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Chinese Journal of Materials Research  2012, Vol. 26 Issue (6): 561-566    DOI:
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Effects of Calcination Temperature on the Photocatalytic Activity of In–TiO2 Nano–material
ZHANG Wenjie,  CHEN Jinlei,  WANG Hong,  HE Hongbo
1.School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110159
2.Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016
Cite this article: 

ZHANG Wenjie CHEN Jinlei WANG Hong HE Hongbo. Effects of Calcination Temperature on the Photocatalytic Activity of In–TiO2 Nano–material. Chinese Journal of Materials Research, 2012, 26(6): 561-566.

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Abstract  

3%In doped TiO2 nano–material was prepared by sol–gel method, and powder X–ray diffraction (XRD), scanning electron microscope (SEM), FT–IR, and N2 adsorption–desorption were employed to characterize the material calcined at different temperature. Photocatalytic degradation of methyl orange under UV–light irradiation on the materials was also examined. The results show that all the samples present anatase TiO2 phase, and no apparent impact on surface morphology of the samples was
observed. With increasing calcination temperature, TiO2 crystallite size and average pore size increased gradually, while the special surface area decreased. The special surface area and average pore size are 94.4 m2/g and 10.3 nm for the 3%In–TiO2 sample calcinated at 400oC. Meanwhile, the sample also have the optimal photocatalytic degradation activity, and methyl orange degradation rate is 43.1% after 30 min of UV–light irradiation.

Key words:  inorganic non–metallic materials      thermal treatment      In–TiO2      photocatalysis      methyl orange     
Received:  09 October 2012     
ZTFLH:  O643  
Fund: 

Supported by National Natural Science Foundation of China No.41271251 and Liaoning Science and Technology Project No.2010229002.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I6/561


1 M.Palacio, P.I.Villabrille, G.P.Romanelli, P.G.Vazquez, C.V.Caceres, Preparation, characterization and use of V2O5–TiO2 mixed xerogels as catalysts for sustainable oxidation with hydrogen peroxide of 2,3,6–trimethylphenol, Applied Catalysis A: General, 417–418, 273(2012)

2 P.H.Wang, P.S.Yap, T.T.Lim, C–N–S tridoped TiO2 for photocatalytic degradation of tetracycline under visible–light irradiation, Applied Catalysis A: General, 399, 252(2011)

3 T.C.An, J.K.Liu, G.Y.Li, S.Q.Zhang, H.J.Zhao, X.Y.Zeng, G.Y.Sheng, J.Fu, Structural and photocatalytic degradation characteristics of hydrothermally treat mesoporous TiO2, Applied Catalysis A: General, 350, 237(2008)

4 LI Li, WANG Kuanling, LI Jiabo, ZHANG Wenjie, Effect of hydrochloric acid modification of NaZSM–5 zeolite on the properities of TiO2/ZSM–5 photocatalyst, Chinese Journal of Materials Research, 24(5), 535(2010)

(李 莉, 王宽岭, 李家博, 张文杰, 对NaZSM--5分子筛盐酸改性制备TiO2/ZSM--5光催化剂, 材料研究学报, 24(5), 535(2010))

5 QU Xiaoguang, SONG Yunting, LIU Qing, CAO Wenbin, Preparation of nanocrystalline Cr–doped TiO2 powders and their photocatalytic properties under visible light irradiation, Chinese Journal of Materials Research, 24(2), 144(2010)

(曲晓光, 宋云婷, 刘青, 曹文斌, Cr掺杂纳米TiO2的制备及其可见光催化性能, 材料研究学报, 24(2), 144(2010))

6 S.M.Lopez, M.C.Hidalgo, J.A.Nav?o, Synthesis, characterization and photocatalytic activity of Bi–doped TiO2 photocatalysts under simulated solar irradiation, Applied Catalysis A: General, 404, 59(2011)

7 J.Arana, O.G.D´?az, M.Miranda, Acid photocatalytic degradation using Fe–TiO2 catalysts: dependence of the degradation mechanism on the Fe catalysts content, Applied Catalysis B: Environmental, 36(2), 113(2002)

