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Chinese Journal of Materials Research  2021, Vol. 35 Issue (6): 467-473    DOI: 10.11901/1005.3093.2020.357
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Interficial Bonding within Cu-based Composites Reinforced with TiC- or Ni-coated Carbon Fiber
YANG Yana, CHEN Wenge(), XUE Yuanlin
School of Materials Science and Engineering, Xi′an University of Technology, Xi′an 710000, China
Cite this article: 

YANG Yana, CHEN Wenge, XUE Yuanlin. Interficial Bonding within Cu-based Composites Reinforced with TiC- or Ni-coated Carbon Fiber. Chinese Journal of Materials Research, 2021, 35(6): 467-473.

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Abstract  

Carbon fibers were coated with thin film of TiC and Ni respectively of about 0.8 μm in thickness by means of magnetron sputtering technique. Then the Cu-based composites reinforced with 2.5 %(volume fraction) coated carbon fibers were prepared by traditional powder metallurgy technology. The results show that the mechanical and electrical properties of Cu-based composites were improved through the reinforcements. The carbon fibers were homogeneously distributed in the matrix without obvious segregation. The hardness and electrical properties of the composite with reinforcer of TiC film coated carbon fibers were 40.8HV and 91.0%IACS, respectively, and those of Ni film coated carbon fibers were 38.8HV and 79.7%IACS, respectively. It follows that interaction of couples Ti/C and Ni/Cu respectively at interfaces of coated thin film/carbon fiber/Cu-matrix could be confirmed, which is beneficial to the interfacial bonding strength.

Key words:  composites      copper-based      interface bonding      magnetron sputtering      carbon fiber     
Received:  28 August 2020     
ZTFLH:  TB333  
Fund: Key R & D Projects in Shaanxi Province(2017ZDXM-GY-050)
About author:  CHEN Wenge, Tel: 13572896325, E-mail: wgchen001@263.net

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2020.357     OR     https://www.cjmr.org/EN/Y2021/V35/I6/467

SpecificationNumber of filament/(number/bunch)Filament diameter/μmTensile strength/GPaElastic modulus/GPaDensity/g·cm-3Elongation at break/%
HTS406000~7.04.42301.771.9
Table 1  Properties of carbon fiber
Fig.1  XRD patterns of carbon fiber surface magnetron sputtered metal before and after (a) Sputtering Ti, (b) Sputtering Ni, (c) Carbon fiber
Fig.2  Morphology diagram of CFs surface before and after sputtering metal (a) The original state, (b) Surface roughening, (c) Sputtering Ti, (d) Cross section of sputtering Ti, (e) Sputtering Ni, (F) Cross section of sputtering Ni
Fig.3  Microstructure of CFs reinforced copper matrix composites (a) Strengthened by sputtering Ti, (b) Strengthened by sputtering Ni, (c) Interface between matrix and Ti-CF, (d) Element distribution of Cu-Ti-C at the interface, (e) Interface between matrix and Ni-CF, (f) Element distribution of Cu-Ni-C at the interface
Sample

Density

/g·cm-3

Relative density/%Conductivity/(%IACS)Hardness/(HV)
Sputtering TiC carbon fiber/Cu8.3796.191.040.8
Sputtering Ni carbon fiber/Cu8.3795.879.738.8
Table 2  Density, relative density, conductivity and hardness of carbon fiber reinforced copper matrix composites
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