Synthesis and Property of Proton Exchange Membrane Based on Tadpole-type POSS Block Copolymer

doi:10.11901/1005.3093.2016.417

Chinese Journal of Materials Research

2017, Vol. 31

Issue (4): 314-320 DOI: 10.11901/1005.3093.2016.417

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Synthesis and Property of Proton Exchange Membrane Based on Tadpole-type POSS Block Copolymer

Jie ZHANG^1,²(

), Fang CHEN³, Xiaoyan MA³

1 School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities Duyun 558000, China
2 Department of Applied Statistics and Science, Xijing University, Xi'an 710123, China
3 School of Natural and Applied Science, Northwestern Polytechnical University, Xi'an 710129, China

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Jie ZHANG, Fang CHEN, Xiaoyan MA. Synthesis and Property of Proton Exchange Membrane Based on Tadpole-type POSS Block Copolymer. Chinese Journal of Materials Research, 2017, 31(4): 314-320.

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Abstract

Tadpoles-type POSS block copolymer with polystyrene block copolymer and polymethyl methacrylate as arms (PMMA-b-PS) was synthesized by atom transfer radical polymerization (ATRP) method with polysilsesquioxane (POSS) as the initiator and polystyrene block copolymer and polymethyl methacrylate as raw material, and then was characterized by means of FTIR, ¹H NMR and GPC. The results show that the tadpoles-type POSS block copolymer was synthesized successfully. Proton exchange membrane based on the tadpoles-type POSS type block copolymer was prepared, of which the ion exchange capacity, water uptake and swelling rate, proton conductivity and thermal performance was as sessed . The results show that proton exchange membrane based on the tadpole-type POSS block copolymer has higher proton conductivity at high temperature as well as high initial decomposition temperature and high temperature resistant performance.

Key words: organic polymer materials PEM ATRP tadpole shaped block copolymer POSS

Received: 20 July 2016

ZTFLH:

O631.1+1

Fund: Supported by Fund Project of shaanxi Provincial Department of Education (No.16JK2240);2016 High-level Scientific Research Foundation for the Introduction of Talent for Qiannan Normal University for Nationalities (No.qnsyrc201615);Base of Production, Education & Research of Functional Polymer Materials for Qiannan Normal University for Nationalities (No.Qnsyk201604);College Students Innovation and Entrepreneurship Training Program for Xijing University (No.127152016148）

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.417 OR https://www.cjmr.org/EN/Y2017/V31/I4/314

Fig.1 Synthesis of tadpole-shaped POSS block copolymer via ATRP

Fig.2 FTRP of tadpole-shaped POSS block copolymer

Fig.3 ¹H NMR of tadpole-shaped POSS block copolymer

Fig.4 GPC of tadpole-shaped POSS block copolymer

Table 1 Molecular weight and block ratio of tadpole-shaped POSS block copolymer

Table 2 IEC of tadpole-shaped POSS block copolymer PEM

Fig.5 Water uptake of PEM under different temperature

Fig.6 λ of PEM under different temperature

Fig.7 Swelling ratio of PEM on the thin

Fig.8 Proton conduction of PEM under different temperature

Fig.9 Relation between proton conduction and λ

Fig.10 Proton transfer mechanism of PEM POSS-PMMA-b-SPS₈

Fig.11 TGA curveof tadpole-shaped POSS block copolymer

Table 3 Thermal properties of tadpole-shaped POSS block copolymer

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