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Preparation and Properties of Sodium Alginate/Polyacrylamide/Graphene Oxide Nanocomposite Hydrogels |
Cuiyun LIU1,2,Xiping GAO1,2,Jie LIU1,Keyong TANG1,**( ),Chang LU2,Yuqing ZHANG2 |
1. College of Materials and Engineering, Zhengzhou University, Zhengzhou 450052, China 2. School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology,Luoyang 471003, China |
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Cite this article:
Cuiyun LIU,Xiping GAO,Jie LIU,Keyong TANG,Chang LU,Yuqing ZHANG. Preparation and Properties of Sodium Alginate/Polyacrylamide/Graphene Oxide Nanocomposite Hydrogels. Chinese Journal of Materials Research, 2015, 29(7): 517-522.
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Abstract Nanocomposite hydrogels of sodium alginate (SA) / polyacrylamide (PAM)/ graphene oxide (GO) were prepared by in situ polymerization.The structure and properties of hydrogels were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscope (AFM), Fourier transform infrared spectroscopy(FTIR) and thermogravimetric analysis (TG). The effect of GO content on the chemical structure, mechanical and swelling properties of the hydrogels was investigated. The results show that the well exfoliated GO flakes could be uniformly dispersed in the polymer matrix, therewith the intermolecular interactions between the components might be enhanced and parts of PAM macromolecules chains were probably grafted onto the GO nanosheets, which in turn changed the microstructure of the hydrogels and resulted in significant enhancement of mechanical properties of the composite hydrogels. As a result, in comparison with the two hydrogeles of pure SA and pure PAM, the prepared composite hydrogels exhibited both of higher tensile strength and breaking elongation up to 200%, as well as a higher compressive strength up to 156%. The swelling capacity of the composite hydrogels increased and then declined with the increasing GO content, while increased with the increasing SA content.
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Received: 21 August 2014
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Fund: *Supported by National Natural Science Foundation of China Nos. 50973097 and 21076199. |
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