Preparation and Photocatalytic Property of Co-Doped Hydroxyl-Zr Pillared Titanate

doi:10.11901/1005.3093.2015.542

Chinese Journal of Materials Research

2016, Vol. 30

Issue (4): 285-291 DOI: 10.11901/1005.3093.2015.542

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Preparation and Photocatalytic Property of Co-Doped Hydroxyl-Zr Pillared Titanate

HE Liwen^1,², SUN Dongya^1,², LIAN Jiqiong², LIN Bizhou^1,^**(

)

1. College of Materials Science & Engineering, Huaqiao University, Xiamen 361021, China
2. College of Materials Science & Engineering, Xiamen University of Technology, Xiamen 361024, China

Cite this article:

HE Liwen, SUN Dongya, LIAN Jiqiong, LIN Bizhou. Preparation and Photocatalytic Property of Co-Doped Hydroxyl-Zr Pillared Titanate. Chinese Journal of Materials Research, 2016, 30(4): 285-291.

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Abstract

Mesoporous nanocomposite of Co-doped hydroxyl-Zr -pillared titanate (CZPT) was prepared via an exfoliation-restacking route, and the pre-exfoliated layered titanate was reassembled in an aqueous solution containing hydroxyl-Zr oligocations and Co ions. The influence of the doping Co cations on the preparation and catalytic activity of Zr-pillared titanate (abbreviated as ZPT) composites was investigated. The prepared CZPT was characterized by powder X-ray diffraction, scanning electron microscope, transmission electron microscopy, UV-Vis spectra and porosity measurements. XRD and N₂ absorption results suggested that the ZPT doped with 5% Co (mass fraction) had bigger pore diameter and specific area. The presence of 5% Co could effectively suppress the annihilation of the photogenerated hole-electron pairs, and correspondingly the absorption wavelength exhibits obviously red-shift. The degradation of rhodamine B (RhB) under ultraviolet and visible radiation shows that the as-prepared nanocomposite exhibits higher photocatalytic activities than that of layered titanate alone. The enhanced photocatalytic activity of the as-prepared nanocomposite CZPT-5 for the degradation of RhB under visible irradiation may be attributed to the coupling interaction between cations of the host and the Co containing guest.

Key words: composite titanate nanosheets Co-doped pillared materials hydroxyl-Zr oligocations photocatalytic

Received: 24 September 2015

ZTFLH:	O611.5
	O613.51

Fund: Supported by National Natural Science Foundation of China No.50872037 and Education Scientific Project of Young Teacher of Fujian Province No.JB14077

About author: To whom correspondence should be addressed, Tel: 15959448863, E-mail: 2013123205@xmut.edu.cn

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.542 OR https://www.cjmr.org/EN/Y2016/V30/I4/285

Fig.1 Schematic illustration of the exfoliation-restacking route to prepare titanate composites

Fig.2 Powder XRD spectra of layered cesium titanate (a), layered protonic titanate (b), ZPT-5 (c), CZPT-20 (d), CZPT-10 (e) and CZPT-5 (f)

Table 1 Parameters obtained from N₂ adsorption-desorption measurements

Table 2 Compositions of pillared composites (%, atomic fraction)

Fig.3 Nitrogen adsorption (closed symbols)-desorption (opened symbols) isotherms of ZPT-5 (a) and CZPT-5 (b)

Fig.4 SEM (a) and HRTEM (b) images of CZPT-5

Fig.5 UV-Vis diffuse reflectance spectra (a) and (F(R)hv)^0.5-hv curves (b) of CZPT samples

Fig.6 Photodegradation of rhodamine B by layered titanate, ZPT-5, CZPT-20, CZPT-10 and CZPT-5

Table 3 The repeatability of pillared composites (%)

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