Microwave Absorbing and Magnetic Properties of the Polyaniline-Co0.7Cr0.1Zn0.2Fe2O4 Composites

doi:10.11901/1005.3093.2014.707

Chinese Journal of Materials Research

2015, Vol. 29

Issue (8): 622-626 DOI: 10.11901/1005.3093.2014.707

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Microwave Absorbing and Magnetic Properties of the Polyaniline-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ Composites

Ruiting MA^JIANGDan^**(

),Xiao WANG,Haitao ZHAO

School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China

Cite this article:

Ruiting MA,Xiao WANG,Haitao ZHAO. Microwave Absorbing and Magnetic Properties of the Polyaniline-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ Composites. Chinese Journal of Materials Research, 2015, 29(8): 622-626.

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Abstract

The spinel cobalt chromium zinc ferrites (Co_0.7Cr_0.1Zn_0.2Fe₂O₄) and composites of polyaniline(PANI)-Co_0.7Cr_0.1Zn_0.2Fe₂O₄were prepared by polyacrylamide gel and in situ polymerization method, respectively, and then the synthesized materials were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FT-IR), their magnetic properties were measured using vibrating sample magnetometer (VSM) and their microwave absorbing capability was investigated by wave-guide method. The results show that the spinel Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrites and the composites PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ are acquired. Because a small amount Co²⁺ ion of the octahedron ferrite is replaced by Cr³⁺ ions, the lattice constant of the Co_0.8Zn_0.2Fe₂O₄ ferrite reduces from 0.8409 nm to 0.8377 nm. The saturation magnetization (M_s), remanent magnetization (M_r) and coercive force (H_c) of the PPy-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ composites are 8.80 emug^-1, 3.14 emug^-1 and 37.22 kAm^-1, respectively, which are smaller than that of the Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrite. In a measuring frequency range of 5.0-20.0 GHz, two peak values of reflection loss for the composites PPy-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ appear at 14.1 GHz and 17.9 GHz with -13.17 dB and -15.36 dB, respectively, which is obviously higher than those of the Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrite.

Key words: composites ferrite polyaniline microwave absorbing properties magnetic properties

Received: 27 November 2014

Fund: Supported by National Science Foundation of Liaoning Province No.2014020094.

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.707 OR https://www.cjmr.org/EN/Y2015/V29/I8/622

Fig.1 XRD spectra of the samples, (a) PANI-Co_0.7Cr_0.1-Zn_0.2Fe₂O₄, (b) Co_0.7Cr_0.1Zn_0.2Fe₂O₄ and (c) Co_0.8Zn_0.2-Fe₂O₄

Fig.2 FT-IR spectra of the samples (a) PANI-Co_0.7Cr_0.1-Zn_0.2Fe₂O₄, (b) Co_0.7Cr_0.1Zn_0.2Fe₂O₄

Fig.3 Hysteresis loops of the samples (a) PANI-Co_0.7Cr_0.1-Zn_0.2Fe₂O₄, (b) Co_0.7Cr_0.1Zn_0.2Fe₂O₄

Table 1 Magnetic parameters of the PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ and Co_0.7Cr_0.1Zn_0.2Fe₂O₄

Fig.4 Dielectric loss curves of the samples, (a) PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄, (b) Co_0.7Cr_0.1Zn_0.2Fe₂O₄

Fig.5 Reflection loss curves of the samples, (a) PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄, (b) Co_0.7Cr_0.1Zn_0.2Fe₂O₄

