<strong>Cr</strong>含量对<strong>Ni-Fe-Cr-Al</strong>合金抗氧化性能的影响

doi:10.11901/1005.3093.2023.557

材料研究学报

2024, Vol. 38

Issue (10): 732-740 DOI: 10.11901/1005.3093.2023.557

研究论文

本期目录 | 过刊浏览

Cr含量对Ni-Fe-Cr-Al合金抗氧化性能的影响

张凯¹, 付广艳¹(

), 刘恩泽², 谭政², 宁礼奎², 郑志²

^1.沈阳化工大学机械与动力工程学院沈阳 110142
^2.中国科学院金属研究所沈阳 110016

Effect of Cr Content on Oxidation Resistance of Ni-Fe-Cr-Al Alloy

ZHANG Kai¹, FU Guangyan¹(

), LIU Enze², TAN Zheng², NING Likui², ZHENG Zhi²

^1.School of Mechanical and Power Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
^2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

引用本文:

张凯, 付广艳, 刘恩泽, 谭政, 宁礼奎, 郑志. Cr含量对Ni-Fe-Cr-Al合金抗氧化性能的影响[J]. 材料研究学报, 2024, 38(10): 732-740.
Kai ZHANG, Guangyan FU, Enze LIU, Zheng TAN, Likui NING, Zhi ZHENG. Effect of Cr Content on Oxidation Resistance of Ni-Fe-Cr-Al Alloy[J]. Chinese Journal of Materials Research, 2024, 38(10): 732-740.

全文: PDF(15439 KB) HTML

摘要:

用不连续称重法表征了Cr含量(质量分数)分别为20%、24%和28%的Ni-Fe-Cr-Al合金在1200℃空气中氧化后氧化膜的形貌和相组成，研究了这类合金的氧化行为。结果表明：这三种不同Cr含量的Ni-Fe-Cr-Al合金在1200℃氧化100 h后其氧化动力学曲线都符合抛物线规律，氧化速率相近，Cr含量的提高使其抗氧化性能有所提高。这三种Ni-Fe-Cr-Al合金在1200℃氧化1 h后生成的氧化膜均具有两层结构，外层由Cr₂O₃和少量尖晶石氧化物NiCr₂O₄组成,内层为Al₂O₃层；氧化100 h后氧化膜仍为两层结构，与氧化1 h的不同之处是外层主要由混合尖晶石和少量Cr₂O₃组成，混合尖晶石为NiCr₂O₄、NiFe₂O₄，内层为连续Al₂O₃层。这三种合金在氧化过程中均出现明显的内氮化。Cr含量的提高对氧化1 h发生的内氮化有一定的抑制。随着氧化时间的延长(100 h)这三种合金的内氮化深度相近，提高Cr含量对内氮化影响不大。

关键词 ：金属材料, Ni-Fe-Cr-Al合金, 氧化动力学, 内氮化, Cr含量

Abstract：

The oxidation behavior of Ni-Fe-Cr-Al alloys with Cr content of 20%Cr, 24%Cr and 28%Cr (mass percentage) respectively at 1200^oC in air for 100 h were studied by intermittent weighing method. The microstructure and phase composition of the alloys and oxide scales were also characterized. The results show that the oxidation kinetics curves of the three alloys all conform to the parabolic law. The oxidation resistance of the alloys is enhanced with the increasing Cr content. A two-layered oxide scale is formed on the surface of the three alloys after oxidation at 1200^oC for 1 h, i.e. the outer layer was composed of Cr₂O₃ and a small amount of spinel oxide NiCr₂O₄, and the inner layer was Al₂O₃ layer. After 100 h oxidation, the oxide scale still has a two-layered structure, which is slightly different from those of the 1 h oxidation, namely, the outer layer is mainly composed of mixed spinel and a small amount of Cr₂O₃, the mixed spinel is NiCr₂O₄ and NiFe₂O₄, and the inner one is continuous Al₂O₃ layer. The three Ni-Fe-Cr-Al alloys with different Cr content showed obvious internal nitriding during air oxidation. When oxidized for 1 h, the increase of Cr content presents a certain inhibitory effect on internal nitriding. With the extension of oxidation time (100 h), the nitriding depth of the three alloys is similar, and the increase of Cr content has little effect on the internal nitriding.

Key words： metallic materials Ni-Fe-Cr-Al alloy oxidation kinetics internal nitriding Cr content

收稿日期: 2023-11-22

ZTFLH:

TG132.3+3

基金资助:国家重点研发计划(2021YFC2202402)

通讯作者: 付广艳，教授，Fu_guangyan@126.com，研究方向为金属材料及腐蚀与防护技术

Corresponding author: FU Guangyan, Tel: 13504997591, E-mail: Fu_guangyan@126.com

作者简介: 张凯，男，1998年生，硕士生

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表1 实验用合金的名义成分

图1 三种Ni-Fe-Cr-Al合金在1200℃氧化100 h的氧化动力学曲线

表2 三种合金的氧化抛物线速率常数Kp

图2 三种Ni-Fe-Cr-Al合金在1200℃氧化后单位面积增重的平方随时间的变化

图3 三种合金在1200℃氧化1 h和100 h后表面氧化产物的XRD谱

图4 三种合金在1200℃氧化不同时间后的表面形貌

表3 20%Cr合金氧化后表面不同位置的EDS分析

图5 三种合金在1200℃氧化不同时间后的横截面形貌

图6 20%Cr合金在1200℃氧化不同时间后的横截面EDS面扫结果

表4 三种合金在1200℃氧化1 h和100 h后的横截面不同位置的EDS分析

图7 合金在1200℃氧化不同时间后AlN的分布

图8 三种合金在1200℃氧化1 h和100 h后内氮化深度

图9 Ni-Fe-Cr-Al合金在1200℃氧化过程的示意图

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