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Chinese Journal of Materials Research  2015, Vol. 29 Issue (7): 517-522    DOI: 10.11901/1005.3093.2014.438
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Preparation and Properties of Sodium Alginate/Polyacrylamide/Graphene Oxide Nanocomposite Hydrogels
Cuiyun LIU1,2,Xiping GAO1,2,Jie LIU1,Keyong TANG1,**(),Chang LU2,Yuqing ZHANG2
1. College of Materials and Engineering, Zhengzhou University, Zhengzhou 450052, China
2. School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology,Luoyang 471003, China
Cite this article: 

Cuiyun LIU,Xiping GAO,Jie LIU,Keyong TANG,Chang LU,Yuqing ZHANG. Preparation and Properties of Sodium Alginate/Polyacrylamide/Graphene Oxide Nanocomposite Hydrogels. Chinese Journal of Materials Research, 2015, 29(7): 517-522.

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Abstract  

Nanocomposite hydrogels of sodium alginate (SA) / polyacrylamide (PAM)/ graphene oxide (GO) were prepared by in situ polymerization.The structure and properties of hydrogels were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscope (AFM), Fourier transform infrared spectroscopy(FTIR) and thermogravimetric analysis (TG). The effect of GO content on the chemical structure, mechanical and swelling properties of the hydrogels was investigated. The results show that the well exfoliated GO flakes could be uniformly dispersed in the polymer matrix, therewith the intermolecular interactions between the components might be enhanced and parts of PAM macromolecules chains were probably grafted onto the GO nanosheets, which in turn changed the microstructure of the hydrogels and resulted in significant enhancement of mechanical properties of the composite hydrogels. As a result, in comparison with the two hydrogeles of pure SA and pure PAM, the prepared composite hydrogels exhibited both of higher tensile strength and breaking elongation up to 200%, as well as a higher compressive strength up to 156%. The swelling capacity of the composite hydrogels increased and then declined with the increasing GO content, while increased with the increasing SA content.

Key words:  composites      sodium alginate      polyacrylamide      graphene oxide      hydrogel      mechanical property     
Received:  21 August 2014     
Fund: *Supported by National Natural Science Foundation of China Nos. 50973097 and 21076199.

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2014.438     OR     https://www.cjmr.org/EN/Y2015/V29/I7/517

Fig.1  AFM image and the height profile of the GO sheets
Fig.2  XRD spectra of graphite, GO and SA/PAM GO hydrogels with different amounts of GO
Fig.3  FTIR spectra of SA1/PAM and SA1/PAM/GO with various contents of GO
Fig.4  TG curses of SA1/PAM/GO dried gels with different amounts of GO and GO
Fig.5  SEM images of SA1/PAM/GO hydrogels with different amounts of GO, (a) 0, (b) 0.7%, (c) 1.3%, (d) 2.4%
Fig.6  Effect of GO and SA content on swelling ratio of SA/PAM /GO hydrogels
Fig.7  Tensile (A) and compressive (B) strain-stress curves of SA1/PAM/GO hydrogels with different amounts of GO, (1) 0, (2) 0.7%, (3) 1.3%, (4) 2.4%, (5) 3.0%
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