8 H.Yu, J.Li, A.J.Zheng, W.Xu, Photocatalytic activity of TiO2 thin film nonuniformly doped by Ni, Materials Chemistry and Physics, 97(1), 59(2006)

9 F.B.Li, X.Z.Li, C.H.Ao, S.C.Lee, M.F.Hou, Enhanced photocatalytic degradation of VOCs using Ln3+–TiO2 catalysts for indoor air purification, Chemosphere, 59(6), 787(2005)

10 CHEN Xun, LIN Pingyong, SHI Xicheng, ZHANG Zhongliang, XIE Zhipeng, LI Zhaohui, Nanocrystalline In-OOH: control synthesis and photocatalytic performance in aqueous phase, Chinese Journal of Inorganic Chemistry, 25(11), 1917(2009)

(陈 旬, 林平勇, 史喜成, 张忠良, 谢志鹏, 李朝晖, InOOH纳米晶的控制合成及其液相光催化性能, 无机化学学报, 25(11), 1917(2009))

11 S.F.Chen, X.L.Yu, H.Y.Zhang, W.Liu, Preparation, characterization and activity evaluation of heterostructure In2O3/In(OH)3 photocatalyst, Journal of Hazardous Meterial,

180, 735(2010)

12 E.J.Wang, W.S.Yang, Y.A.Cao, Unique surface chemical species on indium doped TiO2 and their effect on the visible light photocatalytic activity, Journal of Physical Chemistry C, 113, 20912(2009)

13 V.R.Gonzalez, A.M.Rodriguez, M.May, Slurry photodegradation of 2,4–dich–lorophenxyacetic acid: A comparative study of impregnated and sol–gel In2O3–TiO2 mixed oxide catalysts, Journal of Photochemistry and Photobiology A: Chemistry, 193, 266(2008)

14 LONG Huijing, WANG Enjun, DONG Jiangzhou, WANG Lingling, CAO Yongqiang, YANG Wensheng, CAO Yana, Photocatalytic activity of Indium doped TiO2 nanotube under visible light, Acta Chimica Sinica, 67(14), 1533(2009)

(龙绘锦, 王恩君, 董江舟, 王玲玲, 曹永强, 杨文胜, 曹亚安, In离子掺杂二氧化钛纳米管可见光催化活性的研究, 化学学报, 67(14), 1533(2009))

15 ZHANG Wenjie, YANG Bo, Synthesis and photocatalytic properties of B–TiO2, Chinese Journal of Materials Research, 26(2), 149(2012)

(张文杰, 杨波, B掺杂TiO2光催化剂的制备和光催化性能, 材料研究学报, 26(2), 149(2012))

16 SUN Jing, GAO Lian, ZHANG Qinghong, Preparation of nano rutile titania powders with high photocatalytic properties, Acta Chimica Sinica, 61(1), 75(2003)

(孙  敬, 高  濂, 张青红, 制备具有光催化活性的金红石相纳米氧化钛粉末, 化学学报, 61(1), 75(2003))

17 YUAN Jin, LU Yongkang, LI Yu, LI Junping, Preparation of mesoporous magnetic photocatalyst and its catalytic activity for degradation of nitrobenzene, Chinese Journal of Catalysis, 31(5), 5973(2010)

(袁 进, 吕永康, 李 裕, 李军平, 介孔磁性光催化剂的制备及其催化降解硝基苯, 催化学报, 31(5), 5973(2010))

18 S.Yuan, Q.R.Sheng, J.L.Zhang, Synthesis of La3+ doped mesoporous titania with highly crystallized walls, Microporous and Mesoporous Materials,79, 93(2005)

19 J.W.Tang, Z.G.Zou, J.H.Ye, Effects of substituting Sr2+ and Ba2+ for Ca2+ on the structural properties and photocatalytic behaviors of CaIn2O4, Chemical Materials, 16(9), 1644(2004)

20 J.G.Yu, J.F.Xiong, B.Cheng, S.W.Liu, Fabrication and characterization of Ag–TiO2 multiphase nanocomposite thin films with enhanced photocatalytic activity, Applied Catalysis B: Environmental, 60(3–4), 21(2005)


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