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Flame Retardant Properties of Nylon 6/SiO2 Modified MCA Composites |
WEI Shanshan1, YAO Feng1, XU Xiangyang2, XIE Xiang1 |
1.College of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou 412007
2.School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 |
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Cite this article:
WEI Shanshan, YAO Feng, XU Xiangyang, XIE Xiang. Flame Retardant Properties of Nylon 6/SiO2 Modified MCA Composites. Chinese Journal of Materials Research, 2012, 26(6): 627-631.
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Abstract As a modifier, silica sol was introduced into the traditional melamine cyanurate (MCA) preparation process and therewith modified MCA (mMCA) was prepared. mMCA was blended with nylon 6 (PA 6) to prepare flame retardant PA 6 composites and the flame retardant properties were investigated. The results show that silica sol may contribute to the enhancement of flame retardant property. With the increase of silica sol content, the limited oxygen index (LOI) of PA 6/mMCA composites increase firstly
and then decrease, and the self-extinguishing time decreases. In the presence of silica sol, the amount of drippings can be reduced, the formation of non-flame dripping increases and the char structure can be improved.
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Received: 06 September 2012
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Fund: Supported by Nature Science Foundation of China No.11101136, Hunan Provincial Natural Science Foundation Nos10JJ5047&11JJ3054, Science and Technology Planning Project of Hunan Province No.2011FJ3211 and Hunan Province Universities Innovation Platform of Open Fund Project No.12K114. |
1 Z.Y.Wu, W.Xu, Y.C.Liu, J.K.Xia, Q.X.Wu, W.J.Xu, Preparation and characterization of flame-retardant melamine cyanurate/polyamide 6 nanocomposites by in situ polymerization, Journal of Applied Polymer Science, 113, 2109(2009)2 Y.H.Chen, Q.Wang, W.Yan, H.M.Tang, Preparation of flame retardant polyamide 6 composite with melamine cyanurate nanoparticles in situ formed in extrusion process, Polymer Degradation and Stability, 91, 2632(2006)3 Z.Hu, G.P.Lin, L.Chen, Y.Z.Wang, Flame retardation of glass-fiber-reinforced polyamide 6 by combination of aluminum phenylphosphinate with melamine pyrophosphate, Polymers for Advanced Technologies, 22(7), 1166(2011)4 Y.H.Chen, Q.Wang, Preparation, properties and characterizations of halogen-free nitrogen-phosphorous flameretarded glass fiber reinforced polyamide 6 composite, Polymer Degradation and Stability, 91, 2003(2006)5 Q.L.Tai, R.K.K.Yuen, W.Yang, Z.H.Qiao, L.Song, Y.Hu, Iron-montmorillonite and zinc borate as synergistic agents in flame-retardant glass fibre reinforced polyamide 6 composites in combination with melamine polyphosphate, Composites part A- Applied Science and Manufacturing, Composites Part A: Applied Science and Manufacturing, 43(3), 415(2012)6 K.Y.Fang, J.Li, C.H.Ke, Q.L.Zhu, K.Tao, J.Zhu, Q.Yan, Intumescent flame retardation of melamine-modified montmorillonite on polyamide 6: Enhancement of condense phase and flame retardance, Polymer Engineering & Science, 51(2), 377(2011)7 Bin Zhao, Zhi Hu, Li Chen, Yun Liu, Ya Liu, Yuzhong Wang, A phosphorus-containing inorganic compound as an effective flame retardant for glass-fiber-reinforced polyamide 6, Journal of Applied Polymer Science, 119(4), 2379(2011)8 Pieter Gijsman, Rieky Steenbakkers, Christian F¨urst, Joyce Kersjes. Differences in the flame retardant mechanism of melamine cyanurate in polyamide 6 and polyamide 66. Polymer Degradation and Stability, 78, 219(2002)9 WEI Shanshan, YAO Feng, LIU Yiwu, LIU Yuejun. Mechanical properties of nylon 6 /modified melamine cyanurate composites, Minning and Metallurgical Engineering, 29(3), 88(2009)(魏珊珊, 姚 峰, 刘亦武, 刘跃军, 尼龙6 /改性MCA复合材料的力学性能研究, 矿冶工程, 29(3), 88(2009))10 WEI Shanshan, ZHANG Ping, WANG Xiayu, Study on the mechanical properties of nylon 6/nano-SiO2composites, Natural Science Journal of Xiangtan University, 24(4), 42(2002)(魏珊珊, 张 平, 王霞瑜, 尼龙6/纳米SiO2复合材料力学性能研究, 湘潭大学自然科学学报, 24(4), 42(2002))11 S.S.Wei, Y.J.Liu, X.G.Li, Y.G.Huang, X.Y.Wang, P.Zhang, Preparation and rheological behaviors of PA6/SiO2 nanocompsite, Frontiers of Chemical Engineering in China, 4, 233(2007)12 G.Schmaucks, B.Friede, H.Schreiner, J.O.Roszinski, Fire retardancy of polymers new strategies and mechanisms, RSC Press, (2009) pp.35 |
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