SiCf/SiC复合材料用B-N-Si新型界面相的高通量制备与性能研究

doi:10.11901/1005.3093.2025.348

材料研究学报

2026, Vol. 40

Issue (8): 624-630 DOI: 10.11901/1005.3093.2025.348

研究论文

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SiC_f/SiC复合材料用B-N-Si新型界面相的高通量制备与性能研究

雷一明¹, 石金瑜¹^,², 吕熙睿¹, 张洁¹(

), 王京阳¹

^1.中国科学院金属研究所沈阳材料科学国家研究中心沈阳 110016
^2.中国科学技术大学材料科学与工程学院沈阳 110016

High-throughput Screening of a Novel B-N-Si Interphase for Continuous SiC Fiber Reinforced SiC Ceramic Matrix Composites

LEI Yiming¹, SHI Jinyu¹^,², LV Xirui¹, ZHANG Jie¹(

), WANG Jingyang¹

^1.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

雷一明, 石金瑜, 吕熙睿, 张洁, 王京阳. SiC_f/SiC复合材料用B-N-Si新型界面相的高通量制备与性能研究[J]. 材料研究学报, 2026, 40(8): 624-630.
Yiming LEI, Jinyu SHI, Xirui LV, Jie ZHANG, Jingyang WANG. High-throughput Screening of a Novel B-N-Si Interphase for Continuous SiC Fiber Reinforced SiC Ceramic Matrix Composites[J]. Chinese Journal of Materials Research, 2026, 40(8): 624-630.

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摘要:

连续碳化硅纤维增强碳化硅陶瓷基复合材料(SiC_f/SiC)中，界面相通常对载荷传递、界面解离及纤维保护起着关键作用，进而决定了复合材料的力学性能、热力学稳定性及耐腐蚀性。针对热解碳和六方氮化硼等传统界面相高温水蒸气氧化性能较差的瓶颈，本研究聚焦B-N-Si新型界面相。采用高通量组合材料芯片制备及表征技术，系统研究了Si含量对其结构、力学性能以及抗高温水蒸气氧化性能的影响。结果表明，在室温沉积的B-N-Si薄膜均为非晶结构，且掺杂的硅原子倾向于取代硼原子形成Si-N键。Si含量(原子分数)为7.57%~19.66%的薄膜均满足裂纹偏转的力学判据，具有理想的增韧潜力；Si含量高于11.76%的薄膜在900 ℃、90%H₂O-10%O₂条件下因氧化生成B₂O₃‧SiO₂玻璃相而膨胀，具有优异的自愈合能力和抗氧化性能。

关键词 ：材料表面与界面, 组合材料芯片, 界面相, 裂纹偏转, 水蒸气氧化

Abstract：

Continuous SiC fiber reinforced SiC ceramic matrix composites are promising high-temperature structural materials for aerospace applications, whose performance is strongly influenced by the interphase between the fiber and the matrix. Although traditional interphases such as pyrolytic carbon and hexagonal boron nitride possess a layered structure, the resistance against high-temperature steam oxidation is relatively poor. This work focused on the B-N-Si ternary system as a novel interphase candidate. The effect of Si content on the structure, mechanical properties, and high-temperature water vapor oxidation behavior of B-N-Si interphase material were systematically investigated by means of high-throughput fabrication and characterization technique. The results showed that all B-N-Si coatings deposited at room temperature exhibited an amorphous structure, with silicon atoms preferentially replacing boron atoms and forming Si-N bonds. When silicon content was in the range of 7.57%-19.66% (atomic fraction), all coatings satisfied the mechanical requirements for crack deflection. Moreover, when the silicon content exceeds 11.76%, the coatings could swell up after oxidation at 900 ^oC in a 90%H₂O-10%O₂ atmosphere due to the formation of B₂O₃·SiO₂ glass phase, exhibiting remarkable self-healing capability and oxidation resistance.

