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Chinese Journal of Materials Research  2019, Vol. 33 Issue (1): 53-58    DOI: 10.11901/1005.3093.2017.787
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Preparation of Needle Cokes with High Electrical Conductivity and Low Coefficient of Thermal Expansion
Bin QIN,Qun WANG,FuMeng WANG,LiE JIN,XiaoLing XIE,Qing CAO()
Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, China
Cite this article: 

Bin QIN,Qun WANG,FuMeng WANG,LiE JIN,XiaoLing XIE,Qing CAO. Preparation of Needle Cokes with High Electrical Conductivity and Low Coefficient of Thermal Expansion. Chinese Journal of Materials Research, 2019, 33(1): 53-58.

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Abstract  

Needle-cokes (NCs) were synthesized via a two-step process, namely mesocarbon microbeads (MCMB) were firstly blended with coal tar pitch (CTP) at 180oC for ca 30 min, and which was then calcined in an autoclave filled with 0.5 MPa nitrogen at 1500oC for 5 h. The microstructure of mesophase, semi-cokes and the final product NCs was characterized by means of polarizing microscope, XRD and SEM. The resistivity and coefficient of thermal expansion (CTE) were measured by resistivity meter and thermal mechanical analyzer, respectively. The results show that the addition of moderate amount of MCMB could affect the formation of NCs, so that promote the formation of graphite-like layered structure, which significantly reduced the resistivity and CTE value of NCs. The structure of needle-cokes could be effectively improved with the increase of MCMB content (≤50 mass fraction%). However, the quality of needle-cokes began to decline as the content of MCMB exceeded 50%. The resistivity and CTE value (at 0-100oC) of NCs decreased by 27.9% and 45.7%, respectively, when the content of MCMB is 50% in feedstock, meanwhile, the corresponding graphitization degree increased by 46.2%, as comparing with the parent needle-coke.

Key words:  synthesizing and processing technics      needle coke      secondary growth      mesocarbon microbead      resistivity      coefficient of thermal expansion     
Received:  08 January 2018     
ZTFLH:  TQ522.65  
Fund: Supported by National Natural Science Foundation of China(51174144)

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2017.787     OR     https://www.cjmr.org/EN/Y2019/V33/I1/53

SampleTI*/%QIs/%SP/℃CV/%
CTP27.054.7310652.10
Table 1  Some properties of CTP.
SampleTIQIsV**AM
MCMB99.196.27.660.230.18
  
Fig.1  Temperature-controlling programme during carbonization
Fig.2  SEM images of NCs obtained from different contents of MCMB (a) NC-0%-MCMB; (b) NC-50%-MCMB; (c) NC-60%-MCMB
Fig.3  Polarized micrographs of mesophase and SCs
Fig.4  XRD patterns of NCs with different contents of MCMB
Sample2θ/(°)d002/nm*Lc/nmMG/%
NC-0%-MCMB25.940.34329.18527.769.30
NC-50%-MCMB25.970.34289.26028.0113.60
NC-60%-MCMB25.940.34328.93027.029.30
Table 3  Structural parameters of NCs
Fig.5  Relationship between the resistivity of NCs and the contents of MCMB
Fig.6  Effect of MCMB contents on the CTE of NCs
Fig.7  Possible formation mechanism of NCs
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