Stability of MLG/Fe2O3 Nano-particulate Tribo-layer on TC11 Ti-alloy

doi:10.11901/1005.3093.2019.283

Chinese Journal of Materials Research

2019, Vol. 33

Issue (10): 763-770 DOI: 10.11901/1005.3093.2019.283

ARTICLES

Current Issue | Archive | Adv Search

Stability of MLG/Fe2O3 Nano-particulate Tribo-layer on TC11 Ti-alloy

ZHOU Yin¹(

),WANG Shuqi²,ZHAO Zhenjiang¹,XU Sheng¹,WANG Jian¹

1. School of Shipping and Mechatronic Engineering, Taizhou University, Taizhou 225300, China
2. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China

Cite this article:

ZHOU Yin,WANG Shuqi,ZHAO Zhenjiang,XU Sheng,WANG Jian. Stability of MLG/Fe2O3 Nano-particulate Tribo-layer on TC11 Ti-alloy. Chinese Journal of Materials Research, 2019, 33(10): 763-770.

Download:

HTML

PDF(10539KB)
Export: BibTeX | EndNote (RIS)

Abstract

The tribological behavior of TC11 Ti-alloy was studied via an MPX-2000 type friction and wear tester with TC11Ti-alloy as pin and GCr15 steel as disc in conditions of applying different loads and incorporating various nano-lubricants onto the interface of pin/disc. The surface morphology, cross-section morphology, composition and structure of worn TC11 Ti-alloy were comparatively characterized by means of scanning electron microscopy with energy dispersive spectroscope and X-ray diffractometer. The results show that tribo-layer of nano-particulates could form on the worn surface of TC11 Ti-alloy when different type of nanomaterials were incorporated onto the sliding interface of the tribo-pairs. The stability of the tribo-layer depends on its composition and the relative content of each component. The multi-layered graphene (MLG) containing tribo-layer possessed poor stability and readily damaged because of its low load-bearing capacity. The Fe₂O₃containing tribo-layer possessed good stability under lower loads, resulting in the reduced wear and increased friction. The double-layered tribo-layer composed simultaneously of MLG and Fe₂O₃ possessed high stability, which can be ascribed to the good lubrication and load-bearing capacity. As a result, the friction and wear performance of TC11 Ti-alloy was markedly enhanced. Especially the double-layered MLG/Fe₂O₃ nano-particulate tribo-layer with Fe₂O₃-rich nanocomposite possessed higher stability and thus the tribological properties of TC11 Ti-alloy could be much effectively improved.

Key words: materials failure and protection nano-particulate tribo-layer friction and wear TC11 alloy graphene stability

Received: 30 May 2019

ZTFLH:

TH117.1

Fund: National Science Foundation of the Jiangsu Higher Education Institutions of China(18KJB430025);Jiangsu Province Key Laboratory of High-end Structural Materials Open Fund Project(hsm1807);Science and Technology Support Program of Taizhou(TS201820);Research Startup Fund Project for High-level Talents of Taizhou University(TZXY2017QDJJ013)

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Yin ZHOU
	Shuqi WANG
	Zhenjiang ZHAO
	Sheng XU
	Jian WANG

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2019.283 OR https://www.cjmr.org/EN/Y2019/V33/I10/763

Fig.1 Preparation procedure of MLG and MLG/Fe₂O₃

Fig.2 Schematic diagram of modification of the lower disk specimen

Fig.3 Micro-morphologies of nano-particulates (a) MLG; (b) Fe₂O₃; (c) MLG/Fe₂O₃

Fig.4 Wear rate of TC11 alloy as a function of load with various nano-lubricants

Fig.5 Average friction coefficient of sliding system under the conditions of various nano-lubricants and loads

Fig.6 XRD patterns of worn surfaces of TC11 alloy under the conditions of various nano-lubricants and loads (a) No additive, 120 N; MLG, 120 N; Fe₂O₃, 60 N and 80 N; (b) MLG/Fe₂O₃(1:2), 100 N and 120 N; MLG/Fe₂O₃(1:1), 100 N and 120 N; MLG/Fe₂O₃(2:1), 100 N and 120 N

