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| Preparation and Properties of Carbon Coated Manganese Dioxide Electrode Materials |
Shuang PAN,Xue ZHUANG,Bing WANG( ),Lidan TANG,Liang LIU,Jingang QI |
| School of Materials Science and Engineering, Liaoning of Technology, Jinzhou 121000, China |
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Cite this article:
Shuang PAN,Xue ZHUANG,Bing WANG,Lidan TANG,Liang LIU,Jingang QI. Preparation and Properties of Carbon Coated Manganese Dioxide Electrode Materials. Chinese Journal of Materials Research, 2019, 33(7): 530-536.
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Abstract Manganese dioxide powders were firstly prepared via electric pulse assisted redox method with KMnO4 and MnSO4 as raw material, then MnO2/C composite materials coated with different amounts of carbon were fabricated via liquid phase sintering with glucose as a carbon source. The effect of amount of coated carbon on the morphology, structure and electrochemical properties of the MnO2/C materials were investigated. Results show that the coated carbon could induce the transformation of crystallographic structure of MnO2 from γ-type into α-type. Under heating conditions glucose decomposed and coated on the surface of MnO2 particles, which could inhibit the grain growth and thus refine grains. When the preparation with the process parameters: glucose concentration was 1.5 g/L and the current density was 2 A·g-1, the prepared MnO2/C material presented the specific capacitance of MnO2 of 722.2 F·g-1, in other words, the carbon coating could increase the specific capacitance by 80%, in comparison with that of the blank ones. Furthermore, after 4000 charge-discharge cycles, the capacitance retention rate could still maintain 74.72%, displayed good electrochemical performance and cycling performance.
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Received: 05 November 2018
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| Fund: Liaoning Natural Science Foundation(2015020215);Liaoning Provincial University Talents Project(LJQ2015050);Liaoning Education Department General Project(L2035236) |
| [1] | Xing B L, Huang G, Zhan L J, et al. Research status and prospects of supercapacitor electrode materials [J]. Matererial News, 2012, 26(10): 21 | | [1] | (刑宝林, 黄光, 谌伦建等. 超级电容器电极材料的研究现状与展望 [J]. 材料导报, 2012, 26(10): 21) | | [2] | Peng X, Peng L, Wu C, et al. Two dimensional nanomaterials for flexible supercapacitors [J]. Chemical Society Reviews, 2014, 45(26): 3303 | | [3] | Borysiewicz M. A., Ekielski M., Ogorza?ek Z., et al. Highly transparent supercapacitors based on ZnO/MnO2 nanostructures [J]. Nanoscale, 2017, 9(22): 7577 | | [4] | Xia X H, Chao D L, Zhang Y Q, et al. Generic synthesis of carbon nanotube branches on metal oxide arrays exhibiting stable high-rate and long-cycle sodium-ion storage [J]. Small, 2016, 12(22): 3048 | | [5] | Cao J, Li X, Wang Y, et al. Materials and fabrication of electrode scaffolds for deposition of MnO2 and their true performance in supercapacitors [J]. Power Source, 2015, 293(20): 657 | | [6] | Dubal S V, Patil G. Polyaniline-polypyrrole nanograined composite via electrostatic adsorption for high performance electrochemical supercapacitors [J]. Journal of Alloys and Compounds, 2013, 552(5): 240 | | [7] | Kazemi S, Kiani M, Mohamadi R, et al. Metal-polyaniline nanofibre composite for supercapacitor applications [J]. Bulletin of Materials Science, 2014, 37(5): 1001 | | [8] | Wei W, Cui X, Chen W, et al. Manganese oxide-based materials as electrochemical supercapacitor electrodes [J]. Chemical Society Reviews, 2011, 40(3): 1697 | | [9] | Zhao Y, Ran W, He J, et al. High-performance asymmetric supercapacitors based on multilayer MnO2/graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability [J]. Small, 2015, 11(11): 1310 | | [10] | Huang M, Mi R, Liu H, et al. Layered manganese oxides-decorated and nickel foam-supported carbon nanotubes as advanced binderfree supercapacitor electrodes [J]. Power Source, 2014, 269(10): 760 | | [11] | Yu Z, Duong B, Abbitt D, et al. Highly ordered MnO2 nanopillars for enhanced supercapacitor performance [J]. Advanced Materials, 2013, 25(24): 3302 | | [12] | Li S, Qi L, Lu L, et al. Facile preparation and performance of mesoporous manganese oxide for supercapacitors utilizing neutralaqueous electrolytes [J]. RSC Advanced, 2012, 2(8): 3298 | | [13] | Jiang J, Li Y, Liu J, et al. Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage [J]. Advanced Materials, 2012, 24(38): 5166 | | [14] | Machefaux E, Verbaere A, Guyomard D. Preparation of nanowires of M substituted manganese dioxides (M=Al, Co, Ni) by the electrochemical hydrothermal method [J]. Journal of Physics and Chemistry of Solids, 2013, 67(5-6): 1315 | | [15] | Chun K Y, Ryu C W, Kim K B. Onset mechanism of Jahn-Teller distortion in 4V LiMn2O4 and its suppression by LiM0.05Mn1.95O4 (M=Co, Ni)coating [J]. Journal of the Electrochemical Society, 2005, 152(4): A791 | | [16] | Sun M, Tie J, Cheng G, et al. In situ growth of burl-like nickel cobalt sulfide on carbon fibers as high-performance supercapacitors [J]. Materials Chemical A, 2015, 3(1): 1730 | | [17] | Su X, Yu L, Cheng G, et al. High-performance α-MnO2 nanowire electrode for supercapacitor [J]. Applied Energy, 2015, 153(1): 94 | | [18] | Yang M Y, Ni P, Li Y, et al. Synthesis and electrochemical performance of β-MnO2 with semitubular morphology [J]. Materials Chemical Physical, 2010, 124(1): 155 | | [19] | Kim Y J, Yang C M, Park K C, et al. Edge-enriched, porous carbon-based, high energy density supercapacitors for hybrid electric vehicles [J]. Chemical Sustainable Chemical, 2012, 5(3): 535 | | [20] | Cao F F, Wu X L, Xin S, et al. Facile synthesis of mesoporous TiO2-C nanosphere as an improved anode material for superior high rate 1.5V rechargeable Li ion batteries containing LiFePO4-C cathode [J]. Physical Chemistry C, 2010, 114(22): 10308 | | [21] | Liu Y, Ai C C, Hu Y, et al. Research progress of supercapacitor carbon-coated metal oxide electrode materials [J]. Chemical Lindustry and Engineering Progress, 2013, 32(2): 1849 | | [21] | (刘 洋, 艾常春, 胡 意等. 碳包覆金属氧化物作为超级电容器电极材料的研究进展 [J]. 化工进展, 2013, 32(2): 1849) | | [22] | YANG J, WANG B F, WANG K, et al. Si/C composites for high capacity lithium storage materials [J]. Electrochemical Solid-State Letterr, 2003, 6(8): A154 | | [23] | Pan S, Wang B, Ma Z J, et al. Preparation and electrochemical performance of Al-doped manganese dioxide nanowires [J]. Piezoelectrics & Acoustooptics, 2019, 41(01): 72 | | [23] | (潘 双, 王 冰, 马泽军等. 铝掺杂二氧化锰纳米线的制备及其电化学性能 [J]. 压电与声光, 2019, 41(01): 72) | | [24] | Jin E M, Lim J G, Jeong S M. Facile synthesis of graphene-wrapped CNT-MnO2 nanocomposites for asymmetric electrochemical capacitors [J]. Journal of Industrial and Engineering Chemistry, 2017, 54(25): 421 | | [25] | Li J, Ma J, Gao Y, et al. Research on solidification structure refinement of pure aluminum by electric current pulse with parallel electrodes [J]. Materials Science and Engineering A, 2008, 490(1): 452 | | [26] | Zhou X. In vitro degradation characteristic of carbon fiber reinforced polylactide (C/PLA) composite under pulsed electoimagnetic field [D]. Jinzhou: Liaoning University of Technology, 2016 | | [26] | (周 想. 脉冲电磁场作用下碳纤维增强聚乳酸(C/PLA)复合材料的降解特性 [D]. 锦州: 辽宁工业大学, 2016) | | [27] | Zhang D. Effects and Mechanism of LaxSr1-xCryNi1-yO3 Powders' Exsolution Characteristics under Pulsed Current [D]. Jinzhou: Liaoning University of Technology, 2018 | | [27] | (张 迪. 脉冲电流对LaxSr1-xCryNi1-yO3溶出特性的影响及其作用机理 [D]. 锦州: 辽宁工业大学, 2018) | | [28] | Fang L. The Preparation and Eelectrochemical Performance of MnO2 Assisted with Pulse Electromagnetic Field [D]. Jinzhou: Liaoning University of Technology, 2018 | | [28] | (方 琳. 脉冲电磁场辅助制备二氧化锰及其电化学性能研究 [D]. 锦州: 辽宁工业大学, 2018) | | [29] | Liu K Y, Zhang Y, Zhang W, et al. Charge-discharge process of MnO2 supercapacitor [J]. Transactions of Nonfcrrous Metals Society of China, 2007, 17(3): 649 | | [30] | Zhang X, Sun X, Zhang H, et al. Comparative performance of birnessite-type MnO2 nanoplates and octahedral molecular sieve(OMS-5) nanobelts of manganese dioxide as electrode materials for supercapacitor application [J]. Electrochimica Acta, 2014, 132(03): 315 |
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