Ni-Al2O3/Diamond复合涂层的制备和性能

doi:10.11901/1005.3093.2024.314

材料研究学报

2025, Vol. 39

Issue (4): 314-320 DOI: 10.11901/1005.3093.2024.314

研究论文

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Ni-Al₂O₃/Diamond复合涂层的制备和性能

李红蕾¹, 刘闯¹, 卢政伟², 褚天义¹, 陈育秋¹, 姜肃猛¹, 宫骏¹, 裴志亮¹(

)

^1.中国科学院金属研究所沈阳 110016
^2.中国航发湖南动力机械研究所株洲 412002

Preparation and Performance of Ni-Al₂O₃/Diamond Composite Coating

LI Honglei¹, LIU Chuang¹, LU Zhengwei², CHU Tianyi¹, CHEN Yuqiu¹, JIANG Sumeng¹, GONG Jun¹, PEI Zhiliang¹(

)

^1.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.AECC Hunan Aviation Powerplant Research Institute, Zhuzhou 412002, China

引用本文:

李红蕾, 刘闯, 卢政伟, 褚天义, 陈育秋, 姜肃猛, 宫骏, 裴志亮. Ni-Al₂O₃/Diamond复合涂层的制备和性能[J]. 材料研究学报, 2025, 39(4): 314-320.
Honglei LI, Chuang LIU, Zhengwei LU, Tianyi CHU, Yuqiu CHEN, Sumeng JIANG, Jun GONG, Zhiliang PEI. Preparation and Performance of Ni-Al₂O₃/Diamond Composite Coating[J]. Chinese Journal of Materials Research, 2025, 39(4): 314-320.

全文: PDF(11881 KB) HTML

摘要:

在电镀液中加入纳米Al₂O₃颗粒和微米金刚石颗粒进行电沉积，使金属镍、Al₂O₃颗粒与金刚石颗粒共沉积制备出Ni-Al₂O₃/Diamond (金刚石)复合涂层，为了比较还制备了Ni-Al₂O₃复合涂层。使用XRD和SEM观察等手段表征涂层的形貌、组织结构和成分并测试了摩擦磨损性能和力学性能。结果表明：Ni-Al₂O₃/Diamond复合涂层致密、连续，耐磨颗粒在涂层中分布均匀；涂层与基体结合良好，平均结合强度高于55.2 MPa；涂层对基体的拉伸性能影响很小，其磨损率比基体降低了43.8%，比Ni-Al₂O₃复合涂层磨损率降低了76.4%。Ni-Al₂O₃/Diamond复合涂层的磨损机制为磨粒磨损和粘着磨损。

关键词 ：材料表面与界面, 电沉积, Al₂O₃, 金刚石, 组织结构, 摩擦磨损

Abstract：

Ni-nano-Al₂O₃/micro-Diamond composite coating was prepared by electrodeposition on 9310 carburizing steel. The morphology, microstructure, composition of the composite coating were characterized by XRD and SEM, while its bond strength, tensile properties and wear resistance were also tested. Ni-Al₂O₃/Diamond composite coating is dense and continuous. The average bonding strength between the coating and the substrate is higher than 55.2 MPa. The wear rate of the composite coating is reduced by 43.8% compared with the 9310 carburizing steel and reduced by 76.4% compared with the Ni-Al₂O₃ composite coating. Wear mechanism of the composite coating was abrasive wear and adhesive wear by analyzing wear tracks.

Key words： surface and interface in the materials electrodeposition Al₂O₃ diamond microstructure friction and wear

收稿日期: 2024-07-24

ZTFLH:

TG174.4

通讯作者: 裴志亮，副研究员，zlpei@imr.ac.cn，防护涂层的研制与应用

Corresponding author: PEI Zhiliang, Tel: (024)23971448, E-mail: zlpei@imr.ac.cn

作者简介: 李红蕾，男，1992年生，工程师

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https://www.cjmr.org/CN/10.11901/1005.3093.2024.314 或 https://www.cjmr.org/CN/Y2025/V39/I4/314

图1 拉伸试样的示意图

图2 复合涂层的表面形貌和截面形貌

图3 Ni-Al2O3涂层和Ni-Al2O3/Diamond复合涂层的XRD谱

图4 涂层的拉伸断口形貌和结合强度

图5 基体未渗碳和渗碳涂层的拉伸性能

表1 9310钢和9310渗碳钢的拉伸性能

图6 渗碳拉伸样品的断口SEM形貌

图7 基体和复合涂层的摩擦系数随时间变化曲线和磨痕截面形貌

图8 基体、Ni-Al2O3涂层以及Ni-Al2O3 /Diamond涂层的磨痕形貌

图9 基体、Ni-Al2O3涂层以及Ni-Al2O3 /Diamond涂层对应的磨球表面形貌

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