Fig.7 Morphology of worn surfaces of TC11 alloy under the conditions of various nano-lubricants and loads (a) No lubricant, 120 N; (b) MLG, 120 N; (c) Fe₂O₃, 60 N; (d) Fe₂O₃, 80 N; (e) MLG/Fe₂O₃(1:2), 120 N; (f) MLG/Fe₂O₃(1:1), 100 N; (g) MLG/Fe₂O₃(1:1), 120 N; (h) MLG/Fe₂O₃(2:1), 100 N; (i) MLG/Fe₂O₃(2:1), 120 N

Fig.8 EDS analysis of the marked regions in Fig.7 (a) EDS1; (b) EDS2; (c) EDS3

Fig.9 Cross-section morphology of worn surfaces of TC11 alloy under the conditions of various nano-lubricants and loads (a) No lubricant, 120 N; (b) MLG, 120 N; (c) Fe₂O₃, 60 N; (d) Fe₂O₃, 80 N; (e) MLG/Fe₂O₃(1:2), 100 N; (f) MLG/Fe₂O₃(1:2), 120 N; (g) MLG/Fe₂O₃(1:1), 100 N; (h) MLG/Fe₂O₃(1:1), 120 N; (i) MLG/Fe₂O₃(2:1), 100 N

Fig.10 Comparison of critical load under the conditions of various nano-lubricants

Fig.11 Schematic diagram of formation mechanism for double-layer MLG/Fe₂O₃ nano-particulate tribo-layer

[1]	Kim H J, Emge A, Karthikeyan S ,et al. Effects of tribooxidation on sliding behavior of aluminum [J]. Wear, 2005, 259: 501
[2]	Straffelini G, Molinari A. Dry sliding wear of Ti-6Al-4V alloy as influenced by the counterface and sliding conditions [J]. Wear, 1999, 236: 328
[3]	Molinari A, Straffelini G, Tesi B ,et al. Dry sliding wear mechanisms of the Ti6Al4V alloy [J]. Wear, 1997, 208: 105
[4]	Qiu M, Zhang Y Z, Yang J H ,et al. Effects of friction heat on tribological properties of Ti6Al4V alloy sliding against GCr15 steel [J]. Tribology, 2006, 26: 203
[4]	邱明, 张永振, 杨建恒等. 摩擦热对Ti6Al4V合金摩擦磨损性能的影响 [J]. 摩擦学学报, 2006, 26: 203
[5]	Sahoo R, Jha B B, Sahoo T K. Dry sliding wear behaviour of Ti-6Al-4V alloy consisting of bimodal microstructure [J]. Trans. Indian Inst. Met., 2014, 67: 239
[6]	Mao Y S, Wang L, Chen K M ,et al. Tribo-layer and its role in dry sliding wear of Ti-6Al-4V alloy [J]. Wear, 2013, 297: 1032
[7]	Wang L, Wang S Q, Zhang Q Y. Effect of the formation of tribo-layer on the wear performance of TC4 alloy [J]. Tribology, 2014, 34: 673
[7]	王兰, 王树奇, 张秋阳. 摩擦层的形成对TC4合金磨损性能的影响 [J]. 摩擦学学报, 2014, 34: 673
[8]	Zhang Q Y, Zhou Y, Wang L ,et al. Investigation on tribo-layers and their function of a titanium alloy during dry sliding [J]. Tribol. Int., 2016, 94: 541
[9]	Li X X, Zhang Q Y, Zhou Y ,et al. Mild and severe wear of titanium alloys [J]. Tribol. Lett., 2016, 61: 1
[10]	Chelliah N, Kailas S V. Synergy between tribo-oxidation and strain rate response on governing the dry sliding wear behavior of titanium [J]. Wear, 2009, 266: 704
[11]	Yao X F, Xie F Q, Han Y ,et al. Effects of temperature on wear properties and friction coefficient of TC4 alloy [J]. Rare Met. Mater. Eng., 2012, 41: 1463
[11]	姚小飞, 谢发勤, 韩勇等. 温度对TC4钛合金磨损性能和摩擦系数的影响 [J]. 稀有金属材料与工程, 2012, 41: 1463
[12]	Shin J H, Lim D S, Ahn H S. Effect of annealing and Fe2O3 addition on the high temperature tribological behavior of the plasma sprayed yttria-stabilized zirconia coating [J]. Surf. Coat. Technol., 2000, 133-134: 403

