Preparation and Properties of Composite Functional Resin Prepared from Poly (Butyl Methacrylate-co-butyl Acrylate)/Calcium Carbonate

doi:10.11901/1005.3093.2014.729

Chinese Journal of Materials Research

2015, Vol. 29

Issue (11): 843-852 DOI: 10.11901/1005.3093.2014.729

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Preparation and Properties of Composite Functional Resin Prepared from Poly (Butyl Methacrylate-co-butyl Acrylate)/Calcium Carbonate

Xiaofang NIU¹,Naiku XU^1,^**(

),Bowen CHENG¹,Chun XIE²,Chengyue GUO²,Changfa XIAO¹,Jia GUO¹

1. School of Material Science and Engineering, Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300387, China
2. Rongsheng Petrochemical Co., Ltd., Hangzhou 311247, China

Cite this article:

Xiaofang NIU,Naiku XU,Bowen CHENG,Chun XIE,Chengyue GUO,Changfa XIAO,Jia GUO. Preparation and Properties of Composite Functional Resin Prepared from Poly (Butyl Methacrylate-co-butyl Acrylate)/Calcium Carbonate. Chinese Journal of Materials Research, 2015, 29(11): 843-852.

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Abstract

An active tertiary hydrogen atom containing poly (butyl methacrylate-co-butyl acrylate)was firstly synthesized via suspension polymerization, and then a novel functional resin containing rigid calcium carbonate was prepared by reactive extrusion while poly (butyl methacrylate-co-butyl acrylate), nano-calcium carbonate, hydroxyethyl methacrylate and benzoyl peroxide were used as matrix polymer, filler, reactive monomer and initiator, respectively. The corresponding structure and properties of the prepared resin were characterized by using thermogravimetric analyzer, field emission scanning electron microscope and X-ray diffractometer. The oil absorption of the resin before and after acid treatment and the capability of the resin before and after alkali treatment to absorb cationic blue dye were investigated in detail. The results show that acid treatment can not affect the oil absorption of the resin, and the resin can completely remove oil from water through absorption when circulating absorption time reached 50-60 min; additionally, the composite after alkali treatment for 30 min has good capacity to absorb cationic blue dye in comparison with the untreated ones.

Key words: organic polymer materials butyl methacrylate butyl acrylate hydroxyethyl methacrylate nano-calcium carbonate reactive extrusion functional resin

Received: 09 December 2014

Fund: *Supported by National Natural Science Foundation of China No. 51103099, Tianjin Municipal Natural Science Foundation No. 12JCQNJC01600, Research Fund for the Doctoral Program of Higher Education of China No.20111201120002, and China Postdoctoral Science Foundation No. 2014M550143.

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	Xiaofang NIU
	Naiku XU
	Bowen CHENG
	Chun XIE
	Chengyue GUO
	Changfa XIAO
	Jia GUO

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.729 OR https://www.cjmr.org/EN/Y2015/V29/I11/843

Fig.1 Sketch map of the device used for absorbing moving oil

Fig.2 TG (a) and DTG (b) curves of samples 1#-4#

Fig.3 Morphologies of surface and cross section of samples 2#-4#

Fig.4 TG (a) and DTG (b) curves of samples BMA-BA copolymer、0# and 5#

Fig.5 Surface (a) and cross section (b) morphologies of sample 5#

Fig.6 Absorption curves for motor oil (a), pump oil (b) and vegetable oil (c) before acid and alkali treatment

Fig.7 Dynamic absorption curves of 4# sample before and after acid treatment for pump oil

Fig.8 Color change of oil-water mixture during dynamic absorption for 4# sample

Fig.9 Curves of dye absorption efficiency with time for the resin after alkali treatment, (a) 1#, (b) 2#, (c) 3#, (d) 4#

Fig.10 XRD spectra of resin before acid and alkali treatment

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