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Chin J Mater Res  2004, Vol. 18 Issue (3): 301-307    DOI:
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Effects of functional groups on the friction properties of self--assembled monolayers
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大连海事大学
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. Effects of functional groups on the friction properties of self--assembled monolayers. Chin J Mater Res, 2004, 18(3): 301-307.

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Abstract  The friction properties of two kinds of self--asssembled monolayers with the same length of molecule chain and different functional groups were investigated. The effects of load and sliding velocity on the friction characteristics of SAMs were analyzed. The results indicate that the stronger the chemical activity of functional group in self--assembled molecules is, the more remarkable the SAMs cluster topography characteristics are. The friction forces increase with increasing the loads for these two self--assembled molecules with short chain. However, the effects of sliding velocity on the friction force appear when the chemical reactivity of functional group in self--assembled molecules is strong enough. The friction forces decrease markedly after the formation of SAMs with stable structure, which exhibits anti--friction effect. The anti--friction effect disappears if the load rises to a threshold for SAMs with stronger active functional group. The stronger the chemical activity of functional group in self-assembled molecule is, the larger the friction forces are.
Key words:  organic polymer materials      surface and interface in the materials      atomic force microscopy      friction      se     
Received:  19 July 2004     
ZTFLH:  TB324  
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