Synthesis and Properties of TiO2/PVDF Hybrid Membrane

Chin J Mater Res

2012, Vol. 26

Issue (3): 247-254 DOI:

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Synthesis and Properties of TiO2/PVDF Hybrid Membrane

YOU Yuting, WANG Yang, ZHANG Xia

College of Sciences, Northeastern University, Shenyang 110004

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YOU Yuting WANG Yang ZHANG Xia. Synthesis and Properties of TiO2/PVDF Hybrid Membrane. Chin J Mater Res, 2012, 26(3): 247-254.

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Abstract The hybrid membrane was prepared through reversed phase cast method by blending the anatase-TiO2 nanoparticles with the PVDF casting solutions. The metallographic microscope, scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to character the hybrid films, and the effects of TiO2 nanoparticle content on the properties of the TiO2/PVDF hybrid membraine were investigated. The results showed that a promoted adsorption and elution efficiencies of PVDF/TiO2 hybrid membranes were observed compared with that of the neat PVDF film. And with increase of TiO2 nanoparticle content, the surface water contact angle of the hybrid membraine decreases, the hydrophily, pure water flux (TiO2 nanoparticle content <8%) and the contamination resistance increase. The optimum conditions were determined as follows: w(LiCl)=2%, w(PEG600)=2%, w(PVDF)=20% and w(TiO2)=5%–8%.

Key words: composites organic-inorganic hybrid membrane PVDF TiO2 adsorption of Cu(II)

Received: 14 January 2012

ZTFLH:

O647

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Supported by National Natural Science Foundation of China No.21103017 and Fundamental Research Funds for the Central Universities No.N090405006 and No.N110405007.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2012/V26/I3/247

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