Key words： surface and interface in the materials combinatorial material chip interphase crack deflection steam oxidation resistance

收稿日期: 2025-11-26

ZTFLH:

TG174.2

基金资助:国家重点研发计划(2022YFB3707700)

通讯作者: 张洁，研究员，jiezhang@imr.ac.cn，研究方向为极端环境陶瓷涂层应用基础

Corresponding author: ZHANG Jie, Tel: (024)23970490, E-mail: jiezhang@imr.ac.cn

作者简介: 雷一明，男，1992年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2025.348 或 https://www.cjmr.org/CN/Y2026/V40/I8/624

图1 制备在单晶氧化铝上的组合材料芯片光学照片和Si含量分布图

图2 不同Si含量样品的XPS图谱

图3 B-N-Si薄膜的硬度和模量与Si含量的关系

图4 裂纹偏转潜能(σic/σ2c)与两侧材料模量比值E2/E1的关系[22]

图5 B-N-Si薄膜在900 ℃、90%H2O-10%O2条件下氧化前后的厚度变化

图6 Si含量为7.57%、8.22%、11.76%和17.44%的B-N-Si薄膜在900 ℃、90%H2O-10%O2条件下氧化后的表面形貌

[1]	Diaz O G, Luna G G, Liao Z R, et al. The new challenges of machining Ceramic Matrix Composites (CMCs): review of surface integrity [J]. Int. J. Mach. Tools Manuf., 2019, 139: 24 doi: 10.1016/j.ijmachtools.2019.01.003
[2]	Jones R H, Giancarli L, Hasegawa A, et al. Promise and challenges of SiC_f/SiC composites for fusion energy applications [J]. J. Nucl. Mater., 2002, 307-311(Part 2): 1057
[3]	Padture N P. Advanced structural ceramics in aerospace propulsion [J]. Nat. Mater., 2026, 15: 804 doi: 10.1038/nmat4687
[4]	Wang P R, Liu F Q, Wang H, et al. A review of third generation SiC fibers and SiC_f/SiC composites [J]. J. Mater. Sci. Technol., 2019, 35(12): 2743 doi: 10.1016/j.jmst.2019.07.020
[5]	Liu Z F, Li Z Q, Li Q, et al. Ultra-high strength and toughness continuous SiC_f/SiC ceramic matrix composites prepared by an additive manufacturing manipulator [J]. J. Eur. Ceram. Soc., 2025, 45(6): 117176 doi: 10.1016/j.jeurceramsoc.2024.117176
[6]	Morscher G N, Yun H M, Dicarlo J A, et al. Effect of a boron nitride interphase that debonds between the interphase and the matrix in SiC/SiC composites [J]. J. Am. Ceram. Soc., 2004, 87: 104 doi: 10.1111/jace.2004.87.issue-1
[7]	Chen M L, Pan L, Xia X D, et al. Boron nitride (BN) and BN based multiple-layer interphase for SiC_f/SiC composites: A review [J]. Ceram. Int., 2022, 48(23): 34107 doi: 10.1016/j.ceramint.2022.07.021
[8]	Ji S Y, Liang B, Hu C L, et al. Mechanical properties and oxidation behaviors of self-healing SiC_f/SiC-SiBCN composites exposed to H₂O/O₂/Na₂SO₄ environments [J]. Acta Metall. Sin. (Engl. Lett.), 2023, 36(11): 1909 doi: 10.1007/s40195-023-01596-7
[9]	Rezaie A, Fahrenholtz W G, Hilmas G E. Oxidation of zirconium diboride-silicon carbide at 1500℃ at a low partial pressure of oxygen [J]. J. Am. Ceram. Soc., 2006, 89: 3240 doi: 10.1111/jace.2006.89.issue-10
[10]	Duan X M, Yang Z H, Chen L, et al. Review on the properties of hexagonal boron nitride matrix composite ceramics [J]. J. Eur. Ceram. Soc., 2016, 36(15): 3725 doi: 10.1016/j.jeurceramsoc.2016.05.007
[11]	Sathiyamoorthy R, Prakash K S, Sathishkumar C, et al. Investigation on SiC_f/SiC composites with SiBN interface processed through chemical vapor infiltration [J]. Mater. Today Proc., 2016, 3(10): 4220
[12]	Moore A W, Sayir H, Fanner S C, et al. Improved interface coatings for SiC fibers in ceramic composites [A]. Proceedings of the 19th Annual Conference on Composites, Advanced Ceramics, Materials, and Structures—A: Ceramic Engineering and Science Proceedings, Volume 16 [C]. Florida: The American Ceramic Society, 1995: 409
