Preparation of Si-containing Benzoxazine and Its Influence on Curing Reaction Kinetics of Bismaleimide Ester Resin

doi:10.11901/1005.3093.2019.475

Chinese Journal of Materials Research

2020, Vol. 34

Issue (6): 459-465 DOI: 10.11901/1005.3093.2019.475

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Preparation of Si-containing Benzoxazine and Its Influence on Curing Reaction Kinetics of Bismaleimide Ester Resin

JIA Yuan¹, ZHANG Liying¹, MA Mingyang¹(

), SHI Ruifeng²

1.College of Chemical Engineering, Xi'an University, Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, Xi’an 710065，China
2.School of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi 'an 710054, China

Cite this article:

JIA Yuan, ZHANG Liying, MA Mingyang, SHI Ruifeng. Preparation of Si-containing Benzoxazine and Its Influence on Curing Reaction Kinetics of Bismaleimide Ester Resin. Chinese Journal of Materials Research, 2020, 34(6): 459-465.

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Abstract

A new Si-containing BOZ resin monomer (Si-BOZ) was prepared via chemical synthesis method, which was then used as the modifier to blend with BMI, so that to yield the BMI prepolymer with lower viscosity, and the modified BMI resin can also exhibits excellent heat resistance, radiation resistance and mechanical properties. The gelation time of Si-BOZ, BMI, Si-BOZ/BMI resin was studied by plate small knife method, the chemical reactions of Si-BOZ and BMI during curing process were studied by FTIR, and the effect of the addition of Si-BOZ on the curing reaction kinetics of BMI was studied by non-isothermal scanning calorimetry (DSC). The role of parameters in the curing process was also discussed by Kissinger method and Ozawa method.

Key words: composite bismaleimide polymer blends benzoxazine resin curing kinetics

Received: 15 October 2019

ZTFLH:

O631

Fund: Scientific Research Plan of Education Department of Shaanxi Province(19JK0741);Innovation and Entrepreneurship Project for College Students of Shaanxi Province(S201911080053)

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	Yuan JIA
	Liying ZHANG
	Mingyang MA
	Ruifeng SHI

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.475 OR https://www.cjmr.org/EN/Y2020/V34/I6/459

Fig.1 Synthesis of organic-inorganic Si-BOZ

Fig.2 FTIR image of Si-BOZ/BMI

Fig.3 Relationship between gelation time and temperature of two BOZ system

Fig.4 FTIR image of Si-BOZ/BMI

Fig.5 Relationship between gelation time and temperature of BMI and Si-BOZ/BMI resin

Fig.6 DSC of BMI and Si-BOZ/BMI resin in different rate of temperature increase (a: BMI, b: Si-BOZ/BMI)

Table 1 Peak temperature of DSC of BMI

Table 2 Peak temperature of DSC of Si-BOZ/BMI

Fig.7 Linear regression curve of peak temperature of DSC of BMI and Si-BOZ/BMI (a: BMI, b: Si-BOZ/BMI)

Fig.8 Linear regression curve of Kissinger_{(a: BMI, b: Si-BOZ/BMI)}

Fig.9 Linear regression curve of Ozawa (a: BMI; b: Si-BOZ/BMI)

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