[1]	WANG Wei, XIE Zelei, QU Yishen, CHANG Wenjuan, PENG Yiqing, JIN Jie, WANG Kuaishe. Tribological Properties of Graphene/SiO₂ Nanocomposite as Water-based Lubricant Additives[J]. 材料研究学报, 2023, 37(7): 543-553.
[2]	ZHANG Tengxin, WANG Han, HAO Yabin, ZHANG Jiangang, SUN Xinyang, ZENG You. Damping Enhancement of Graphene/Polymer Composites Based on Interfacial Interactions of Hydrogen Bonds[J]. 材料研究学报, 2023, 37(6): 401-407.
[3]	LI Qiao, NIU Ben, ZHANG Ruiqian, LIU Huiqun, LIN Guoqiang, WANG Qing. Effect of Ta/Zr on High-temperature Microstructural Stability of Warm-rolled Sheets of Fe-Cr-Al-Mo-Nb Alloy[J]. 材料研究学报, 2023, 37(6): 423-431.
[4]	JIANG Shuimiao, MING Kaisheng, ZHENG Shijian. A Review on Grain Boundary Segregation, Interfacial Phase and Mechanical Property Adjusting-controlling for Nanocrystalline Materials[J]. 材料研究学报, 2023, 37(5): 321-331.
[5]	WANG Chunjin, CHEN Wenge, KANG Ningning, YANG Tao. Microstructure and Properties of Graphene-regulated Functional Titanium by Laser Additive Manufacturing[J]. 材料研究学报, 2023, 37(10): 791-800.
[6]	CHEN Kaiwang, ZHANG Penglin, LI Shuwang, NIU Xianming, HU Chunlian. High-temperature Tribological Properties for Plasma Spraying Coating of Ni-P Plated Mullite Powders[J]. 材料研究学报, 2023, 37(1): 39-46.
[7]	LI Fulu, HAN Chunmiao, GAO Jiawang, JIANG Jian, XU Hui, LI Bing. Temperature Dependent Luminescence Properties of Graphene Oxide[J]. 材料研究学报, 2022, 36(8): 597-601.
[8]	LIU Yanyun, LIU Yutao, LI Wanxi. Preparation and Electrochemical Performance of rGO/PANI/MnO₂ Ternary Composites[J]. 材料研究学报, 2022, 36(7): 552-560.
[9]	GAO Wei, LIU Jiangnan, WEI Jingpeng, YAO Yuhong, YANG Wei. Structure and Properties of Cu₂O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy[J]. 材料研究学报, 2022, 36(6): 409-415.
[10]	HUANG Huan, ZHANG Xuntao, YANG Shangke, XIAO Liuxin, ZHANG Zhaoxin, YAN Lei, LIN Hailan, BIAN Jun, CHEN Daiqiang. Properties of Nylon PA6-based Nanocomposites Co-modified with Graphene Oxide/sodium Benzoate Complex Nucleating Agent[J]. 材料研究学报, 2022, 36(6): 416-424.
[11]	ZHANG Shuqi, DONG Dandan, WAN Peng, WANG Qing, DONG Chuang, YANG Rui. Composition Design of Alumina-Forming Austenitic Stainless Steels Based on Cluster-Plus-Glue-Atom Model[J]. 材料研究学报, 2022, 36(5): 353-364.
[12]	YANG Liuyang, TAN Zhuowei, LI Tongyue, ZHANG Dalei, XING Shaohua, JU Hong. Dynamic Corrosion Behavior of Pipeline Defects Characterized by WBE and EIS Testing Techniques[J]. 材料研究学报, 2022, 36(5): 381-391.
[13]	LIU Jialiang, XU Dongwei, CHEN Ping. Preparation and Microwave Absorption Properties of Magnetic Porous rGO@Co/CoO Composites[J]. 材料研究学报, 2022, 36(5): 332-342.
[14]	SUN Yi, HAN Tongwei, CAO Shumin, LUO Mengyu. Tensile Properties of Fluorinated Penta-Graphene[J]. 材料研究学报, 2022, 36(2): 147-151.
[15]	LI Yufeng, ZHANG Nianfei, LIU Lishuang, ZHAO Tiantian, GAO Wenbo, GAO Xiaohui. Preparation of Phosphorus-containing Graphene and Corrosion Resistance of Composite Coating[J]. 材料研究学报, 2022, 36(12): 933-944.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed