Please wait a minute...
Chin J Mater Res  2011, Vol. 25 Issue (1): 51-56    DOI:
论文 Current Issue | Archive | Adv Search |
The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide
LI Yanwei 1,2, LI Yuexiao1,YAO Jinhuan1,LIU Changjiu1,2,ZHU Wenfeng2
1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004
2. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials of Ministry of Education, Guilin University of Technology, Guilin 541004
Cite this article: 

LI Yanwei LI Yuexiao YAO Jinhuan LIU Changjiu ZHU Wenfeng . The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide. Chin J Mater Res, 2011, 25(1): 51-56.

Download:  PDF(1125KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  α/β mutually embedded nickel hydroxide has been synthesized by chemical coprecipitation method. The microstructure and surface morphology of the prepared samples were analyzed by X–ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM). The electrochemical performance of the prepared sample was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge discharge tests. Compared to the pure β nickel hydroxide, the α/β mutually embedded nickel hydroxide shows a higher electrochemical reaction activity, lower electrochemical reaction impedance, higher discharge capacity, and higher discharge voltage. Moreover, α/β mutually embedded nickel hydroxide has better cyclic performance.
Key words:  inorganic non–metallic materials       nickel hydroxide       electrode active material       microstructure       electrochemical performance     
Received:  08 October 2010     
ZTFLH: 

TB321

 
Fund: 

Supported by National Natural Science Foundation of China No.20563001, Postdoctoral Science Foundation of China No.20090450188, and Natural Science Foundation of Guangxi Province No. 0991247.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2011/V25/I1/51

1 XIAO Huiming, WANG Jianming, CHEN Hui, PAN Tao, ZHANG Jianqing, Synthesis of Al–substituted alpha–nickel hydroxide in organic solvent and its electrochemical performance, Functional Materials, 34(5), 553(2003)

(肖慧明, 王建明, 陈惠, 潘滔, 张鉴清, Al取代α--Ni(OH)2的有机溶剂法合成及其电化学性能, 功能材料,  34(5), 553(2003))

2 WU Yuping, ZHANG Hanping, WU Feng, ZHANG Peng, GUAN Shiyou, Green Power Material (first edition), (Beijing, Chemical Industry Press, 2008) p.136

(吴宇平, 张汉平, 吴锋, 张鹏, 关士友, 绿色电源材料(第一版) (北京, 化学工业出版社, 2008) p.136)

3 ZHAI Haijun, WANG Xianyou, YANG Hongping, LI Jingming, Studies on the electrode characteristics of metal substituted α–Ni(OH)2, Chinese Journal of Power Source, 27, 197(2005)

(翟海军, 王先友, 杨红平, 李晶明, 掺杂α--Ni(OH)2 的电极性能研究, 电源技术,  27, 197(2005))

4 LIU Yuangang, TANG Zhiyuan, XU Qiang, ZHANG Xiaoyang, LIU Yong, Research development and prospect of α–Ni(OH)2, Progress in Chemisty, 18(7/8), 833(2006)

(刘元刚, 唐致远, 徐强, 张晓阳, 柳 勇, α--Ni(OH)2的研究进展, 化学进展,  18(7/8), 833(2006))

5 ZHANG Qian, XU Yanhui, WANG Xiaolin, HE Guorong, LIN Kezhi, Preparation of Al–doped α–Ni(OH)2 by homogeneous precipitation and its electrochemical performance, Rare Metal Materials and Engineering, 33(12), 1291(2004)

(张倩, 徐艳辉, 王晓琳, 何国荣, 林克芝, 均相沉淀法制备α--Ni(OH)2及其电化学性能研究, 稀有金属材料与工程,  33(12), 291(2004))

6 R.S.Jayashree, K.P.Vishnu, Factors governing the electrochemical synhesis of α–nickel (II) hydroxide, Journal of Applied Electrochemistry, 29(4), 449(1999)

7 S.Akiko, I.Shintaro, H.Kenzo, Preparation and characterization of Ni/Al–layered double hydroxide, Journal of The Electrochemical Society, 146(4), 1251(1999)

8 ZHANG Hongbing, PU Tan, LI Daohuo, Research on nanostructure Al3+, Zn2+ instituted Ni(OH)2 electrode materials, Journal of Power Source, 28(5), 276(2003)

(张红兵, 浦坦, 李道火, Al3+, Zn2+替代镍离子的纳米氢氧化镍电极材料, 电源技术,  28(5), 276(2003))

