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The Preparation of Microcrystalline Si Films Deposited by ECR-PECVD Using SiH4+Ar |
CHENG Hua, ZHANG Xin, ZHANG Guangcheng, LIU Ruhong, WU Aimin, SHI Nanlin |
1.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2.Armor Technique Institute of PLA, Changchun 130117
3.Dalian University of Technology, Dalian 116024 |
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Cite this article:
CHENG Hua ZHANG Xin ZHANG Guangcheng LIU Ruhong WU Aimin SHI Nanlin. The Preparation of Microcrystalline Si Films Deposited by ECR-PECVD Using SiH4+Ar. Chin J Mater Res, 2010, 24(5): 547-549.
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Abstract Microcrystalline silicon films were prepared using Ar diluted SiH4 gaseous mixture by electron cyclotron resonance plasma-enhanced chemical vapor deposition (ECR--PECVD). The effects of the microwave power on deposition rate, crystallinity, grain size and the configuration of H existing in microcrystalline silicon films were investigated. The results show that the crystallinity increases and the concentration of hydrogen decreases
monotonously with the increasing of the microwave power. But the deposition rate first increases monotonously, and then decreases. Optimized microwave power is 600 W for the highest deposition rate. <111> orientation is the only dominant crystal texture for films obtained with different power.
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Received: 07 June 2010
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[1] A. Fontcuberta i Morral, J. Bertomeu, P. Roca i Cabarrocas, The role of hydrogen in the formation of microcrystalline silicon, Materials Science and Engineering B, 69–70, 559–563 (2000)
[2] Michio Kondo, Makoto Fukawa, Lihui Guo, et al. High rate growth of microcrystalline silicon at low temperatures, Journal of Non-Crytalline Solids, 266-269, 84-89 (2000)
[3] Rui Huang, Xuanying Lin, Wenyong Huang, et al. Effect of Hydrogen on the Low Temperature Growth of Polycrystalline Silicon Film Deposited by SiCl4/H2, Thin Solid Films, 513, 380-384 (2006)
[4] N. H. Nickel, N. M. Johnson, J. Walker, Hydrogen induced generation of acceptorlike defects in polycrystalline silicon, Physical Review Letters, 75, 3720-3723 (1995)
[5] G.Tureban, Y. Catherine, and B. Grolleau, Mass spectrometry of a silane glow discharge during plasma deposition of a-Si: H films, Thin Solid Films, 67, 309 (1980)
[6] Liu Guohan, Ding Yi, He Deyan, et al. Investigation of deposition of hydrogenated amorphous silicon thin film with HW-MWECR-CVD system. Acta Energiae Solaris Sinica, 27, 986-989 (2006)
[7] H. Cheng, A. M. Wu, N. L. Shi, L. S. Wen, Effect of Ar on polycrystalline Si films deposited by ECR-PECVD using SiH4. Journal of Material Science and Technology, 24, 690-692 (2008)
[8] B. Strahma, A.A. Howling, L. Sansonnens, Microcrystalline silicon deposited at high rate on large areas from pure silane with efficient gas utilization, Solar Energy Materials & Solar Cells, 91, 495–502 (2007)
[9] L Sansonnens, A A Howling, Ch Hollenstein, et al. The role of metastable atoms in argon-diluted silane radiofrequency plasmas, J. Phys. D: Appl. Phys., 27, 1406-1411 (1994)
[10] W. J. Soppe, C. Devilee, M. Geusebroek, et al. The effect of argon dilution on deposition of microcrystalline silicon by microwave plasma enhanced chemical vapor deposition, Thin Solid Films, 515, 7490-7494 (2007)
[11] E. Amanatides, S. Stamou, D. Mataras, Gas phase and surface kinetics in plasma enhanced chemical vapor deposition of microcrystalline silicon: The combined effect of rf power and hydrogen dilution, J. Appl. Phys., 90, 5786 (2001)
[12] G. Cicalaa, P. Brunob, A. M. Losaccoc, PECVD of hydrogenated diamond-like carbon films from CH4–Ar mixtures: growth chemistry and material characteristics, Diamond and Related Materials, 13, 1361–1365 (2004)
[13] Wen-Chu Hsiao, Chuan-Pu Liu, Ying-Lang Wang, Thermal prosperities of hydrogenated amorphous silicon prepared by high-density plasma chemical vapor depositon, Journal of Physics and Chemistry of Solids, 69, 648-652 (2008)
[14] Debajyoti Das, Madhusudan Jana, A. K. Barua, Heterogeneity in microcrystalline-transition state: Origin of Si-nucleation and microcrystallization at higher rf power from Ar-diluted SiH4 plasma, Journal of Applied Physics, 89, 3041-3048 (2001)
[15] G. Ambrosone, U. Coscia, S. Lettieri, Microcrystalline silicon thin films grown at high deposition rate by PECVD, Thin Solid Films, 511 – 512, 280 – 284 (2006)
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