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Preparation of Needle Cokes with High Electrical Conductivity and Low Coefficient of Thermal Expansion |
Bin QIN,Qun WANG,FuMeng WANG,LiE JIN,XiaoLing XIE,Qing CAO( ) |
Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, China |
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Cite this article:
Bin QIN,Qun WANG,FuMeng WANG,LiE JIN,XiaoLing XIE,Qing CAO. Preparation of Needle Cokes with High Electrical Conductivity and Low Coefficient of Thermal Expansion. Chinese Journal of Materials Research, 2019, 33(1): 53-58.
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Abstract Needle-cokes (NCs) were synthesized via a two-step process, namely mesocarbon microbeads (MCMB) were firstly blended with coal tar pitch (CTP) at 180oC for ca 30 min, and which was then calcined in an autoclave filled with 0.5 MPa nitrogen at 1500oC for 5 h. The microstructure of mesophase, semi-cokes and the final product NCs was characterized by means of polarizing microscope, XRD and SEM. The resistivity and coefficient of thermal expansion (CTE) were measured by resistivity meter and thermal mechanical analyzer, respectively. The results show that the addition of moderate amount of MCMB could affect the formation of NCs, so that promote the formation of graphite-like layered structure, which significantly reduced the resistivity and CTE value of NCs. The structure of needle-cokes could be effectively improved with the increase of MCMB content (≤50 mass fraction%). However, the quality of needle-cokes began to decline as the content of MCMB exceeded 50%. The resistivity and CTE value (at 0-100oC) of NCs decreased by 27.9% and 45.7%, respectively, when the content of MCMB is 50% in feedstock, meanwhile, the corresponding graphitization degree increased by 46.2%, as comparing with the parent needle-coke.
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Received: 08 January 2018
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Fund: Supported by National Natural Science Foundation of China(51174144) |
1 | KumarS, SrivastavaM. Influence of presence/addition of asphaltenes on semi-coke textures and mesophase development in petroleum feed stocks [J]. Fuel, 2016, 173: 69 | 2 | KangH G, ParkJ K, HanB S, et al. Electrochemical characteristics of needle coke refined by olten caustic leaching as an anode material for a lithium-ion battery [J]. Journal of Power Sources, 2006, 153(1): 170 | 3 | WangJ, WangL, ChenM, et al. Nanoporous carbons from oxidized green needle coke for use in high performance supercapacitors [J]. New Carbon Materials, 2015, 30(2): 141 | 4 | TangX Y, WeiX H, et al. Removal of QI from medium-temperature coal tar pitch and preparation of needle coke through carbonization [J]. Chinese Journal of Materials Research, 2016, 30(6): 448 | 4 | 唐闲逸, 魏晓慧, 许德平等. 中温煤沥青喹啉不溶物的脱除及炭化制备针状焦 [J]. 材料研究学报, 2016, 30(6): 448) | 5 | CaiChuang, ChenYing, WangFu, et al. The prospects for the development of coal based needle coke industry [J]. Fuel & Chemical Processes, 2017, 48(6): 1 | 5 | 蔡闯, 陈莹, 王伏等. 煤系针状焦行业发展前景 [J]. 燃料与化工, 2017, 48(6): 1) | 6 | AlvarezP, DiezN, SantamaríaR, et al. Novel coal-based precursors for cokes with highly oriented microstructures[J]. Fuel, 2012, 95: 400 | 7 | ChengX, ZhaQ, LiX, et al. Modified characteristics of mesophase pitch prepared from coal tar pitch by adding waste polystyrene[J]. Fuel Processing Technology, 2008, 89(12): 1436 | 8 | BrzozowskaT, ZielinskiJ, MachnikowskiJ. Effect of polymeric additives to coal tar pitch on carbonization behaviour and optical texture of resultant cokes [J]. Journal of Analytical and Applied Pyrolysis, 1998, 48(1): 45 | 9 | LinQ, LiT, JiY, et al. Study of the modification of coal-tar pitch with p-methyl benzaldehyde [J]. Fuel, 2005, 84(2): 177 | 10 | LinQ, LiT, ZhengC, et al. Carbonization behavior of coal-tar pitch modified with divinylbenzene and optical texture of resultant semi-cokes [J]. Journal of Analytical and Applied Pyrolysis, 2004, 71(2): 817 | 11 | XuD P, TangS B, TangX Y, et al. Research advances of composites in feedstock on formation of mesophase in needle coke preparation [J]. Carbon Techniques, 2016, 35(1): 34 | 11 | 许德平, 唐世波, 唐闲逸等. 针状焦制备过程中原料组分对中间相影响的研究进展 [J]. 炭素技术, 2016, 35(1): 34) | 12 | SunS, WangC, ChenM, et al. A method to observe the structure of the interface between mesocarbon microbeads and pitch [J]. Journal of Colloid and Interface Science, 2014, 426: 206 | 13 | MochidaI, OyamaT, KoraiY, et al. Study of carbonization using a tube bomb: evaluation of lump needle coke, carbonization mechanism and optimization [J]. Fuel, 1988, 67(9): 1171 | 14 | CaoQ, XieX, LiJ, et al. A novel method for removing quinoline insolubles and ash in coal tar pitch using electrostatic fields [J]. Fuel, 2012, 96: 314 | 15 | ImU S, KimJ, LeeS H, et al. Effects of Two-stage Heat Treatment on Delayed Coke and Study of Their Surface Texture Characteristics [J]. JOM, 2017, 69(12): 2460 | 16 | Im JiS, LeeC W, HalimH P. Preparation of needle coke from petroleum by-products [J]. Carbon Letters, 2013, 14(3): 152 |
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