ′) and (d) imaginary part (μ″)

Fig.8 dielectric loss tangent (tanδ_ε) (a), magnetic loss tangent (tanδ_μ) (b), Cole-Cole semicircles (ε′ versus ε″) (c~e) and C₀ versus f in the range of 1~18 GHz (f)

Fig.9 Attenuation constant and Impedance matching ratio of Ni、RGO and RGO@Ni composites

[1]	Liu T, Pang Y, Zhu M, et al. Microporous Co@CoO nanoparticles with superior microwave absorption properties [J]. Nanoscale, 2014, 6: 2447 doi: 10.1039/c3nr05238a pmid: 24452196
[2]	Ma X H, Li Y, Shen B, et al. Carbon composite networks with ultrathin skin layers of graphene film for exceptional electromagnetic interference shielding [J]. ACS Appl. Mater. Interfaces, 2018, 10: 38255 doi: 10.1021/acsami.8b15545 pmid: 30360062
[3]	Song W L, Guan X T, Fan L Z, et al. Magnetic and conductive graphene papers toward thin layers of effective electromagnetic shielding [J]. J. Mater. Chem., 2015, 3A: 2097
[4]	Li X Y, Huang X L, Liu D P, et al. Synthesis of 3D hierarchical Fe₃O₄/Graphene composites with high lithium storage capacity and for controlled drug delivery [J]. J. Phys. Chem., 2011, 115C: 21567
[5]	Xu D W, Xiong X H, Chen P, et al. Superior corrosion-resistant 3D porous magnetic graphene foam-ferrite nanocomposite with tunable electromagnetic wave absorption properties [J]. J. Magn. Magn. Mater., 2019, 469: 428
[6]	Zeng Q, Xiong X H, Chen P, et al. Air@rGO€Fe₃O₄ microspheres with spongy shells: self-assembly and microwave absorption performance [J]. J. Mater. Chem., 2016, 4C: 10518
[7]	Zeng Q, Chen P, Yu Q, et al. Self-assembly of graphene hollow microspheres with wideband and controllable microwave absorption properties [J]. Chin. J. Mater. Res., 2018, 32: 119
	(曾强, 陈平, 于祺等. 具有宽频与可控微波吸收性能的石墨烯空心微球的自组装 [J]. 材料研究学报, 2018, 32: 119)
[8]	Chu H R, Chen P, Yu Q, et al. Preparation and microwave absorption properties of FeCo/Graphene [J]. Chin. J. Mater. Res., 2018, 32: 161
	(褚海荣, 陈平, 于祺等. FeCo/石墨烯的制备和吸波性能 [J]. 材料研究学报, 2018, 32: 161)
[9]	Liu J, Cao M S, Luo Q, et al. Electromagnetic property and tunable microwave absorption of 3D nets from nickel chains at elevated temperature [J]. ACS. Appl. Mater. Interfaces, 2016, 8: 22615 pmid: 27509241
[10]	Liu P B, Huang Y. Decoration of reduced graphene oxide with polyaniline film and their enhanced microwave absorption properties [J]. J. Polym. Res., 2014, 21: 430
[11]	Qiu B C, Xing M Y, Zhang J L. Recent advances in three-dimensional graphene based materials for catalysis applications [J]. Chem. Soc. Rev., 2018, 47: 2165 doi: 10.1039/c7cs00904f pmid: 29412198
[12]	Han M K, Yin X W, Kong L, et al. Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties [J]. J. Mater. Chem., 2014, 2A: 16403
[13]	Kim T Y, Jung G, Yoo S, et al. Activated graphene-based carbons as supercapacitor electrodes with macro- and mesopores [J]. ACS Nano, 2013, 7: 6899 doi: 10.1021/nn402077v pmid: 23829569
[14]	Tong G X, Hu Q, Wu W H, et al. Submicrometer-sized NiO octahedra: facile one-pot solid synthesis, formation mechanism, and chemical conversion into Ni octahedra with excellent microwave-absorbing properties [J]. J. Mater. Chem., 2012, 22: 17494 doi: 10.1039/c2jm31790g
[15]	Li Z X, Li X H, Zong Y, et al. Solvothermal synthesis of nitrogen-doped graphene decorated by superparamagnetic Fe₃O₄ nanoparticles and their applications as enhanced synergistic microwave absorbers [J]. Carbon, 2017, 115: 493
[16]	Chu H R, Zeng Q, Chen P, et al. Synthesis and electromagnetic wave absorption properties of matrimony vine-like iron oxide/reduced graphene oxide prepared by a facile method [J]. J. Alloys Compd., 2017, 719: 296 doi: 10.1016/j.jallcom.2017.05.199
[17]	Lv H L, Ji G B, Liu W, et al. Achieving hierarchical hollow carbon@Fe@Fe₃O₄ nanospheres with superior microwave absorption properties and lightweight features [J]. J. Mater. Chem., 2015, 3C: 10232
[18]	Zong M, Huang Y, Zhao Y, et al. Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO-Fe₃O₄ composites [J]. RSC Adv., 2013, 3: 23638
[19]	Zhou M, Zhang X, Wei J M, et al. Morphology-controlled synthesis and novel microwave absorption properties of hollow urchinlike α-MnO₂ nanostructures [J]. J. Phys. Chem., 2011, 115C: 1398
[20]	Sun G B, Dong B X, Cao M H, et al. Hierarchical dendrite-like magnetic materials of Fe₃O₄, γ-Fe₂O₃ and Fe with high performance of microwave absorption [J]. Chem. Mater., 2011, 23: 1587
[21]	Zhao B, Guo X Q, Zhao W Y, et al. Facile synthesis of yolk–shell Ni@void@SnO₂(Ni₃Sn₂) ternary composites via galvanic replacement/kirkendall effect and their enhanced microwave absorption properties [J]. Nano Res., 2017, 10: 331
[22]	Wu Z C, Tian K, Huang T, et al. Hierarchically porous carbons derived from biomasses with excellent microwave absorption performance [J]. ACS Appl. Mater. Interfaces, 2018, 10: 11108 pmid: 29514457

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