1	J. W. Ye, Y. Liu, X. F. Chen, M. Yao,Microwave electromagnetic and absorption properties of Sm N/α-Fe/Sm2Fe17N3 composites in 0.5-18 GHz range, J. Alloys. Compd., 526, 59(2012)
2	S. Ke, W. L. Zhong, Y. Zhong,L Li, X. Jiang, H. Ji, Temperature dependence of core losses at high frequency for MnZn ferrites, Physical B, 405, 1018(2010)
3	WU Yanfei,HUANG Ying, ZHANG Yinling, NIU Lei, Several w-type barium ferrites with different Me2: preparation and the electromagnetic properties, Chinese Journal of Materials Research, 25(6), 607(2011)
3	(吴燕飞, 黄英, 张银铃, 牛磊, Me2-W型钡铁氧体的制备及其电磁性能研究, 材料研究学报, 25(6), 607(2011))
4	K. Gupta, P. C. Jana, A. K. Meikap,Electrical transport and optical properties of the composite of polyaniline with gold, Solid State Sci, 14, 324(2012)
5	Y. Yao, H. Y. Jiang, J. Wu, D. Gu, L. Shen,Synthesis of Fe3O4/polyaniline nanocomposite in reversed micelle systems and its performance characteristics, Proc. Eng., 27, 664(2012)
6	LI Yuanxun,LIU Yingli, ZHANG Huaiwu, LING Weiwei, XIE Yunsong, XIAO Johnqiang, Preparation, Characterization and properities of polyaniline-barium ferrite nanocomposite, Chemical Journal of Chinese Universities, 29(3), 640(2008)
6	(李元勋, 刘颖力, 张怀武, 凌味未, 谢云松, XIAO JohnQiang, 聚苯胺钡铁氧体纳米复合材料的制备、表征及性能, 高等学校化学学报, 29(3), 640(2008).)
7	S. P. Gairola, V. Verma, L. Kumar, M. A. Dar, S. Annapoomi, R. K. Kotnala,Enhanced microwave absorption properties in polyaniline and nano-ferrite composite in X-band, Synth. Met., 160, 2315(2010)
8	C. C. Yang, Y. J. Gung, W. C. Hung, T. H. Ting, K. H. Wu,Infrared and microwave absorbing properties of BaTiO3/polyaniline and BaFe12O19/polyaniline composites, Compos. Sci. Technol., 70, 466(2010)
9	R. T. Ma, Y. W. Tian, H. T. Zhao, G. Zhang, H. Zhao,Synthesis, Characterization and electromagnetic studies on nanocrystalline Co0.5Zn0.5Fe2O4 by polyacrylamide gel, J. Mater. Sci. & Technol., 24(4), 628(2008)
10	C. C. Hwang, J. S. Tasi, T. H. Huang,Combustion synthesis of Ni–Zn ferrite by using glycine and metal nitrates—investigations of precursor homogeneity, product reproducibility, and reaction mechanism, Mater. Chem. Phys., 93, 330(2005)
11	C. J. Leng, J. H. Wei, Z. Y. Liu, J. Shi,Influence of imidazolium-based ionic liquids on the performance of polyaniline-CoFe2O4 nanocomposites, J. Alloys Compd., 509, 3052(2011)
12	C. D. Prasanna, H. S. Jayanna, A. R. Lamani, S. Dash,Polyaniline/CoFe2O4 nanocomposites: A novel synthesis, characterization and magnetic properties, Synth. Met., 161, 2306(2011)
13	D. S. Birajadar, U. N. Debatwal, K. M. Jadhav,X-ray, IR and bulk magnetic properties of Cu1-xMnxFe2-2xO4 ferrite system, J. Mater. Sci., 37, 1443(2002)
14	L. C. Li, J. Jiang, F. Xu,Synthesis and ferromagnetic properities of novel Sm-substituted LiNi ferrite-polyaniline nanocomposite, Mater. Lett., 61, 1091(2007)
15	G. Namita, S. Kuldeep, O. Anil, D. P. Singh, S. K. Dhawan,Thermal, dielectric and microwave absorption properties of polyaniline-CoFe2O4 nanocomposites, Compos. Sci. Technol., 71, 1754(2011)
16	Y. P. Duan, G. L. Wu, X. G. Li,On the correlation between structural characterization and electromagnetic properties of doped polyaniline, Solid State Sci., 12, 1374(2010)
17	S. W. Phang, T. Hino, M. H. Abdullah, N. Kuramoto,Applications of polyaniline doubly doped with p-toluene sulphonic acid and dichloroacetic acid as microwave absorbing and shielding materials, Mater. Chem. Phys., 104, 327(2007)
18	T. H. Ting, R. P. Yu, Y. N. Jau,Synthesis and microwave absorption characteristics of polyaniline/NiZn ferrite composites in 2-40 GHz, Mater. Chem. Phys., 126, 364(2011)

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