9 C.Nethravathi, N.Ravishankar, C.Shivakumara, M.Rajamathi, Nanocomposites of α–hydroxides of nickel and cobalt by delamination and co–stacking: Enhanced stability of α–motifs in alkaline medium and electrochemical behaviour, Journal of Power Sources, 172(2), 970(2007)

10 A.B.B´el´ek´e, M.Mizuhata, Electrochemical properties of nickel | aluminum layered double hydroxide/carbon composite fabricated by liquid phase deposition, Journal of Power Sources, 22(195), 7669(2010)

11 J.Qi, P.Xu, Z.Lv, X.Liu, A.Wen, Effect of crystallinity on the electrochemical performance of nanometer Al–stabilizedα–nickel hydroxide, Journal of Alloys and Compounds, 462(1/2), 164(2008)

12 M.E.P´erez–Bernal, R.J.Ruano–Casero, F.Benitoa, V.Rives, Nickel | aluminum layered double hydroxides prepared via inverse micelles formation, Solid State Chemistry, 182(6), 1593(2009)

13 H.Wang, Z.Tang, Y.Liu, H.Lee, Synthesis and behavior of Al–stabilized α–Ni(OH)2, Transactions of Nonferrous Metals Society of China, 19(1), 170(2009)

14 X.Kong, X.Liu, Y.He, D.Zhang, X.Wang, Y.Li, Hydrothermal synthesis of β–nickel hydroxide microspheres with flakelike nanostructures and their electrochemical properties, Materials Chemistry and Physics, 106(2/3), 375(2007)

15 Q.Jiao, Z.Tian, Y.Zhao, Preparation of nickel hydroxide nanorods/nanotubes and microscopic nanorings under hydrothermal conditions, Journal of Nanoparticle Research, 9(3), 519(2007)

16 R.S.Jayashree, P.V.Kamath, Layered double hydroxide of Ni with Cr and Mn as candidate electrode materials for alkaline secondary cells, Journal of Power Sources, 107(1), 120(2003)

17 T.Pan, J.M.Wang, Y.L.Zhao, H.Chen, H.M.Xiao, J.Q.Zhang, Al–stabilized α–nickel hydroxide prepared by electrochemical impregnation, Materials Chemistry and Physics, 78(3), 711(2003)

18 ZHANG Qian, XU Yanhui, WANG Xiaolin, The preparation and electrochemical performance of α–Ni(OH)2 with different Al contents, Rare Metal Materials and Engineering, 35(5), 690(2006)

(张倩, 徐艳辉, 王晓琳, 不同Al含量α--Ni(OH)2 的制备及电化学性能研究, 稀有金属材料与工程,  35(5), 690(2006))

19 H.Zhang, H.Liu, X.Cao, S.S.Li, C.Sun, Preparation and properties of the aluminum–substituted α–Ni(OH)2, Materials Chemistry and Physics, 79(1), 37(2003)

20 ZHANG Qian,XU Yanhui, WANG Xiaolin, The structure and electrochemical performance of Al–doped α–Ni(OH)2, Rare Metal Materials and Engineering, 32(10), 825(2003)

(张倩, 徐艳辉, 王晓琳, Al代α--Ni(OH)2的结构与电化学性能, 稀有金属材料与工程,  32(10), 825(2003))

21 L.J.Yang, X.P.Gao, Q.D.Wu, H.Y.Zhu, and G.L.Pan, Phase distribution and electrochemical properties of Al–substituted nickel hydroxides, The Journal of Physical Chemistry C, 111(12), 4614(2007)

22 ZHANG Wenkui, HUANG Na, HUANG Hui, GAN Yongping, Preparation of flaky α–Ni(OH)2 by coprecipitation method, The Chinese Journal of Nonferrous Metals, 17(1), 166(2007)

(张文魁, 黄娜, 黄辉, 甘永平, 均匀沉淀法制备片状结构a--Ni(OH)2, 中国有色金属学报, 17(1), 166(2007))

23 B.Liu, H.Yuan, Y.Zhang, Impedance of Al–substituted α–nickel hydroxide electrodes, International Journal of Hydrogen Energy, 29(5), 453(2004)

24 H.Li, J.Ma, Molecular dynamics modeling of the structure andbinding energies of a–nickel hydroxides and nickel–aluminum layered double hydroxides containing various interlayer guest anions, Chemistry of Materials, 18, 4405(2006)