[13]	Morscher G N, Bryant D R and Tressler R E. Environmental durability of BN-based interphases (for SiC_f/SiC_m composites) in H₂O containing atmospheres at intermediate temperatures [A]. Proceedings of the 21st Annual Conference on Composites, Advanced Ceramics, Materials, and Structures—A: Ceramic Engineering and Science Proceedings, Volume 18 [C]. Florida: The American Ceramic Society, 1997: 525
[14]	Zhang S Y, Liu M, Luo Y X, et al. Theoretical prediction on structure evolution and optimal properties of silicon modified hexagonal boron nitride as interphase in SiC_f/SiC composite [J]. J. Eur. Ceram. Soc., 2022, 42(13): 5323 doi: 10.1016/j.jeurceramsoc.2022.06.074
[15]	Liu B, Zhao J L, Liu Y C, et al. Application of high-throughput first-principles calculations in ceramic innovation [J]. J. Mater. Sci. Technol., 2021, 88: 143 doi: 10.1016/j.jmst.2021.01.071
[16]	Lv X R, Lei Y M, Zhang Z, et al. Accelerating the design of multicomponent rare earth silicates for SiC_f/SiC CMC by combinatorial material chip design and high throughput screening [J]. J. Mater. Sci. Technol., 2023, 150: 96 doi: 10.1016/j.jmst.2022.11.043
[17]	Yang L Y, Wang L M, Dong S, et al. Lightweight C_f/HC-SiBCN composite for multifunctional applications [J]. J. Adv. Ceram., 2025, 14(5): 9221068 doi: 10.26599/JAC.2025.9221068
[18]	Chen M L, Pan L, Xia X D, et al. Boron nitride (BN) and BN based multiple-layer interphase for SiC_f/SiC composites: a review [J]. Ceram. Int., 2022, 48(23): 34107 doi: 10.1016/j.ceramint.2022.07.021
[19]	Alkoy S, Toy C, Gönül T, et al. Crystallization behavior and characterization of turbostratic boron nitride [J]. J. Eur. Ceram. Soc., 1997, 17(12): 1415 doi: 10.1016/S0955-2219(97)00040-X
[20]	Le Gallet S, Chollon G, Rebillat F, et al. Microstructural and microtextural investigations of boron nitride deposited from BCl₃-NH₃-H₂ gas mixtures [J]. J. Eur. Ceram. Soc., 2004, 24(1): 33 doi: 10.1016/S0955-2219(03)00126-2
[21]	Liu Y S, Chai N, Li Z, et al. Effect of deposition temperature on deposition kinetics and mechanism of silicon boron nitride coating deposited from SiCl₄-BCl₃-NH₃-H₂-Ar mixture using low pressure chemical vapor deposition [J]. Surf. Coat. Technol., 2015, 261: 295 doi: 10.1016/j.surfcoat.2014.11.015
[22]	Pompidou S, Lamon J. Analysis of crack deviation in ceramic matrix composites and multilayers based on the Cook and Gordon mechanism [J]. Compos. Sci. Technol., 2007, 67(10): 2052 doi: 10.1016/j.compscitech.2006.11.013
[23]	Jacobson N S, Morscher G N, Bryant D R, et al. High-temperature oxidation of boron nitride: II, boron nitride layers in composites [J]. J. Am. Ceram. Soc., 1999, 82(6): 1473 doi: 10.1111/jace.1999.82.issue-6
[24]	Detwiler K N, Opila E J. Oxidation of SiC/BN/SiC ceramic matrix composites in dry and wet oxygen at intermediate temperatures [J]. J. Eur. Ceram. Soc., 2022, 42(10): 4110 doi: 10.1016/j.jeurceramsoc.2022.04.003
[25]	Yang H T, Lu Z L, Bie B X, et al. Microstructure and damage evolution of SiC_f/PyC/SiC and SiC_f/BN/SiC mini-composites: A synchrotron X-ray computed microtomography study [J]. Ceram. Int., 2019, 45(9): 11395 doi: 10.1016/j.ceramint.2019.03.004
[26]	Christensen V L, Zok F W. Insights into internal oxidation of SiC/BN/SiC composites [J]. J. Am. Ceram. Soc., 2023, 106: 1561 doi: 10.1111/jace.v106.2
[27]	Quemard L, Rebillat F, Guette A, et al. Self-healing mechanisms of a SiC fiber reinforced multi-layered ceramic matrix composite in high pressure steam environments [J]. J. Eur. Ceram. Soc., 2007, 27(4): 2085 doi: 10.1016/j.jeurceramsoc.2006.06.007

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