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The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide |
LI Yanwei 1,2, LI Yuexiao1,YAO Jinhuan1,LIU Changjiu1,2,ZHU Wenfeng2 |
1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004
2. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials of Ministry of Education, Guilin University of Technology, Guilin 541004 |
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Cite this article:
LI Yanwei LI Yuexiao YAO Jinhuan LIU Changjiu ZHU Wenfeng . The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide. Chin J Mater Res, 2011, 25(1): 51-56.
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Abstract α/β mutually embedded nickel hydroxide has been synthesized by chemical coprecipitation method. The microstructure and surface morphology of the prepared samples were analyzed by X–ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM). The electrochemical performance of the prepared sample was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge discharge tests. Compared to the pure β nickel hydroxide, the α/β mutually embedded nickel hydroxide shows a higher electrochemical reaction activity, lower electrochemical reaction impedance, higher discharge capacity, and higher discharge voltage. Moreover, α/β mutually embedded nickel hydroxide has better cyclic performance.
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Received: 08 October 2010
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Fund: Supported by National Natural Science Foundation of China No.20563001, Postdoctoral Science Foundation of China No.20090450188, and Natural Science Foundation of Guangxi Province No. 0991247. |
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