25 Y.W.Li, J.H.Yao, C.J.Liu, W.M.Zhao, W.X.Deng, S.K.Zhong, Effect of interlayer anions on the electrochemical performance of Al–substituted α–type nickel hydroxide electrodes, International Journal of Hydrogen Energy, 35(6), 2539(2010)
[1] MAO Jianjun, FU Tong, PAN Hucheng, TENG Changqing, ZHANG Wei, XIE Dongsheng, WU Lu. Kr Ions Irradiation Damage Behavior of AlNbMoZrB Refractory High-entropy Alloy[J]. 材料研究学报, 2023, 37(9): 641-648.
[2] ZHAO Zhengxiang, LIAO Luhai, XU Fanghong, ZHANG Wei, LI Jingyuan. Hot Deformation Behavior and Microstructue Evolution of Super Austenitic Stainless Steel 24Cr-22Ni-7Mo-0.4N[J]. 材料研究学报, 2023, 37(9): 655-667.
[3] XING Dingqin, TU Jian, LUO Sen, ZHOU Zhiming. Effect of Different C Contents on Microstructure and Properties of VCoNi Medium-entropy Alloys[J]. 材料研究学报, 2023, 37(9): 685-696.
[4] OUYANG Kangxin, ZHOU Da, YANG Yufan, ZHANG Lei. Microstructure and Tensile Properties of Mg-Y-Er-Ni Alloy with Long Period Stacking Ordered Phases[J]. 材料研究学报, 2023, 37(9): 697-705.
[5] PAN Xinyuan, JIANG Jin, REN Yunfei, LIU Li, LI Jinghui, ZHANG Mingya. Microstructure and Property of Ti / Steel Composite Pipe Prepared by Hot Extrusion[J]. 材料研究学报, 2023, 37(9): 713-720.
[6] XIONG Shiqi, LIU Enze, TAN Zheng, NING Likui, TONG Jian, ZHENG Zhi, LI Haiying. Effect of Solution Heat Treatment on Microstructure of DZ125L Superalloy with Low Segregation[J]. 材料研究学报, 2023, 37(8): 603-613.
[7] SHI Chang, DU Yuhang, LAI Liming, XIAO Siming, GUO Ning, GUO Shengfeng. Mechanical Properties and Oxidation Resistance of a Refractory Medium-entropy Alloy CrTaTi[J]. 材料研究学报, 2023, 37(6): 443-452.
[8] LEI Zhiguo, WEN Shengping, HUANG Hui, ZHANG Erqing, XIONG Xiangyuan, NIE Zuoren. Influence of Rolling Deformation on Microstructure and Mechanical Properties of Al-2Mg-0.8Cu(-Si) Alloy[J]. 材料研究学报, 2023, 37(6): 463-471.
[9] LI Yanwei, LUO Kang, YAO Jinhuan. Lithium Ions Storage Properties of Ni(OH)2 Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient[J]. 材料研究学报, 2023, 37(6): 453-462.
[10] XIA Bo, WANG Bin, ZHANG Peng, LI Xiaowu, ZHANG Zhefeng. Effect of Tempering Temperature on Microstructure and Impact Properties of Two High-strength Leaf Spring Steels[J]. 材料研究学报, 2023, 37(5): 341-352.
[11] ZHANG Shuaijie, WU Qian, CHEN Zhitang, ZHENG Binsong, ZHANG Lei, XU Pian. Effect of Mn on Microstructure and Properties of Mg-Y-Cu Alloy[J]. 材料研究学报, 2023, 37(5): 362-370.
[12] ZHANG Ruixue, MA Yingjie, JIA Yandi, HUANG Sensen, LEI Jiafeng, QIU Jianke, WANG Ping, YANG Rui. Microstructure Evolution and Element Partitioning Behavior during Heat-treatment in Metastable β Titanium Alloy[J]. 材料研究学报, 2023, 37(3): 161-167.
[13] LIN Shifeng, XU Dongan, ZHUANG Yanxin, ZHANG Haifeng, ZHU Zhengwang. Preparation and Mechanical Properties of TiZr-based Bulk Metallic Glass/TC21 Titanium Alloy Dual-layered Composites[J]. 材料研究学报, 2023, 37(3): 193-202.
[14] DONG Yu'ang, YANG Huajie, BEN Dandan, MA Yunrui, ZHOU Xianghai, WANG Bin, ZHANG Peng, ZHANG Zhefeng. Excellent Cryogenic Tensile Properties of Ultra-fine Grained 316L Stainless Steel after Electropulsing Treatment in Liquid Nitrogen[J]. 材料研究学报, 2023, 37(3): 168-174.
[15] ZHAO Yunmei, ZHAO Hongze, WU Jie, TIAN Xiaosheng, XU Lei. Effect of Heat Treatment on Microstructure and Properties of TIG Welded Joints of Powder Metallurgy Inconel 718 Alloy[J]. 材料研究学报, 2023, 37(3): 184-192.
No Suggested Reading articles found!