In-situ Growth of MoS2 on the Surface of Polyquinazoline Conjugated Microporous Polymers and Its Electrocatalysis Hydrogen Performance

doi:10.11901/1005.3093.2021.263

Chinese Journal of Materials Research

2022, Vol. 36

Issue (12): 900-906 DOI: 10.11901/1005.3093.2021.263

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In-situ Growth of MoS₂ on the Surface of Polyquinazoline Conjugated Microporous Polymers and Its Electrocatalysis Hydrogen Performance

JIANG Haichao¹(

), AN Haodong¹, YANG Jing¹, SU Yujin¹, LI Ze¹, ZHANG Bin²

^1.Hebei University of Science & Technology, College of Chemical and Pharmaceutical, Shijiazhuang 050018, China
^2.Hebei Chemical & Pharmaceutical College, Shijiazhuang 050026, China

Cite this article:

JIANG Haichao, AN Haodong, YANG Jing, SU Yujin, LI Ze, ZHANG Bin. In-situ Growth of MoS₂ on the Surface of Polyquinazoline Conjugated Microporous Polymers and Its Electrocatalysis Hydrogen Performance. Chinese Journal of Materials Research, 2022, 36(12): 900-906.

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Abstract

Tripolyquinazoline-based conjugated microporous polymers (TQ-CMPs) were synthesized, and molybdenum sulfide (MoS₂) nanoparticles grown in-situ on the surface of TQ-CMPs via hydrothermal method as a new type of composite electrocatalyst for hydrogen evolution reaction. Its electrocatalytic hydrogen evolution activity was studied. As a result, when the mass ratio of the TQ-CMPs and MoS₂ is 2∶1 the electrocatalyst has excellent electrocatalytic activity for an overpotential of 71 mV and a Tafel slope of 52 mV·dec^-1 for hydrogen evolution reaction. TQ-CMPs have large specific surface areas, which improve the dispersion of MoS₂. The accumulation of MoS₂ was avoided effectively, and more MoS₂ edges was exposed, which improved the electrocatalytic activity. In addition, the abundant porous structure and extended π-conjugated framework of TQ-CMPs facilitated mass transport and charge transfer.

Key words: composits conjugated microporous polymers molybdenum sulfide hydrogen evolution reaction electrocatalysis

Received: 25 April 2021

ZTFLH:

TB322

Fund: Key Research and Development Program of Hebei Province(19273808D);the Science and Technology Research and Development Program of Shijiazhuang City(201240253A)

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	Haichao JIANG
	Haodong AN
	Jing YANG
	Yujin SU
	Ze LI
	Bin ZHANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.263 OR https://www.cjmr.org/EN/Y2022/V36/I12/900

Fig.1 FI-IR spectra of TQ-CMPs

Fig.2 N₂ adsorption and desorption isotherms at 77K (a) and pore width distribution (b)

Fig.3 XRD pattern of MoS₂, TQ-CMPs@MoS₂ and TQ-CMP

Fig.4 SEM images of TQ-CMPs (a) and TQ-CMPs@MoS₂ 2∶1 (b). TEM images of TQ-CMPs (c) and TQ-CMPs@MoS₂ 2∶1 (d). HRTEM images of TQ-CMPs@MoS₂ 2∶1 (e, f)

Fig.5 Electrochemical performances of all catalysts (a) LSV in 0.5 mol·L^?1 H₂SO₄, (b) Tafel slope calculated from LSVs, (c) Nyquist plots of all catalysts, (d) Stability and (e) Cyclic voltammetry curves of TQ-CMPs@MoS₂ 2∶1, (f) The double-layer capacitance (C_dl) of all catalystsv (■: Pt/C 20%;◆: TQ-CMPs@ MoS₂ 5∶1; ▲: TQ-CMPs@ MoS₂ 2∶1; ●: TQ-CMPs@MoS₂ 1∶1; ▼: TQ-CMPs@MoS₂ 1∶2; ?: TQ-CMPs; ?: MoS₂)

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